中国物理B ›› 2014, Vol. 23 ›› Issue (8): 88801-088801.doi: 10.1088/1674-1056/23/8/088801

所属专题： INVITED REVIEW — International Conference on Nanoscience & Technology, China 2013

• INVITED REVIEW—International Conference on Nanoscience & Technology, China 2013 • 上一篇    下一篇

Functionalization of carbon nanotubes/graphene by polyoxometalates and their enhanced photo-electrical catalysis

张双双a b, 刘荣基a, 张光晋a, 谷战军c   

  1. a Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
    b University of Chinese Academy of Sciences, Beijing 100049, China;
    c Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
  • 收稿日期:2013-09-04 修回日期:2014-03-14 出版日期:2014-08-15 发布日期:2014-08-15
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant No. 21371173) and the National Basic Research Program of China (973 Program) (Grant No. 2012CB932504).

Functionalization of carbon nanotubes/graphene by polyoxometalates and their enhanced photo-electrical catalysis

Zhang Shuang-Shuang (张双双)a b, Liu Rong-Ji (刘荣基)a, Zhang Guang-Jin (张光晋)a, Gu Zhan-Jun (谷战军)c   

  1. a Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
    b University of Chinese Academy of Sciences, Beijing 100049, China;
    c Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
  • Received:2013-09-04 Revised:2014-03-14 Online:2014-08-15 Published:2014-08-15
  • Contact: Zhang Guang-Jin E-mail:zhanggj@home.ipe.ac.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No. 21371173) and the National Basic Research Program of China (973 Program) (Grant No. 2012CB932504).

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摘要： Carbon nanotubes and graphene are carbon-based materials, which possess not only unique structure but also properties such as high surface area, extraordinary mechanical properties, high electronic conductivity, and chemical stability. Thus, they have been regarded as an important material, especially for exploring a variety of complex catalysts. Considerable efforts have been made to functionalize and fabricate carbon-based composites with metal nanoparticles. In this review, we summarize the recent progress of our research on the decoration of carbon nanotubes/graphene with metal nanoparticles by using polyoxometalates as key agents, and their enhanced photo-electrical catalytic activities in various catalytic reactions. The polyoxometalates play a key role in constructing the nanohybrids and contributing to their photo-electrical catalytic properties.

关键词: carbon nanotube, graphene, polyoxometalate, photo-electro-catalysis

Abstract: Carbon nanotubes and graphene are carbon-based materials, which possess not only unique structure but also properties such as high surface area, extraordinary mechanical properties, high electronic conductivity, and chemical stability. Thus, they have been regarded as an important material, especially for exploring a variety of complex catalysts. Considerable efforts have been made to functionalize and fabricate carbon-based composites with metal nanoparticles. In this review, we summarize the recent progress of our research on the decoration of carbon nanotubes/graphene with metal nanoparticles by using polyoxometalates as key agents, and their enhanced photo-electrical catalytic activities in various catalytic reactions. The polyoxometalates play a key role in constructing the nanohybrids and contributing to their photo-electrical catalytic properties.

Key words: carbon nanotube, graphene, polyoxometalate, photo-electro-catalysis

中图分类号:  (Carbon nanotubes)

  • 88.30.rh
78.67.Bf (Nanocrystals, nanoparticles, and nanoclusters) 82.45.Jn (Surface structure, reactivity and catalysis)