中国物理B ›› 2017, Vol. 26 ›› Issue (10): 104208-104208.doi: 10.1088/1674-1056/26/10/104208

• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇    下一篇

Structural evolution study of additions of Sb2S3 and CdS into GeS2 chalcogenide glass by Raman spectroscopy

Hai-Tao Guo(郭海涛), Ming-Jie Zhang(张鸣杰), Yan-Tao Xu(许彦涛), Xu-Sheng Xiao(肖旭升), Zhi-Yong Yang(杨志勇)   

  1. 1. Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China;
    2. State Key Laboratory of Transient Optics and Photonics, Xi'an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences(CAS), Xi'an 710119, China;
    3. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China
  • 收稿日期:2017-04-29 修回日期:2017-06-01 出版日期:2017-10-05 发布日期:2017-10-05
  • 通讯作者: Hai-Tao Guo, Zhi-Yong Yang E-mail:guoht_001@opt.ac.cn;yangzhiyong@jsnu.edu.cn
  • 基金资助:

    Project supported by the National Natural Science Foundation of China (Grant Nos. 61475189, 61405240, and 61575086), the Natural Science Basic Research Project in Shaanxi Province, China (Grant No. 2015JQ5141), and the Jiangsu Key Laboratory of Advanced Laser Materials and Devices, Jiangsu Normal University, China (Grant No. KLALMD-2015-08).

Structural evolution study of additions of Sb2S3 and CdS into GeS2 chalcogenide glass by Raman spectroscopy

Hai-Tao Guo(郭海涛)1,2, Ming-Jie Zhang(张鸣杰)1,3, Yan-Tao Xu(许彦涛)2, Xu-Sheng Xiao(肖旭升)2, Zhi-Yong Yang(杨志勇)1   

  1. 1. Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China;
    2. State Key Laboratory of Transient Optics and Photonics, Xi'an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences(CAS), Xi'an 710119, China;
    3. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China
  • Received:2017-04-29 Revised:2017-06-01 Online:2017-10-05 Published:2017-10-05
  • Contact: Hai-Tao Guo, Zhi-Yong Yang E-mail:guoht_001@opt.ac.cn;yangzhiyong@jsnu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Grant Nos. 61475189, 61405240, and 61575086), the Natural Science Basic Research Project in Shaanxi Province, China (Grant No. 2015JQ5141), and the Jiangsu Key Laboratory of Advanced Laser Materials and Devices, Jiangsu Normal University, China (Grant No. KLALMD-2015-08).

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摘要：

The structures of pseudo-binary GeS2-Sb2S3, GeS2-CdS, Sb2S3-CdS, and pseudo-ternary GeS2-Sb2S3-CdS chalcogenide systems are systematically investigated by Raman spectroscopy. It is shown that a small number of[S3Ge-GeS3] structural units (SUs) and -S-S-/S8 groups exist simultaneously in GeS2 glass which has a three-dimensional continuous network backbone consisting of cross-linked corner-sharing and edge-sharing[GeS4] tetrahedra. When Sb2S3 is added into GeS2 glass, the network backbone becomes interconnected[GeS4] tetrahedra and[SbS3] pyramids. Moreover, Ge atoms in[S3Ge-GeS3] SUs tend to capture S atoms from Sb2S3, leading to the formation of[S2Sb-SbS2] SUs. When CdS is added into GeS2 glass,[Cd4GeS6] polyhedra are formed, resulting in a strong crystallization tendency. In addition, Ge atoms in[S3Ge-GeS3] SUs tend to capture S atoms from CdS, resulting in the dissolution of Ge-Ge bond. Co-melting of Sb2S3 or CdS with GeS2 reduces the viscosity of the melt and improves the homogeneity of the glass. The GeS2 glass can only dissolve up to 10-mol% CdS without crystallization. In comparison, GeS2-Sb2S3 glasses can dissolve up to 20-mol% CdS, implying that Sb2S3 could delay the construction of[Cd4GeS6] polyhedron and increase the dissolving amount of CdS in the glass.

关键词: chalcogenide glass, Raman spectroscopy, structure, Ge-Sb-Cd-S system

Abstract:

The structures of pseudo-binary GeS2-Sb2S3, GeS2-CdS, Sb2S3-CdS, and pseudo-ternary GeS2-Sb2S3-CdS chalcogenide systems are systematically investigated by Raman spectroscopy. It is shown that a small number of[S3Ge-GeS3] structural units (SUs) and -S-S-/S8 groups exist simultaneously in GeS2 glass which has a three-dimensional continuous network backbone consisting of cross-linked corner-sharing and edge-sharing[GeS4] tetrahedra. When Sb2S3 is added into GeS2 glass, the network backbone becomes interconnected[GeS4] tetrahedra and[SbS3] pyramids. Moreover, Ge atoms in[S3Ge-GeS3] SUs tend to capture S atoms from Sb2S3, leading to the formation of[S2Sb-SbS2] SUs. When CdS is added into GeS2 glass,[Cd4GeS6] polyhedra are formed, resulting in a strong crystallization tendency. In addition, Ge atoms in[S3Ge-GeS3] SUs tend to capture S atoms from CdS, resulting in the dissolution of Ge-Ge bond. Co-melting of Sb2S3 or CdS with GeS2 reduces the viscosity of the melt and improves the homogeneity of the glass. The GeS2 glass can only dissolve up to 10-mol% CdS without crystallization. In comparison, GeS2-Sb2S3 glasses can dissolve up to 20-mol% CdS, implying that Sb2S3 could delay the construction of[Cd4GeS6] polyhedron and increase the dissolving amount of CdS in the glass.

Key words: chalcogenide glass, Raman spectroscopy, structure, Ge-Sb-Cd-S system

中图分类号:  (Glasses, quartz)

  • 42.70.Ce
42.70.Km (Infrared transmitting materials) 36.20.Ng (Vibrational and rotational structure, infrared and Raman spectra)