摘要： A three-parameter nonlinear model in nonlinear quantum theory,i.e.,the quantized discrete self trapping equation, has been used to calculate the vibrational energy spectrum, including the overtones and combinations with many excited quanta, of AsH stretches of arsine, AsH₃. The model calculations agree well with experiment and other calculations. It is shown that the dominant feature of the energy spectrum of AsH₃ molecule is a pattern of local mode pairs, and that when n≥4, all the vibrational energies are almost localized on a single AsH bond.

Abstract: A three-parameter nonlinear model in nonlinear quantum theory, i.e., the quantized discrete self trapping equation, has been used to calculate the vibrational energy spectrum, including the overtones and combinations with many excited quanta, of AsH stretches of arsine, AsH₃. The model calculations agree well with experiment and other calculations. It is shown that the dominant feature of the energy spectrum of AsH₃ molecule is a pattern of local mode pairs, and that when n≥4, all the vibrational energies are almost localized on a single AsH bond.

中图分类号:  (Vibrational analysis)

• 33.20.Tp

31.15.-p (Calculations and mathematical techniques in atomic and molecular physics)