中国物理B ›› 2020, Vol. 29 ›› Issue (6): 65205-065205.doi: 10.1088/1674-1056/ab8204

• PHYSICS OF GASES, PLASMAS, AND ELECTRIC DISCHARGES • 上一篇    下一篇

Determination of activation energy of ion-implanted deuterium release from W-Y2O3

Xue-Feng Wang(王雪峰), Ji-Liang Wu(吴吉良), Qiang Li(李强), Rui-Zhu Yang(杨蕊竹), Zhan-Lei Wang(王占雷), Chang-An Chen(陈长安), Chun-Rong Feng(冯春蓉), Yong-Chu Rao(饶咏初), Xiao-Hong Chen(谌晓洪), Xiao-Qiu Ye(叶小球)   

  1. 1 School of Sciences and Research Center for Advanced Computation, Xihua University, Chengdu 610039, China;
    2 Science and Technology on Surface Physics and Chemistry Laboratory, Mianyang 621907, China
  • 收稿日期:2020-01-06 修回日期:2020-03-05 出版日期:2020-06-05 发布日期:2020-06-05
  • 通讯作者: Xiao-Hong Chen, Xiao-Qiu Ye E-mail:shengxiaohongb@163.com;xiaoqiugood@sina.com
  • 基金资助:
    Project supported by the National Magnetic Confinement Fusion Energy Research Project, Ministry of Science and Technology of China (Grant No. 2015GB109002), the Innovation Fund of Postgraduate, Xihua University, China (Grant No. ycjj2018017), and the National Natural Science Foundation of China (Grant No. 21401173).

Determination of activation energy of ion-implanted deuterium release from W-Y2O3

Xue-Feng Wang(王雪峰)1,2, Ji-Liang Wu(吴吉良)2, Qiang Li(李强)2, Rui-Zhu Yang(杨蕊竹)2, Zhan-Lei Wang(王占雷)2, Chang-An Chen(陈长安)2, Chun-Rong Feng(冯春蓉)1,2, Yong-Chu Rao(饶咏初)2, Xiao-Hong Chen(谌晓洪)1, Xiao-Qiu Ye(叶小球)2   

  1. 1 School of Sciences and Research Center for Advanced Computation, Xihua University, Chengdu 610039, China;
    2 Science and Technology on Surface Physics and Chemistry Laboratory, Mianyang 621907, China
  • Received:2020-01-06 Revised:2020-03-05 Online:2020-06-05 Published:2020-06-05
  • Contact: Xiao-Hong Chen, Xiao-Qiu Ye E-mail:shengxiaohongb@163.com;xiaoqiugood@sina.com
  • Supported by:
    Project supported by the National Magnetic Confinement Fusion Energy Research Project, Ministry of Science and Technology of China (Grant No. 2015GB109002), the Innovation Fund of Postgraduate, Xihua University, China (Grant No. ycjj2018017), and the National Natural Science Foundation of China (Grant No. 21401173).

摘要: The retention and release of deuterium in W-2%Y2O3 composite materials and commercially pure tungsten after they have been implanted by deuterium plasma (flux ~3.71×1021 D/m2·s, energy ~25 eV, and fluence up to 1.3×1026 D/m2) are studied. The results show that the total amount of deuterium released from W-2%Y2O3 is 5.23×1020 D/m2(2.5 K/min), about 2.5 times higher than that from the pure tungsten. Thermal desorption spectra (TDS) at different heating rates (2.5 K/min-20 K/min) reveal that both W and W-2%Y2O3 have two main deuterium trapped sites. For the low temperature trap, the deuterium desorption activation energy is 0.85 eV (grain boundary) in W, while for high temperature trap, the desorption activation energy is 1.57 eV (vacancy) in W and 1.73 eV (vacancy) in W-2%Y2O3.

关键词: metals and alloys, plasma-based ion implantation, thermal desorption, diffusion in solid

Abstract: The retention and release of deuterium in W-2%Y2O3 composite materials and commercially pure tungsten after they have been implanted by deuterium plasma (flux ~3.71×1021 D/m2·s, energy ~25 eV, and fluence up to 1.3×1026 D/m2) are studied. The results show that the total amount of deuterium released from W-2%Y2O3 is 5.23×1020 D/m2(2.5 K/min), about 2.5 times higher than that from the pure tungsten. Thermal desorption spectra (TDS) at different heating rates (2.5 K/min-20 K/min) reveal that both W and W-2%Y2O3 have two main deuterium trapped sites. For the low temperature trap, the deuterium desorption activation energy is 0.85 eV (grain boundary) in W, while for high temperature trap, the desorption activation energy is 1.57 eV (vacancy) in W and 1.73 eV (vacancy) in W-2%Y2O3.

Key words: metals and alloys, plasma-based ion implantation, thermal desorption, diffusion in solid

中图分类号:  (Metals and alloys)

  • 61.82.Bg
52.77.Dq (Plasma-based ion implantation and deposition) 68.43.Vx (Thermal desorption) 66.30.-h (Diffusion in solids)