Doctor-bladed Cu2ZnSnS4 light absorption layer for low-cost solar cell application

doi:10.1088/1674-1056/21/3/038401

中国物理B ›› 2012, Vol. 21 ›› Issue (3): 38401-038401.doi: 10.1088/1674-1056/21/3/038401

陈勤妙¹ ²,李振庆¹ ²,倪一²,程抒一²,窦晓鸣¹ ² ³

收稿日期:2011-04-29 修回日期:2011-10-23 出版日期:2012-02-15 发布日期:2012-02-15
通讯作者: 窦晓鸣,xm.dou@yahoo.com.cn E-mail:xm.dou@yahoo.com.cn

Doctor-bladed Cu₂ZnSnS₄ light absorption layer for low-cost solar cell application

Chen Qin-Miao(陈勤妙)^a)b), Li Zhen-Qing(李振庆)^a)b), Ni Yi(倪一)^b), Cheng Shu-Yi(程抒一)^b), and Dou Xiao-Ming(窦晓鸣)^a)b)c)

a. Department of Physics, Shanghai Jiao Tong University, Shanghai 200240, China;
b. School of Optical-Electrical and Computer Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China;
c. Consolidated Research Institute for Advanced Science and Medical Care, Waseda University, 513 Wasedatsurumaki-cho, Shinjuku-ku, Tokyo 162-0041, Japan

Received:2011-04-29 Revised:2011-10-23 Online:2012-02-15 Published:2012-02-15
Contact: Dou Xiao-Ming,xm.dou@yahoo.com.cn E-mail:xm.dou@yahoo.com.cn
Supported by:
.

摘要/Abstract

Abstract: The doctor-blade method is investigated for the preparation of Cu₂ZnSnS₄ films for low-cost solar cell application. Cu₂ZnSnS₄ precursor powder, the main raw material for the doctor-blade paste, is synthesized by a simple ball-milling process. The doctor-bladed Cu₂ZnSnS₄ films are annealed in N₂ ambient under various conditions and characterized by X-ray diffraction, ultraviolent/vis spectrophotometry, scanning electron microscopy, and current-voltage (J-V) meansurement. Our experimental results indicate that (i) the X-ray diffraction peaks of the Cu₂ZnSnS₄ precursor powder each show a red shift of about 0.4°; (ii) the high-temperature annealing process can effectively improve the crystallinity of the doctor-bladed Cu₂ZnSnS₄, whereas an overlong annealing introduces defects; (iii) the band gap value of the doctor-bladed Cu₂ZnSnS₄ is around 1.41 eV; (iv) the short-circuit current density, the open-circuit voltage, the fill factor, and the efficiency of the best Cu₂ZnSnS₄ solar cell obtained with the superstrate structure of fluorine-doped tin oxide glass/TiO₂/In₂S₃/Cu₂ZnSnS₄/Mo are 7.82 mA/cm², 240 mV, 0.29, and 0.55%, respectively.

Key words: Cu₂ZnSnS₄, non-vacuum process, mechanochemical ball-milling process, doctor-blade method

中图分类号: (Photoelectric conversion)

84.60.Jt

88.40.H- (Solar cells (photovoltaics)) 88.40.hm (Cost of production of solar cells)

陈勤妙, 李振庆, 倪一, 程抒一, 窦晓鸣. [J]. 中国物理B, 2012, 21(3): 38401-038401.

Chen Qin-Miao(陈勤妙), Li Zhen-Qing(李振庆), Ni Yi(倪一), Cheng Shu-Yi(程抒一), and Dou Xiao-Ming(窦晓鸣) . Doctor-bladed Cu₂ZnSnS₄ light absorption layer for low-cost solar cell application[J]. Chin. Phys. B, 2012, 21(3): 38401-038401.

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