Synthesis and characterization of a single diamond crystal with a high nitrogen concentration

doi:10.1088/1674-1056/21/3/038103

中国物理B ›› 2012, Vol. 21 ›› Issue (3): 38103-038103.doi: 10.1088/1674-1056/21/3/038103

张壮飞,贾晓鹏,刘晓兵,胡美华,李勇,颜丙敏,马红安

收稿日期:2011-09-12 修回日期:2011-10-28 出版日期:2012-02-15 发布日期:2012-02-15
通讯作者: 马红安,maha@jlu.edu.cn E-mail:maha@jlu.edu.cn

Synthesis and characterization of a single diamond crystal with a high nitrogen concentration

Zhang Zhuang-Fei(张壮飞), Jia Xiao-Peng(贾晓鹏), Liu Xiao-Bing(刘晓兵), Hu Mei-Hua(胡美华), Li Yong(李勇), Yan Bing-Min(颜丙敏), and Ma Hong-An(马红安)^†

National Laboratory of Superhard Materials, Jilin University, Changchun 130012, China

Received:2011-09-12 Revised:2011-10-28 Online:2012-02-15 Published:2012-02-15
Contact: Ma Hong-An,maha@jlu.edu.cn E-mail:maha@jlu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 51172089) and the Program for New Century Excellent Talents in University, China.

摘要/Abstract

Abstract: In this paper, we explore diamond synthesis with a series of experiments using an Fe-Ni catalyst and a P₃N₅ additive in the temperature range of 1250-1550 ℃ and the pressure range of 5.0-6.3 GPa. We also investigate the influence of nitrogen on diamond crystallization. Our results show that the synthesis conditions (temperature and pressure) increase with the amount of P₃N₅additive increasing. The nitrogen impurity can significantly influence the diamond morphology. The diamonds stably grow into strip and lamellar shapes in the nitrogen-rich environment. The Fourier-transform infrared spectrum shows that the nitrogen concentration increases rapidly with the content of P₃N₅additive increasing. By spectrum analysis, we find that with the increase of the nitrogen concentration, the Ib-type nitrogen atoms can aggregate in the A-centre form. The highest A-centre nitrogen concentration is approximately 840 ppm.

Key words: characterization, morphology, diamond, nitrogen concentration

中图分类号: (Growth from melts; zone melting and refining)

81.10.Fq

61.72.S- (Impurities in crystals) 64.70.dg (Crystallization of specific substances) 07.57.Ty (Infrared spectrometers, auxiliary equipment, and techniques)

张壮飞, 贾晓鹏, 刘晓兵, 胡美华, 李勇, 颜丙敏, 马红安. [J]. 中国物理B, 2012, 21(3): 38103-038103.

Zhang Zhuang-Fei(张壮飞), Jia Xiao-Peng(贾晓鹏), Liu Xiao-Bing(刘晓兵), Hu Mei-Hua(胡美华), Li Yong(李勇), Yan Bing-Min(颜丙敏), and Ma Hong-An(马红安) . Synthesis and characterization of a single diamond crystal with a high nitrogen concentration[J]. Chin. Phys. B, 2012, 21(3): 38103-038103.

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