中国物理B ›› 2018, Vol. 27 ›› Issue (4): 48201-048201.doi: 10.1088/1674-1056/27/4/048201
• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇 下一篇
Guang-Chao Yin(尹广超), Guo-Dong Zhao(赵国栋), Hong Yin(殷红), Fu-Chao Jia(贾福超), Qiang Jing(景强), Sheng-Gui Fu(付圣贵), Mei-Ling Sun(孙美玲), Wei Gao(高伟)
Guang-Chao Yin(尹广超)1, Guo-Dong Zhao(赵国栋)1, Hong Yin(殷红)2, Fu-Chao Jia(贾福超)1, Qiang Jing(景强)1, Sheng-Gui Fu(付圣贵)1, Mei-Ling Sun(孙美玲)1, Wei Gao(高伟)2
摘要:
In the present study, high-quality apatite-type La9.33Ge6O26 powders are successfully synthesized by a facile molten-salt synthesis method (MSSM) at low temperatures, using LiCl, LiCl/NaCl mixture (mass ratio 1:1) as molten salt, respectively. Experimental results indicate that the optimal mass ratio between reactant and molten salt is 1:2, and LiCl/NaCl mixed molten-salt is more beneficial for forming high-quality La9.33Ge6O26 powders than LiCl individual molten-salt. Comparing with the conventional solid-state reaction method (SSRM), the synthesis temperature of apatite-type La9.33Ge6O26 powders using the MSSM decreases more than 350℃, which can effectively avoid Ge loss in the preparation process of precursor powders. Furthermore, the powders obtained by the MSSM are homogeneous, non-agglomerated and well crystallized, which are very favorable for gaining dense pellets in the premise of avoiding Ge loss. On the basis of high-quality precursor powders, the dense and pure ceramic pellets of La9.33Ge6O26 are gained at a low temperature of 1100℃ for 2 h, which exhibit higher conductivities (σ 850℃(LiCl)=2.3×10-2 S·cm-1, σ 850℃(LiCl/NaCl)=4.9×10-2 S·cm-1) and lower activation energies (Ea(LiCl)=1.02 eV, Ea(LiCl/NaCl)=0.99 eV) than that synthesized by the SSRM.
中图分类号: (Solid-oxide fuel cells (SOFC))