Phase transition of a diblock copolymer and homopolymer hybrid system induced by different properties of nanorods

doi:10.1088/1674-1056/27/5/058102

中国物理B ›› 2018, Vol. 27 ›› Issue (5): 58102-058102.doi: 10.1088/1674-1056/27/5/058102

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

Phase transition of a diblock copolymer and homopolymer hybrid system induced by different properties of nanorods

Xiao-bo Geng(耿晓波), Jun-xing Pan(潘俊星), Jin-jun Zhang(张进军), Min-na Sun(孙敏娜), Jian-yong Cen(岑建勇)

1 School of Physics and Information Engineering, Shanxi Normal University, Linfen 041004, China;
2 School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004, China

收稿日期:2017-10-14 修回日期:2018-02-11 出版日期:2018-05-05 发布日期:2018-05-05
通讯作者: Jun-xing Pan, Jin-jun Zhang E-mail:panjunxing2007@163.com;zhangjinjun@sxun.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No.21373131),the Provincial Natural Science Foundation of Shanxi,China (Grant No.2015011004),and the Research Foundation for Excellent Talents of Shanxi Provincial Department of Human Resources and Social Security,China.

Phase transition of a diblock copolymer and homopolymer hybrid system induced by different properties of nanorods

Xiao-bo Geng(耿晓波)², Jun-xing Pan(潘俊星)¹, Jin-jun Zhang(张进军)¹, Min-na Sun(孙敏娜)², Jian-yong Cen(岑建勇)¹

1 School of Physics and Information Engineering, Shanxi Normal University, Linfen 041004, China;
2 School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004, China

Received:2017-10-14 Revised:2018-02-11 Online:2018-05-05 Published:2018-05-05
Contact: Jun-xing Pan, Jin-jun Zhang E-mail:panjunxing2007@163.com;zhangjinjun@sxun.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No.21373131),the Provincial Natural Science Foundation of Shanxi,China (Grant No.2015011004),and the Research Foundation for Excellent Talents of Shanxi Provincial Department of Human Resources and Social Security,China.

摘要/Abstract

摘要： We investigated phase transitions in a diblock copolymer-homopolymer hybrid system blended with nanorods (NRs) by using the time-dependent Ginzburg-Landau theory. We systematically studied the effects of the number, length and infiltration properties of the NRs on the self-assembly of the composites and the phase transitions occurring in the material. An analysis of the phase diagram was carried out to obtain the formation conditions of sea island structure nanorod-based aggregate, sea island structure nanorod-based dispersion, lamellar structure nanorod-based multilayer arrangement and nanowire structure. Further analysis of the evolution of the domain sizes and the distribution of the nanorod angle microphase structure was performed. Our simulation provides theoretical guidance for the preparation of ordered nanowire structures and a reference to improve the function of a polymer nanocomposite material.

关键词: self-assembly, block copolymer, nanowires

Abstract: We investigated phase transitions in a diblock copolymer-homopolymer hybrid system blended with nanorods (NRs) by using the time-dependent Ginzburg-Landau theory. We systematically studied the effects of the number, length and infiltration properties of the NRs on the self-assembly of the composites and the phase transitions occurring in the material. An analysis of the phase diagram was carried out to obtain the formation conditions of sea island structure nanorod-based aggregate, sea island structure nanorod-based dispersion, lamellar structure nanorod-based multilayer arrangement and nanowire structure. Further analysis of the evolution of the domain sizes and the distribution of the nanorod angle microphase structure was performed. Our simulation provides theoretical guidance for the preparation of ordered nanowire structures and a reference to improve the function of a polymer nanocomposite material.

Key words: self-assembly, block copolymer, nanowires

中图分类号: (Self-assembly)

81.16.Dn

82.35.Jk (Copolymers, phase transitions, structure) 81.07.Gf (Nanowires)

耿晓波, 潘俊星, 张进军, 孙敏娜, 岑建勇. Phase transition of a diblock copolymer and homopolymer hybrid system induced by different properties of nanorods[J]. 中国物理B, 2018, 27(5): 58102-058102.

Xiao-bo Geng(耿晓波), Jun-xing Pan(潘俊星), Jin-jun Zhang(张进军), Min-na Sun(孙敏娜), Jian-yong Cen(岑建勇). Phase transition of a diblock copolymer and homopolymer hybrid system induced by different properties of nanorods[J]. Chin. Phys. B, 2018, 27(5): 58102-058102.

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Phase transition of a diblock copolymer and homopolymer hybrid system induced by different properties of nanorods

Phase transition of a diblock copolymer and homopolymer hybrid system induced by different properties of nanorods

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