中国物理B ›› 2018, Vol. 27 ›› Issue (5): 54216-054216.doi: 10.1088/1674-1056/27/5/054216
• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇 下一篇
Mohd Shkir, V Ganesh, S AlFaify, I S Yahia, Mohd Anis
收稿日期:
2017-12-07
修回日期:
2018-01-22
出版日期:
2018-05-05
发布日期:
2018-05-05
通讯作者:
Mohd Shkir, S AlFaify
E-mail:shkirphysics@gmail.com;sasaalfaify@hotmail.com
基金资助:
Mohd Shkir1, V Ganesh1, S AlFaify1, I S Yahia1, Mohd Anis2
Received:
2017-12-07
Revised:
2018-01-22
Online:
2018-05-05
Published:
2018-05-05
Contact:
Mohd Shkir, S AlFaify
E-mail:shkirphysics@gmail.com;sasaalfaify@hotmail.com
Supported by:
摘要: In this work, uranine-dyed zinc (tris) thiourea sulfate (ZTS) monocrystals, 26 mm×15 mm×10 mm in size, were synthesized by the solution method at ambient temperature. Their purity, crystallinity, lattice parameters, and functional modes were studied by x-ray diffraction, Fourier transform-infrared spectroscopy (FT-IR), and FT-Raman spectroscopy analyses. The sodium ion content of the crystals from the dye was confirmed by elemental analysis. The diffused reflectance spectral analysis of the dyed crystal revealed a characteristic absorption band at 490 nm attributed to the presence of the dye. The calculated band gaps of the non-dyed and dyed crystals were 4.53 and 4.57 eV, respectively. A green emission peak at ~(512±4) nm was observed in the photoluminescence spectrum of the uranine-dyed crystals. A differential scanning calorimetry study confirmed that the thermal stability improved owing to the addition of the dye. Dielectric and microhardness studies were conducted to examine the significant improvements in the corresponding properties of dyed crystals. The results demonstrated the competency of the dyed ZTS crystals for applications in optoelectronic devices.
中图分类号: (Nonlinear optical crystals)
Mohd Shkir, V Ganesh, S AlFaify, I S Yahia, Mohd Anis. Structural, vibrational, optical, photoluminescence, thermal, dielectric, and mechanical studies on zinc (tris) thiourea sulfate single crystal: A noticeable effect of organic dye[J]. 中国物理B, 2018, 27(5): 54216-054216.
Mohd Shkir, V Ganesh, S AlFaify, I S Yahia, Mohd Anis. Structural, vibrational, optical, photoluminescence, thermal, dielectric, and mechanical studies on zinc (tris) thiourea sulfate single crystal: A noticeable effect of organic dye[J]. Chin. Phys. B, 2018, 27(5): 54216-054216.
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