On-surface synthesis of one-dimensional carbyne-like nanostructures with sp-carbon

doi:10.1088/1674-1056/ac7f90

中国物理B ›› 2022, Vol. 31 ›› Issue (12): 128101-128101.doi: 10.1088/1674-1056/ac7f90

所属专题： SPECIAL TOPIC — The third carbon: Carbyne with one-dimensional sp-carbon

On-surface synthesis of one-dimensional carbyne-like nanostructures with sp-carbon

Wenze Gao(高文泽), Chi Zhang(张弛), Zheng Zhou(周正), and Wei Xu(许维)^†

Interdisciplinary Materials Research Center, College of Materials Science and Engineering, Tongji University, Shanghai 201804, China

收稿日期:2022-05-06 修回日期:2022-07-06 接受日期:2022-07-08 出版日期:2022-11-11 发布日期:2022-11-19
通讯作者: Wei Xu E-mail:xuwei@tongji.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 22125203 and 21790351).

On-surface synthesis of one-dimensional carbyne-like nanostructures with sp-carbon

Wenze Gao(高文泽), Chi Zhang(张弛), Zheng Zhou(周正), and Wei Xu(许维)^†

Interdisciplinary Materials Research Center, College of Materials Science and Engineering, Tongji University, Shanghai 201804, China

Received:2022-05-06 Revised:2022-07-06 Accepted:2022-07-08 Online:2022-11-11 Published:2022-11-19
Contact: Wei Xu E-mail:xuwei@tongji.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 22125203 and 21790351).

摘要/Abstract

摘要： Carbyne is an infinite one-dimensional carbon chain comprising of sp-hybridized carbons. Due to its high chemical reactivity and extreme instability, the synthesis and structural diversity of carbyne have been much less investigated in the past decades compared to carbon allotropes built with sp² hybridized carbons, such as fullerenes, carbon nanotubes, and graphene. The emerging on-surface synthesis strategy provides an extremely promising approach for the fabrication of novel carbyne-like nanostructures with atomic precision. Herein, we summarize recent exciting progress in the synthesis of carbyne-like nanostructures with one-dimensional sp-carbon on surfaces, including polyynes, cumulenes, and organometallic polyynes. We also point out the scientific challenges and prospects, encouraging scientists to explore the fabrication and characterization of single strands of carbyne in this young and promising research field.

关键词: on-surface synthesis, carbyne, scanning tunneling microscopy, atomic force microscopy

Abstract: Carbyne is an infinite one-dimensional carbon chain comprising of sp-hybridized carbons. Due to its high chemical reactivity and extreme instability, the synthesis and structural diversity of carbyne have been much less investigated in the past decades compared to carbon allotropes built with sp² hybridized carbons, such as fullerenes, carbon nanotubes, and graphene. The emerging on-surface synthesis strategy provides an extremely promising approach for the fabrication of novel carbyne-like nanostructures with atomic precision. Herein, we summarize recent exciting progress in the synthesis of carbyne-like nanostructures with one-dimensional sp-carbon on surfaces, including polyynes, cumulenes, and organometallic polyynes. We also point out the scientific challenges and prospects, encouraging scientists to explore the fabrication and characterization of single strands of carbyne in this young and promising research field.

Key words: on-surface synthesis, carbyne, scanning tunneling microscopy, atomic force microscopy

中图分类号: (Carbon/carbon-based materials)

81.05.U-

82.35.Gh (Polymers on surfaces; adhesion) 68.37.Ef (Scanning tunneling microscopy (including chemistry induced with STM)) 68.37.Ps (Atomic force microscopy (AFM))

Wenze Gao(高文泽), Chi Zhang(张弛), Zheng Zhou(周正), and Wei Xu(许维). On-surface synthesis of one-dimensional carbyne-like nanostructures with sp-carbon[J]. 中国物理B, 2022, 31(12): 128101-128101.

Wenze Gao(高文泽), Chi Zhang(张弛), Zheng Zhou(周正), and Wei Xu(许维). On-surface synthesis of one-dimensional carbyne-like nanostructures with sp-carbon[J]. Chin. Phys. B, 2022, 31(12): 128101-128101.

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On-surface synthesis of one-dimensional carbyne-like nanostructures with sp-carbon

On-surface synthesis of one-dimensional carbyne-like nanostructures with sp-carbon

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