Solar cells based on the poly(N-vinylcarbazole):porphyrin: tris(8-hydroxyquinolinato) aluminium blend system

doi:10.1088/1674-1056/20/3/038401

中国物理B ›› 2011, Vol. 20 ›› Issue (3): 38401-038401.doi: 10.1088/1674-1056/20/3/038401

Solar cells based on the poly(N-vinylcarbazole):porphyrin: tris(8-hydroxyquinolinato) aluminium blend system

赵谡玲¹, 徐征¹, 刘晓东¹, 孔超¹, 徐叙瑢¹, 张天慧², 朴玲钰³, 鞠思婷³

(1)Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China; (2)Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China;National Center of Nanoscience and Technology, Beijing 100190, China; (3)National Center of Nanoscience and Technology, Beijing 100190, China

收稿日期:2010-07-30 修回日期:2010-10-17 出版日期:2011-03-15 发布日期:2011-03-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 60978060 and 50602008), the Beijing Municipal Science & Technology Commission (Grant No. Z090803044009001), and the Excellent Doctor's Science and Technology Innovati

Solar cells based on the poly(N-vinylcarbazole):porphyrin: tris(8-hydroxyquinolinato) aluminium blend system

Zhang Tian-Hui(张天慧)^a)b), Zhao Su-Ling (赵谡玲)^a)†, Piao Ling-Yu(朴玲钰)^b)‡, Xu Zheng(徐征)^a), Ju Si-Ting(鞠思婷)^b), Liu Xiao-Dong(刘晓东)^a), Kong Chao(孔超)^a), and Xu Xu-Rong(徐叙瑢)^a)

^a Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China; ^b National Center of Nanoscience and Technology, Beijing 100190, China

Received:2010-07-30 Revised:2010-10-17 Online:2011-03-15 Published:2011-03-15
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 60978060 and 50602008), the Beijing Municipal Science & Technology Commission (Grant No. Z090803044009001), and the Excellent Doctor's Science and Technology Innovation Foundation of Beijing Jiaotong University of China (Grant No. 141107522).

摘要/Abstract

摘要： Organic solar cells based on poly(N-vinylcarbazole) (PVK): porphyrin: tris (8-hydroxyquinolinato) aluminium (Alq3) blend p-n junction systems have been fabricated in this work. The roles of the different components in the blend system and of the amount of porphyrin have been investigated. The 5, 10, 15, 20--tetraphenylporphyrin (TPP) and 5, 10, 15, 20-tetra(o-chloro)phenylporphyrinato-copper (CuTClPP) are used in the solar cells. The results show that TPP is better than CuTClPP in enhancing the performance of PVK:Alq3 solar cells. When the weight ratio of PVK:TPP:Alq3 is 1:1.5:1, the best performance of solar cell is obtained. The open circuit voltage (V_oc) is 0.87 V, and the short circuit current (J_sc) is 17.5 μA·cm^{- 2}. In the ternary bulk hereojunction system, the device may be regarded as a cascade of three devices of PVK:TPP, TPP:Alq3 and PVK:Alq3. PVK, TPP and Alq3 can improve the hole mobility, light absorption intensity and electron mobility of the ternary bulk hereojunction system, respectively.

关键词: organic solar cell, porphyrin, ternary blend system

Abstract: Organic solar cells based on poly(N-vinylcarbazole) (PVK): porphyrin: tris (8-hydroxyquinolinato) aluminium (Alq3) blend p-n junction systems have been fabricated in this work. The roles of the different components in the blend system and of the amount of porphyrin have been investigated. The 5, 10, 15, 20--tetraphenylporphyrin (TPP) and 5, 10, 15, 20-tetra(o-chloro)phenylporphyrinato-copper (CuTClPP) are used in the solar cells. The results show that TPP is better than CuTClPP in enhancing the performance of PVK:Alq3 solar cells. When the weight ratio of PVK:TPP:Alq3 is 1:1.5:1, the best performance of solar cell is obtained. The open circuit voltage (V_oc) is 0.87 V, and the short circuit current (J_sc) is 17.5 μA·cm^{- 2}. In the ternary bulk hereojunction system, the device may be regarded as a cascade of three devices of PVK:TPP, TPP:Alq3 and PVK:Alq3. PVK, TPP and Alq3 can improve the hole mobility, light absorption intensity and electron mobility of the ternary bulk hereojunction system, respectively.

Key words: organic solar cell, porphyrin, ternary blend system

中图分类号: (Photoelectric conversion)

84.60.Jt

88.40.-j (Solar energy) 88.40.jr (Organic photovoltaics) 78.56.-a (Photoconduction and photovoltaic effects)

张天慧, 赵谡玲, 朴玲钰, 徐征, 鞠思婷, 刘晓东, 孔超, 徐叙瑢. Solar cells based on the poly(N-vinylcarbazole):porphyrin: tris(8-hydroxyquinolinato) aluminium blend system[J]. 中国物理B, 2011, 20(3): 38401-038401.

Zhang Tian-Hui(张天慧), Zhao Su-Ling (赵谡玲), Piao Ling-Yu(朴玲钰), Xu Zheng(徐征), Ju Si-Ting(鞠思婷), Liu Xiao-Dong(刘晓东), Kong Chao(孔超), and Xu Xu-Rong(徐叙瑢). Solar cells based on the poly(N-vinylcarbazole):porphyrin: tris(8-hydroxyquinolinato) aluminium blend system[J]. Chin. Phys. B, 2011, 20(3): 38401-038401.

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Solar cells based on the poly(N-vinylcarbazole):porphyrin: tris(8-hydroxyquinolinato) aluminium blend system

Solar cells based on the poly(N-vinylcarbazole):porphyrin: tris(8-hydroxyquinolinato) aluminium blend system

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