Lithium ion batteries cathode material: V2O5

doi:10.1088/1674-1056/ac21be

中国物理B ›› 2022, Vol. 31 ›› Issue (3): 38203-038203.doi: 10.1088/1674-1056/ac21be

Lithium ion batteries cathode material: V₂O₅

Baohe Yuan(袁保合)^†, Xiang Yuan(袁祥), Binger Zhang(张冰儿), Zheng An(安政), Shijun Luo(罗世钧), and Lulu Chen(陈露露)^‡

North China University of Water Resources and Electric Power, Zhengzhou 450011, China

收稿日期:2021-07-10 修回日期:2021-08-19 接受日期:2021-08-27 出版日期:2022-02-22 发布日期:2022-02-17
通讯作者: Baohe Yuan, Lulu Chen E-mail:yuanbaohe@ncwu.edu.cn;chenlulu@ncwu.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51702097 and U1804125) and the Key Scientific and Technological Research Projects of Henan Province, China (Grant No. 202102210222).

Lithium ion batteries cathode material: V₂O₅

Baohe Yuan(袁保合)^†, Xiang Yuan(袁祥), Binger Zhang(张冰儿), Zheng An(安政), Shijun Luo(罗世钧), and Lulu Chen(陈露露)^‡

North China University of Water Resources and Electric Power, Zhengzhou 450011, China

Received:2021-07-10 Revised:2021-08-19 Accepted:2021-08-27 Online:2022-02-22 Published:2022-02-17
Contact: Baohe Yuan, Lulu Chen E-mail:yuanbaohe@ncwu.edu.cn;chenlulu@ncwu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51702097 and U1804125) and the Key Scientific and Technological Research Projects of Henan Province, China (Grant No. 202102210222).

摘要/Abstract

摘要： Among all the known electrode materials, vanadium pentoxide (V₂O₅) has high reversible capacity. It is a very valuable material for research of the complexity, rich structure and morphology. However, it also has some disadvantages, such as poor cycle stability, low discharge voltage, low conductivity and Li⁺ diffusion coefficient. In this regard, researchers have carried out a lot of research, such as using various methods to improve the nanostructures, introducing heterostructures, introducing point defects or cation doping in the crystal structure, etc. The electrochemical performance of V₂O₅ has been significantly improved in reversible capacity, high-rate capacity and long-term cycle stability. In this paper, V₂O₅ based nanostructure with different chemical composition are briefly introduced, and it covers V₂O₅ nanomaterials with different morphology, including 1D nanorods, nanobelts, nanotubes, 2D leaf like nanosheets and other nanosheets, and 3D hollow structures, porous nanostructures, porous eggshell microsphere structures. The composite nanomaterials of V₂O₅ and different carbonaceous supports are also introduced. Finally, the V₂O₅ composite materials doped with cations are discussed. The electrochemical performance of V₂O₅ based electrode can be improved effectively by obtaining appropriate nanostructure and optimized chemical composition.

关键词: lithium ion battery, V₂O₅ nanostructures, electrochemical properties, nanotubes and nanowires

Abstract: Among all the known electrode materials, vanadium pentoxide (V₂O₅) has high reversible capacity. It is a very valuable material for research of the complexity, rich structure and morphology. However, it also has some disadvantages, such as poor cycle stability, low discharge voltage, low conductivity and Li⁺ diffusion coefficient. In this regard, researchers have carried out a lot of research, such as using various methods to improve the nanostructures, introducing heterostructures, introducing point defects or cation doping in the crystal structure, etc. The electrochemical performance of V₂O₅ has been significantly improved in reversible capacity, high-rate capacity and long-term cycle stability. In this paper, V₂O₅ based nanostructure with different chemical composition are briefly introduced, and it covers V₂O₅ nanomaterials with different morphology, including 1D nanorods, nanobelts, nanotubes, 2D leaf like nanosheets and other nanosheets, and 3D hollow structures, porous nanostructures, porous eggshell microsphere structures. The composite nanomaterials of V₂O₅ and different carbonaceous supports are also introduced. Finally, the V₂O₅ composite materials doped with cations are discussed. The electrochemical performance of V₂O₅ based electrode can be improved effectively by obtaining appropriate nanostructure and optimized chemical composition.

Key words: lithium ion battery, V₂O₅ nanostructures, electrochemical properties, nanotubes and nanowires

中图分类号: (Lithium-ion batteries)

82.47.Aa

79.60.Jv (Interfaces; heterostructures; nanostructures) 65.40.gk (Electrochemical properties)

Baohe Yuan(袁保合), Xiang Yuan(袁祥), Binger Zhang(张冰儿), Zheng An(安政), Shijun Luo(罗世钧), and Lulu Chen(陈露露). Lithium ion batteries cathode material: V₂O₅[J]. 中国物理B, 2022, 31(3): 38203-038203.

Baohe Yuan(袁保合), Xiang Yuan(袁祥), Binger Zhang(张冰儿), Zheng An(安政), Shijun Luo(罗世钧), and Lulu Chen(陈露露). Lithium ion batteries cathode material: V₂O₅[J]. Chin. Phys. B, 2022, 31(3): 38203-038203.

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Lithium ion batteries cathode material: V₂O₅

Lithium ion batteries cathode material: V₂O₅

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