Study of glass transition kinetics of As2S3 and As2Se3 by ultrafast differential scanning calorimetry

doi:10.1088/1674-1056/28/4/047802

中国物理B ›› 2019, Vol. 28 ›› Issue (4): 47802-047802.doi: 10.1088/1674-1056/28/4/047802

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Study of glass transition kinetics of As₂S₃ and As₂Se₃ by ultrafast differential scanning calorimetry

Fan Zhang(张凡), Yimin Chen(陈益敏), Rongping Wang(王荣平), Xiang Shen(沈祥), Junqiang Wang(王军强), Tiefeng Xu(徐铁峰)

1 Laboratory of Infrared Material and Devices & Key Laboratory of Photoelectric Materials and Devices of Zhejiang Province, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China;
2 Department of Microelectronic Science and Engineering, Faculty of Science, Ningbo University, Ningbo 315211, China;
3 CAS Key Laboratory of Magnetic Materials and Devices & Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences(CAS), Ningbo 315201, China;
4 Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2018-12-27 修回日期:2019-01-29 出版日期:2019-04-05 发布日期:2019-04-05
通讯作者: Yimin Chen, Junqiang Wang E-mail:chenyimin@nbu.edu.cn;jqwang@nimte.ac.cn

Study of glass transition kinetics of As₂S₃ and As₂Se₃ by ultrafast differential scanning calorimetry

Fan Zhang(张凡)¹, Yimin Chen(陈益敏)^1,2, Rongping Wang(王荣平)¹, Xiang Shen(沈祥)¹, Junqiang Wang(王军强)^3,4, Tiefeng Xu(徐铁峰)¹

1 Laboratory of Infrared Material and Devices & Key Laboratory of Photoelectric Materials and Devices of Zhejiang Province, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China;
2 Department of Microelectronic Science and Engineering, Faculty of Science, Ningbo University, Ningbo 315211, China;
3 CAS Key Laboratory of Magnetic Materials and Devices & Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences(CAS), Ningbo 315201, China;
4 Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Received:2018-12-27 Revised:2019-01-29 Online:2019-04-05 Published:2019-04-05
Contact: Yimin Chen, Junqiang Wang E-mail:chenyimin@nbu.edu.cn;jqwang@nimte.ac.cn

摘要/Abstract

摘要：

Ultrafast differential scanning calorimetry (DSC) was employed to investigate the glass transition kinetics of As₂S₃ and As₂Se₃. By using the Arrhenius method, a fragility index of~22 can be estimated in both As₂S₃ and As₂Se₃. However, when the scanning rate is more than 200 K…^-1, non-Arrhenius behavior can be observed in such “strong” liquids where the Vogel-Fulcher method is more accurate to describe the glass transition kinetics. The fragilities of As₂S₃ and As₂Se₃ glasses are thus extrapolated as 28.3±1.94 and 23.7±1.80, respectively. This indicates that, As₂Se₃ glass has a better structural stability and it is a better candidate for device applications.

关键词: ultrafast DSC, glass transition kinetics, fragility index

Abstract:

Key words: ultrafast DSC, glass transition kinetics, fragility index

中图分类号: (Amorphous materials; glasses and other disordered solids)

78.55.Qr

64.70.P- (Glass transitions of specific systems) 61.43.Fs (Glasses)

张凡, 陈益敏, 王荣平, 沈祥, 王军强, 徐铁峰. Study of glass transition kinetics of As₂S₃ and As₂Se₃ by ultrafast differential scanning calorimetry[J]. 中国物理B, 2019, 28(4): 47802-047802.

Fan Zhang(张凡), Yimin Chen(陈益敏), Rongping Wang(王荣平), Xiang Shen(沈祥), Junqiang Wang(王军强), Tiefeng Xu(徐铁峰). Study of glass transition kinetics of As₂S₃ and As₂Se₃ by ultrafast differential scanning calorimetry[J]. Chin. Phys. B, 2019, 28(4): 47802-047802.

参考文献 25

[1]	Qiao J C, Wang Q, Crespo D, Yang Y and Pelletier J M 2017 Chin. Phys. B 26 016402 doi: 10.1088/1674-1056/26/1/016402
[2]	Angell C A 1995 Science 267 1924 doi: 10.1126/science.267.5206.1924
[3]	Wang L M, Velikov V and Angell C A 2002 J. Chem. Phys. 117 10184 doi: 10.1063/1.1517607
[4]	Böhmer R, Ngai K L, Angell C A and Plazek D J 1993 J. Chem. Phys. 99 4201 doi: 10.1063/1.466117
[5]	Evenson Z, Schmitt T, Nicola M, Gallino I and Busch R 2012 Acta Mater. 60 4712 doi: 10.1016/j.actamat.2012.05.019
[6]	Mauro J C, Yue Y, Ellison A J, Gupta P K and Allan D C 2009 Proc. Natl. Acad. Sci. USA 106 19780 doi: 10.1073/pnas.0911705106
[7]	Orava J, Greer A L, Gholipour B, Hewak D W and Smith C E 2012 Nat. Mater. 11 279 doi: 10.1038/nmat3275
[8]	Orava J, Hewak D W and Greer A L 2015 Adv. Function. Mater. 25 4851 doi: 10.1002/adfm.201501607
[9]	Chen Y, Wang G, Song L, Shen X, Wang J, Huo J, Wang R, Xu T, Dai S and Nie Q 2017 Crystal Growth & Design 17 3687 doi: al Growth
[10]	Chen Y, Pan H, Mu S, Wang G, Wang R, Shen X, Wang J, Dai S and Xu T 2019 Acta Mater. 164 473 doi: 10.1016/j.actamat.2018.10.051
[11]	Şahin H M, Kocatepe K, KayıkcıR and Akar N 2006 Energy Convers. & Manag. 47 19 doi: y Convers.
[12]	Kim S W, Yu H, Kang C H, Lee S H and Kim J C 2004 Int. J. Thermophys. 25 1505 doi: 10.1007/s10765-004-5755-8
[13]	González-Romero R L, Antonelli A, Chaves A S and Meléndez J J 2018 Phys. Chem. Chem. Phys. 20 1809 doi: 10.1039/C7CP07242B
[14]	Ke H B, Wen P and Wang W H 2012 AIP Adv. 2 041404 doi: 10.1063/1.4773224
[15]	Espeau P, Tamarit J L, Barrio M, López D, Perrin M, Allouchi H and Céolin R 2006 Chem. Mater. 18 3821 doi: 10.1021/cm060090s
[16]	Street R A and Yoffe A D 1972 Journal of Non-Crystalline Solids 8-10 745 doi: 10.1016/0022-3093(72)90222-0
[17]	Blachnik R and Hoppe A 1979 J. Non-Cryst. Solids 34 191 doi: 10.1016/0022-3093(79)90035-8
[18]	Chen P, Holbrook C, Boolchand P, Georgiev D, Jackson K and Micoulaut M 2008 Phys. Rev. B 78 224208 doi: 10.1103/PhysRevB.78.224208
[19]	Chen Y, Mu S, Wang G, Shen X, Wang J, Dai S, Xu T, Nie Q and Wang R 2017 Appl. Phys. Express 10 105601 doi: 10.7567/APEX.10.105601
[20]	Bi Q L and Lü Y J 2014 Chin. Phys. Lett. 31 106401 doi: 10.1088/0256-307X/31/10/106401
[21]	Zhang B, Wang R, Zhao D, Pan M and Wang W 2004 Phys. Rev. B 70 224208 doi: 10.1103/PhysRevB.70.224208
[22]	Brüning R and Samwer K 1992 Phys. Rev. B 46 11318 doi: 10.1103/PhysRevB.46.11318
[23]	Málek J and Shánělová J 2005 J. Non-Cryst. Solids 351 3458 doi: 10.1016/j.jnoncrysol.2005.09.004
[24]	Brazhkin V V, Kanzaki M, Funakoshi K and Katayama Y 2009 Phys. Rev. Lett. 102 115901 doi: 10.1103/PhysRevLett.102.115901
[25]	Qiao A, Wang P, Tao H and Yue Y 2018 J. Non-Cryst. Solids 500 225 doi: 10.1016/j.jnoncrysol.2018.08.003

Study of glass transition kinetics of As₂S₃ and As₂Se₃ by ultrafast differential scanning calorimetry

Study of glass transition kinetics of As₂S₃ and As₂Se₃ by ultrafast differential scanning calorimetry

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 25

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Tzu-Chia Chen, Mahyuddin KM Nasution, Abdullah Hasan Jabbar, Sarah Jawad Shoja, Waluyo Adi Siswanto, Sigiet Haryo Pranoto, Dmitry Bokov, Rustem Magizov, Yasser Fakri Mustafa, A. Surendar, Rustem Zalilov, Alexandr Sviderskiy, Alla Vorobeva, Dmitry Vorobyev, and Ahmed Alkhayyat. Effect of spatial heterogeneity on level of rejuvenation in Ni₈₀P₂₀ metallic glass[J]. 中国物理B, 2022, 31(9): 96401-096401.
[2]	Gui-Rong Liu(刘桂榕), Xiao-Dong Chen(陈晓东), Hong-Gang Liu(刘红刚), Yan Wang(王琰), Min Sun(孙敏), Na Yan(闫娜), Qi Qian(钱奇), and Zhong-Min Yang(杨中民). Radiation resistance property of barium gallo-germanate glass doped by Nb₂O₅[J]. 中国物理B, 2022, 31(2): 27801-027801.
[3]	张潇予, 陈飞飞, 章向华, 季伟. Research progress of third-order optical nonlinearity of chalcogenide glasses[J]. 中国物理B, 2018, 27(8): 84208-084208.
[4]	韦宁宁, 杨振, 潘宏波, 张凡, 刘永兴, 王荣平, 沈祥, 戴世勋, 聂秋华. Variable angle spectroscopic ellipsometry and its applications in determining optical constants of chalcogenide glasses in infrared[J]. 中国物理B, 2018, 27(6): 67802-067802.
[5]	王金华, 李泽朋, 刘波, 刘冰冰. Local microstructural analysis for Y₂O₃/Eu³⁺/Mg²⁺ nanorods by Raman and photoluminescence spectra under high pressure[J]. 中国物理B, 2017, 26(2): 26101-026101.
[6]	乔吉超, Q Wang, D Crespo, 杨勇, J M Pelletier. Secondary relaxation and dynamic heterogeneity in metallic glasses: A brief review[J]. 中国物理B, 2017, 26(1): 16402-016402.
[7]	沈艳娇, 陈剑辉, 杨静, 陈兵兵, 陈静伟, 李峰, 代秀红, 刘海旭, 许颖, 麦耀华. Control of epitaxial growth at a-Si: H/c-Si heterointerface by the working pressure in PECVD[J]. 中国物理B, 2016, 25(11): 118801-118801.
[8]	林社宝, 王鹏飞, 佘江波, 郭海涛, 许慎诺, 于成龙, 刘春晓, 彭波. Spectroscopic properties of Yb³⁺-doped TeO₂-BaO-BaF₂-Nb₂O₅-based oxyfluoride tellurite glasses[J]. , 2014, 23(9): 97801-097801.
[9]	于威, 王新占, 戴万雷, 路万兵, 刘玉梅, 傅广生. Surface plasmon enhanced photoluminescence in amorphous silicon carbide films by adjusting Ag island film sizes[J]. 中国物理B, 2013, 22(5): 57804-057804.
[10]	谷月, 晁月盛, 张艳辉. Soft magnetic properties of amorphous Fe₅₂Co₃₄Hf₇B₆Cu₁ alloy treated by pulsed magnetic field and annealing[J]. Chin. Phys. B, 2012, 21(12): 127805-127805.
[11]	田华, 刘技文, 仇坤, 宋俊, 王达健. Color-converted remote phosphor prototype of multiwavelength excitable borosilicate glass for white light-emitting diodes[J]. 中国物理B, 2012, 21(9): 98504-098504.
[12]	李成仁, 李淑凤, 董斌, 孙景昌, 卜晓峰, 范旭楠. Intense up-conversion emissions of Yb³⁺/Dy³⁺ co-doped Al₂O₃ nanopowders prepared by non-aqueous sol–gel method[J]. 中国物理B, 2012, 21(9): 97803-097803.
[13]	郑涛, 秦杰明, 蒋大勇, 吕景文, 肖生春. [J]. 中国物理B, 2012, 21(4): 43302-043302.
[14]	向霞, 郑万国, 袁晓东, 戴威, 蒋勇, 李熙斌, 王海军, 吕海兵, 祖小涛. Irradiation effects of CO₂ laser parameters on surface morphology of fused silica[J]. 中国物理B, 2011, 20(4): 44208-044208.
[15]	李成仁, 李淑凤, 董斌, 程宇琪, 殷海涛, 杨静, 陈宇. Optical parameters of Nd³⁺:Er³⁺:Yb³⁺ co-doped borosilicate glasses and their energy transfers at high temperature[J]. 中国物理B, 2011, 20(1): 17803-017803.