Orange dye–polyaniline composite based impedance humidity sensors

doi:10.1088/1674-1056/22/1/010701

Chin. Phys. B ›› 2013, Vol. 22 ›› Issue (1): 10701-010701.doi: 10.1088/1674-1056/22/1/010701

Orange dye–polyaniline composite based impedance humidity sensors

Muhammad Tariq Saeed Chani^{a b}, Kh. S. Karimov^{a c}, F. A. Khalid^a, S. Z. Abbas^a, M. B. Bhatty^a

a GIK Institute of Engineering Sciences and Technology, Topi 23640, Khyber Pakhtunkhwa, Pakistan;
b Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah 21589, P.O. Box 80203, Saudi Arabia;
c Physical Technical Institute, Aini St. 299/1, Dushanbe, 734063, Tajikistan

收稿日期:2012-01-05 修回日期:2012-02-28 出版日期:2012-12-01 发布日期:2012-12-01

Orange dye–polyaniline composite based impedance humidity sensors

Muhammad Tariq Saeed Chani^{a b}, Kh. S. Karimov^{a c}, F. A. Khalid^a, S. Z. Abbas^a, M. B. Bhatty^a

a GIK Institute of Engineering Sciences and Technology, Topi 23640, Khyber Pakhtunkhwa, Pakistan;
b Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah 21589, P.O. Box 80203, Saudi Arabia;
c Physical Technical Institute, Aini St. 299/1, Dushanbe, 734063, Tajikistan

Received:2012-01-05 Revised:2012-02-28 Online:2012-12-01 Published:2012-12-01
Contact: Muhammad Tariq Saeed Chani E-mail:tariq_chani@yahoo.com

摘要/Abstract

摘要： This study presents the fabrication and investigation of humidity sensors based on orange dye (OD) and polyaniline (PANI) composite films. A blend of 3 wt.% OD with 1 wt.% PANI was prepared in 1 ml water. The composite films were deposited on glass substrates between pre-deposited silver electrodes. The gap between the electrodes was 45 μm. The sensing mechanism was based on the impedance and capacitance variations due to the absorption/desorption of water vapor. It was observed that with the increase in relative humidity (RH) from 30% to 90%, the impedance decreases by 5.2×10⁴ and 8.8×10³ times for the frequencies of 120 Hz and 1 kHz, respectively. The impedance-humidity relationship showed a more uniform change as compared to the capacitance-humidity relationship in the RH range of 30% to 90%. The consequence of annealing, measuring frequency, response and recovery time, and absorption-desorption behavior of the humidity sensor were also discussed in detail. The annealing resulted in the increase in sensitivity upto 2.5 times, while the measured response time and recovery time were 34 s and 450 s, respectively. The impedance-humidity relationship was simulated.

关键词: organic-organic composite, humidity sensor, polyaniline, orange dye

Abstract: This study presents the fabrication and investigation of humidity sensors based on orange dye (OD) and polyaniline (PANI) composite films. A blend of 3 wt.% OD with 1 wt.% PANI was prepared in 1 ml water. The composite films were deposited on glass substrates between pre-deposited silver electrodes. The gap between the electrodes was 45 μm. The sensing mechanism was based on the impedance and capacitance variations due to the absorption/desorption of water vapor. It was observed that with the increase in relative humidity (RH) from 30% to 90%, the impedance decreases by 5.2×10⁴ and 8.8×10³ times for the frequencies of 120 Hz and 1 kHz, respectively. The impedance-humidity relationship showed a more uniform change as compared to the capacitance-humidity relationship in the RH range of 30% to 90%. The consequence of annealing, measuring frequency, response and recovery time, and absorption-desorption behavior of the humidity sensor were also discussed in detail. The annealing resulted in the increase in sensitivity upto 2.5 times, while the measured response time and recovery time were 34 s and 450 s, respectively. The impedance-humidity relationship was simulated.

Key words: organic-organic composite, humidity sensor, polyaniline, orange dye

中图分类号: (Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing)

07.07.Df

07.07.Vx (Hygrometers; hygrometry) 72.80.Le (Polymers; organic compounds (including organic semiconductors)) 84.37.+q (Measurements in electric variables (including voltage, current, resistance, capacitance, inductance, impedance, and admittance, etc.))

Muhammad Tariq Saeed Chani, Kh. S. Karimov, F. A. Khalid, S. Z. Abbas, M. B. Bhatty. Orange dye–polyaniline composite based impedance humidity sensors[J]. Chin. Phys. B, 2013, 22(1): 10701-010701.

参考文献 30

[1]	Fuke M V, Kanitkar P, Kulkarni M, Kale B B and Aiyer R C 2010 Talanta 81 320
[2]	Chen Z and Lu C 2005 Sens. Letters 3 274
[3]	Ramaprasad A T and Rao V 2010 Sensor and Actuators B 148 117
[4]	Nohria R, Khillan R K, Su Y, Dikshit R, Lvov Y and Varahramyan K 2006 Sensor and Actuators B 114 218
[5]	Huang J R, Li M Q, Huang Z Y and Liu J H 2007 Sensor and Actuators A 133 467
[6]	Ahmad Z, Sayyad M H, Saleem M, Karimov K S and Shah M 2008 Physica E 41 18
[7]	Zeng F W, Liu X X, Diamond D and Lau K T 2010 Sensor and Actuators B 143 530
[8]	Matsuguchi M, Okamoto A and Sakai Y 2003 Sensor and Actuators B 94 46
[9]	Palaniappan S and John A 2008 Prog. Polym. Sci. 33 732
[10]	Huang L M, Chen C H, Wen T C and Gopalan A 2006 Electrochimica Acta 51 2756
[11]	Li Y, Ying B, Hong L and Yang M 2010 Synth. Met. 160 455
[12]	Parvatikar N, Jain S, Khasim S, Revansiddappa M, Bhoraskar S V and Prasad M V N A 2006 Sensor and Actuators B 114 599
[13]	Pandey M, Srivastava A, Srivastava A and Shukla R K 2010 Sensors & Transducers Journal 119-2 33
[14]	Karimov K S, Sayyad M H, Ali M, Khan M N, Moiz S A, Khan K B, Farah H and Karieva Z M 2006 J. Power Sources. 155 475
[15]	Karimov K S, Sayyad M H, Ahmed M M, Khan M N, Karieva Z M, Moiz S A, Shah M, Zakaullah K and Turaeva M A 2004 Euras. Chem. Tech. J. 6 145
[16]	Ahmed M M, Karimov K S and Moiz S A 2008 Thin Solid Films 516 7822
[17]	Moiz S A, Ahmed M M and Karimov K S 2005 Jpn. J. App. Phys. 44-3 1199
[18]	Irwin J D 1999 Basic Engineering Circuit Analysis (6th edn.) (New York: John Wiley & Sons)
[19]	Wan M, Huang J and Shen Y 1999 Synth. Met. 101 708
[20]	Sun A, Li Z, Wei T, Li Y and Cui P 2009 Sensor and Actuators B 142 197
[21]	Vilkman M, Lehtinen K, Makela T, Rannou P and Ikkala O 2010 Org. Electron. 11 472
[22]	Sze S M 1985 Semiconductor Devices: Physics and Technology (New York: Wiley)
[23]	Omar M A 2002 Elementary Solid State Physics: Principles and Applications (Singapore: Pearson Education Pte. Ltd.)
[24]	Neamen D A 1992 Semiconductor Physics and Devices: Basic Principles (Boston: Richard D. Irwin Inc.)
[25]	Croft A, Davison R and Hargreaves M 1993 Engineering Mathematics, A Modern Foundation for Electronic, Electrical and Control Engineers (London: Addison-Wesley Publishing Company)
[26]	Irvine R G 1994 Operational Amplifiers Characteristics and Applications (3rd edn.) (New Jersey: Prentice Hall)
[27]	Amy F, Chan C and Kahn A 2005 Org. Electron. 6 85
[28]	Iwamoto M and Manaka T 2005 Proc. Int. Symp. IPAP Conf. Series 6 63
[29]	Boguslavsky S N and Vannikov V V 1968 Organic Semiconductors (Moscow: V.A. Kargin, Nauka)
[30]	Karimov K S, Akhmedov K, Qazi I and Khan T A 2007 J. Optoelectron. Advanced Materials 9 2867

Orange dye–polyaniline composite based impedance humidity sensors

Orange dye–polyaniline composite based impedance humidity sensors

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