Water-assisted highly enhanced crystallographic etching of graphene by iron catalysts

doi:10.1088/1674-1056/24/3/036802

中国物理B ›› 2015, Vol. 24 ›› Issue (3): 36802-036802.doi: 10.1088/1674-1056/24/3/036802

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Water-assisted highly enhanced crystallographic etching of graphene by iron catalysts

薛磊江^a, 余芳^b, 周海青^b, 孙连峰^b

a College of Computer Science and Technology, Shandong University of Technology, Zibo 255049, China;
b National Centre for Nanoscience and Technology, Beijing 100190, China

收稿日期:2014-09-28 修回日期:2014-10-29 出版日期:2015-03-05 发布日期:2015-03-05
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 10774032) and the Instrument Developing Project of the Chinese Academy of Sciences (Grant No. Y2010031).

Water-assisted highly enhanced crystallographic etching of graphene by iron catalysts

Xue Lei-Jiang (薛磊江)^a, Yu Fang (余芳)^b, Zhou Hai-Qing (周海青)^b, Sun Lian-Feng (孙连峰)^b

a College of Computer Science and Technology, Shandong University of Technology, Zibo 255049, China;
b National Centre for Nanoscience and Technology, Beijing 100190, China

Received:2014-09-28 Revised:2014-10-29 Online:2015-03-05 Published:2015-03-05
Contact: Zhou Hai-Qing, Sun Lian-Feng E-mail:hqzhou0817@gmail.com;slf@nanoctr.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 10774032) and the Instrument Developing Project of the Chinese Academy of Sciences (Grant No. Y2010031).

摘要/Abstract

摘要：

We report the assisted role of water vapor in crystallographic cutting of graphene via iron catalysts in reduced atmosphere. Without water, graphene can be tailored with smooth trenches composed of straight lines with angles of 60° or 120° between two adjacent trenches. After the addition of water, new chacteristics are found: such as almost no iron particles can be detected along the trenches; each trench becomes longer and lots of graphene nanoribbons can be generated. The underlying mechanism is proposed and discussed, which is attributed to stimulating and lengthening of the catalytic activity of iron particles by water vapor.

关键词: graphene, Raman spectra, iron catalysts

Abstract:

Key words: graphene, Raman spectra, iron catalysts

中图分类号: (Graphene films)

68.65.Pq

78.30.-j (Infrared and Raman spectra) 81.65.Cf (Surface cleaning, etching, patterning)

薛磊江, 余芳, 周海青, 孙连峰. Water-assisted highly enhanced crystallographic etching of graphene by iron catalysts[J]. 中国物理B, 2015, 24(3): 36802-036802.

Xue Lei-Jiang (薛磊江), Yu Fang (余芳), Zhou Hai-Qing (周海青), Sun Lian-Feng (孙连峰). Water-assisted highly enhanced crystallographic etching of graphene by iron catalysts[J]. Chin. Phys. B, 2015, 24(3): 36802-036802.

参考文献 37

[1]	Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V and Firsov A A 2004 Science 306 666
[2]	Xu W Y, Huang L, Que Y D, Li E, Zhang H G, Lin X, Wang Y L, Du S X and Gao H J 2014 Chin. Phys. B 23 098101
[3]	Geim A K and Novoselov K S 2007 Nat. Mater. 6 183
[4]	Yang H, Shen C M, Tian Y, Wang G Q, Lin S X, Zhang Y, Gu C Z, Li J J and Gao H J 2014 Chin. Phys. B 23 096803
[5]	Du X, Skachko I, Duerr F, Luican A and Andrei E Y 2009 Nature 462 192
[6]	Bolotin K I, Ghahari F, Shulman M D, Stormer H L and Kim P 2009 Nature 462 196
[7]	Kim W Y and Kim K S 2008 Nat. Nanotechnol. 3 408
[8]	Zhang Z H, Chen C F and Guo W L 2009 Phys. Rev. Lett. 103 187204
[9]	Muñoz-Rojas F, Fernández-Rossier J and Palacios J J 2009 Phys. Rev. Lett. 102 136810
[10]	Li X L, Wang X R, Zhang L, Lee S and Dai H J 2008 Science 319 1229
[11]	Ritter K A and Lyding J W 2009 Nat. Mater. 8 235
[12]	Ma L, Wang J L, Yip J and Ding F 2014 J. Phys. Chem. Lett. 5 1192
[13]	Zoberbier T, Chamberlain T W, Biskupek J, Kuganathan N, Eyhusen S, Bichoutskaia E, Kaiser U and Khlobystov A N 2012 J. Am. Chem. Soc. 134 3073
[14]	Wang J, Ma L, Yuan Q, Zhu L and Ding F 2011 Angew. Chem. Int. Ed. 50 8041
[15]	Konishi S, Sugimoto W, Murakami Y and Takasu Y 2006 Carbon 44 2338
[16]	Ma L, Wang J L and Ding F 2013 Chem. Phys. Chem. 14 47
[17]	Lukas M, Meded V, Vijayaraghavan A, Song L, Ajayan P M, Fink K, Wenzel W and Krupke R 2013 Nat. Commun. 4 1379
[18]	Kosynkin D V, Higginbotham A L, Sinitskii A, Lomeda J R, Dimiev A, Price B K and Tour J M 2009 Nature 458 872
[19]	Jiao L Y, Zhang L, Wang X R, Diankov G and Dai H J 2009 Nature 458 877
[20]	Cano-Márquez A G, Rodríguez-Macías F J, Campos-Delgado J, Espinosa-González C G, Tristán-López F, Ramírez-González D, Cullen D A, Smith D J, Terrones M and Vega-CantúY I 2009 Nano Lett. 9 1527
[21]	Jia X T, Hofmann M, Meunier V, Sumpter B G, Campos-Delgado J, Romo-Herrera J M, Son H, Hsieh Y P, Reina A, Kong J, Terrones M and Dresselhaus M S 2009 Science 323 1701
[22]	Warner J H, Rümmeli M H, Ge L, Gemming T, Montanari B, Harrison N M, Büchner B and Briggs G A D 2009 Nat. Nanotechnol. 4 500
[23]	Ci L J, Xu Z P, Wang L L, Gao W, Ding F, Kelly K F, Yakobson B I and Ajayan P M 2008 Nano Res. 1 116
[24]	Ci L J, Song L, Jariwala D, Elías A L, Gao W, Terrones M and Ajayan P M 2009 Adv. Mater. 21 4487
[25]	Datta S S, Strachan D R, Khamis S M and Johnson A T C 2008 Nano Lett. 8 1912
[26]	Campos L C, Manfrinato V R, Sanchez-Yamagishi J D, Kong J and Jarillo-Herrero P 2009 Nano Lett. 9 2600
[27]	Yu F, Zhou H Q, Zhang Z X, Tang D S, Chen M J, Yang H C, Wang G, Yang H F, Gu C Z and Sun L F 2012 Appl. Phys. Lett. 100 101904
[28]	Hata K, Futaba D N, Mizuno K, Namai T, Yumura M and Iijima S 2004 Science 306 1362
[29]	Amama P B, Pint C L, McJilton L, Kim S M, Stach E A, Murray P T, Hauge R H and Maruyama B 2009 Nano Lett. 9 44
[30]	Zhou H Q, Qiu C Y, Liu Z, Yang H C, Hu L J, Liu J, Yang H F, Gu C Z and Sun L F 2010 J. Am. Chem. Soc. 132 944
[31]	Zhou H Q, Yu F, Yang H C, Qiu C Y, Chen M J, Hu L J, Guo Y J, Yang H F, Gu C Z and Sun L F 2011 Chem. Commun. 47 9408
[32]	Zhao Y C, Song L, Deng K, Liu Z, Zhang Z X, Yang Y L, Wang C, Yang H F, Jin A Z, Luo Q, Gu C Z, Xie S S and Sun L F 2008 Adv. Mater. 20 1772
[33]	Cancado L G, Pimenta M A, Neves B R A, Dantas M S S and Jorio A 2004 Phys. Rev. Lett. 93 247401
[34]	You Y M, Ni Z H, Yu T and Shen Z X 2008 Appl. Phys. Lett. 93 163112
[35]	Guo Y F and Guo W L 2011 J. Phys. Chem. C 115 20546
[36]	Yu F, Zhou H Q, Zhang Z X, Wang G, Yang H C, Chen M J, Tao L, Tang D S, He J and Sun L F 2013 Small 9 2405
[37]	Yu F, Zhou H Q, Yang H C, Chen M J, Wang G and Sun L F 2012 Chem. Commun. 48 1042

Water-assisted highly enhanced crystallographic etching of graphene by iron catalysts

Water-assisted highly enhanced crystallographic etching of graphene by iron catalysts

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