Selective excitation of molecular mode in a mixture by femtosecond resonance-enhanced coherent anti-Stokes Raman scattering spectroscopy

doi:10.1088/1674-1056/21/2/027801

中国物理B ›› 2012, Vol. 21 ›› Issue (2): 27801-027801.doi: 10.1088/1674-1056/21/2/027801

贺平¹ ²,李思宁¹,樊荣伟¹,李晓晖¹,夏元钦¹,于欣¹,陈德应¹

收稿日期:2011-03-04 修回日期:2011-04-28 出版日期:2012-01-30 发布日期:2012-01-30
通讯作者: 陈德应,dychen@hit.edu.cn E-mail:dychen@hit.edu.cn

Selective excitation of molecular mode in a mixture by femtosecond resonance-enhanced coherent anti-Stokes Raman scattering spectroscopy

He Ping(贺平)^a)b), Li Si-Ning(李思宁)^a), Fan Rong-Wei(樊荣伟)^a), Li Xiao-Hui(李晓晖)^a), Xia Yuan-Qin(夏元钦)^a), Yu Xin(于欣)^a), and Chen De-Ying(陈德应)^a)^†

a. National Key Laboratory of Science and Technology on Tunable Laser, Institute of Opto-electronics, Harbin Insitute of Technology, Harbin 150080, China;
b. College of Foundation Science, Harbin University of Commerce, Harbin 150028, China

Received:2011-03-04 Revised:2011-04-28 Online:2012-01-30 Published:2012-01-30
Contact: Chen De-Ying,dychen@hit.edu.cn E-mail:dychen@hit.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 60878018 and 61008023), the Natural Scientific Research Innovation Foundation in Harbin Institute of Technology, China (Grant No. HIT.NSRIF.2009009), and the Science and Technology Innovation Foundation, Harbin, China (Grant No. RC2007QN017030).

摘要/Abstract

Abstract: Femtosecond time-resolved coherent anti-Stokes Raman scattering (CARS) spectroscopy is used to investigate gaseous molecular dynamics. Due to the spectrally broad laser pulses, usually poorly resolved spectra result from this broad spectroscopy. However, it can be demonstrated that by the electronic resonance enhancement optimization control a selective excitation of specific vibrational mode is possible. Using an electronically resonance-enhanced effect, iodine molecule specific CARS spectroscopy can be obtained from a mixture of iodine-air at room temperature and a pressure of 1 atm (corresponding to a saturation iodine vapour as low as about 35 Pa). The dynamics on either the electronically excited state or the ground state of iodine molecules obtained is consistent with previous studies (vacuum, heated and pure iodine) in the femtosecond time resolved CARS spectroscopy, showing that an effective method of suppressing the non-resonant CARS background and other interferences is demonstrated.

Key words: ultrafast spectroscopy, coherent anti-Stokes Raman scattering, vibrational analysis, resonance enhancement

中图分类号: (Ultrafast spectroscopy (<1 psec))

78.47.J-

42.65.Dr (Stimulated Raman scattering; CARS) 33.20.Tp (Vibrational analysis) 33.35.+r (Electron resonance and relaxation)

贺平, 李思宁, 樊荣伟, 李晓晖, 夏元钦, 于欣, 陈德应. [J]. 中国物理B, 2012, 21(2): 27801-027801.

He Ping(贺平), Li Si-Ning(李思宁), Fan Rong-Wei(樊荣伟), Li Xiao-Hui(李晓晖), Xia Yuan-Qin(夏元钦), Yu Xin(于欣), and Chen De-Ying(陈德应) . Selective excitation of molecular mode in a mixture by femtosecond resonance-enhanced coherent anti-Stokes Raman scattering spectroscopy[J]. Chin. Phys. B, 2012, 21(2): 27801-027801.

参考文献 30

[1]	Manz J and Woste L 1995 Femtosecond Chemistry (Weinheim Germany, VCH Publishers) p. 916
[2]	Xu J X, Feng Y Y, Sun G J and Dai Z W 2009 Chin. Phys. B 18 3828
[3]	Ma H L 2005 Chin. Phys. 14 511
[4]	Chergui M 1996 Femtochemistry: Ultrafast Chemical and Physical Progress in Molecular Systems (Singapore: World Scientific) p. 134
[5]	Zhang S A, Zhang H, Wang Z G and Sun Z R 2010 Chin. Phys. B 19 043201
[6]	Zewail A H 1994 Femtochemistry: Ultrafast Dynamics of the Chemical Bond (Singapore: World Scientific) p. 915
[7]	Yin J, Yu L Y, Liu X, Wan H, Lin Z Y and Liu H B 2011 Chin. Phys. B 20 014206
[8]	Chen T, Vierheilig A, Waltner P, Heid M, Kiefer W and Materny A 2000 Chem. Phys. Lett. 326 375
[9]	Wang Y H, Peng Y J, He X, Song Y F and Yang Y Q 2009 Chin. Phys. B 18 1463
[10]	Materny A, Chen T, Schmitt M, Siebert T, Vierheilig A, Engel V and Kiefer W 2000 Appl. Phys. B 71 299
[11]	Rahn L A, Zych L J and Mattern P L 1979 Opt. Commun. 30 249
[12]	Fischer D M, Villeneuve M, Vrakking J J and Stolow A 1995 J. Chem. Phys. 102 5566
[13]	Lozovoy V V, Grimberg B I, Brown E J, Pastirkz I and Dantus M 2000 J. Raman Spectrosc. 31 41
[14]	Schmitt M, Knopp G, Materny A and Kiefer W 1997 Chem. Phys. Lett. 270 9
[15]	Xu J X, Feng Y Y, Sun G J and Dai Z W 2009 Chin. Phys. B 18 3828
[16]	Schmitt M, Heid M, Schlucker S and Kiefer W 2002 Biopolymers 67 226
[17]	Apanasevich P A, Kvach V V and Orlovich V A 1989 J. Raman Spectrosc. 20 125
[18]	Karotki A, Drobizhev M, Kruk M, Spangler C, Nichel E, Mamardashvili N and Rebane A 2003 J. Opt. Soc. Am. B bf20 321
[19]	Drobizhev M, Karotki A, Kruk M and Rebane A 2002 Chem. Phys. Lett. bf355 175
[20]	Hanna S F, Kulatilaka W D, Arp Z, Opatrny T, Scully M O, Kuehner J P and Lucht R P 2003 Appl. Phys. Lett. bf83 1887
[21]	Yang B D, Gao J, Liang Q B, Wang J, Zhang T C and Wang J M 2011 Chin. Phys. B 20 044202
[22]	Maeda S, Kamisuki T and Adachi Y 1988 Advances in Non-linear Spectroscopy (New York: Wiley) p. 253
[23]	He P, Fan R W, Xia Y Q, Yu X, Yao Y and Chen D Y 2011 Chin. Phys. Lett. bf28 047804
[24]	Kiefer W and Bernstein H J 1972 J. Mol. Spectrosc. 43 366
[25]	Tellinghuisen J 1973 J. Chem. Phys. 58 2821
[26]	Barrow R E and Yee K K 1973 J. Chem. Soc. Faraday Trans. II 69 684
[27]	Dennis R, O'Keefe and John H 1982 J. Chem. Eng. 27 77
[28]	Rebane A, Drobizhev M, Kruk M, Karotki A, Tehver I and Scully M 2005 J. Mod. Opt. 52 1243
[29]	Averbukh I S and Perelman N 1989 Phys. Lett. A 139 449
[30]	Stolow A, Vrakking M J J and Villeneuve D M 1996 Phys. Rev. A 54 R37

Selective excitation of molecular mode in a mixture by femtosecond resonance-enhanced coherent anti-Stokes Raman scattering spectroscopy

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