中国物理B ›› 2017, Vol. 26 ›› Issue (9): 94208-094208.doi: 10.1088/1674-1056/26/9/094208

• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇    下一篇

Structural deformation of nitro group of nitromethane molecule in liquid phase in an intense femtosecond laser field

Chang Wang(王畅), Hong-lin Wu(吴红琳), Yun-fei Song(宋云飞), Yan-qiang Yang(杨延强)   

  1. 1 College of Science, Heilongjiang Bayi Agricultural University, Daqing 163319, China;
    2 Department of Physics, Harbin Institute of Technology, Harbin 150001, China;
    3 National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, China Academy of Engineering Physics, Mianyang 621900, China
  • 收稿日期:2016-11-29 修回日期:2017-04-08 出版日期:2017-09-05 发布日期:2017-09-05
  • 通讯作者: Yan-qiang Yang E-mail:yqyang@hit.edu.cn
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant Nos. 21673211 and 21203047), the Foundation of Heilongjiang Bayi Agricultural University, China (Grant No. XZR2014-16), and the Science Challenging Program of China (Grant No. JCKY2016212A501).

Structural deformation of nitro group of nitromethane molecule in liquid phase in an intense femtosecond laser field

Chang Wang(王畅)1,2, Hong-lin Wu(吴红琳)3, Yun-fei Song(宋云飞)3, Yan-qiang Yang(杨延强)2,3   

  1. 1 College of Science, Heilongjiang Bayi Agricultural University, Daqing 163319, China;
    2 Department of Physics, Harbin Institute of Technology, Harbin 150001, China;
    3 National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, China Academy of Engineering Physics, Mianyang 621900, China
  • Received:2016-11-29 Revised:2017-04-08 Online:2017-09-05 Published:2017-09-05
  • Contact: Yan-qiang Yang E-mail:yqyang@hit.edu.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant Nos. 21673211 and 21203047), the Foundation of Heilongjiang Bayi Agricultural University, China (Grant No. XZR2014-16), and the Science Challenging Program of China (Grant No. JCKY2016212A501).

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摘要： The structural deformation of NO2 group induced by an intense femtosecond laser field of liquid nitromethane (NM) molecule is detected by time- and frequency-resolved coherent anti-Stokes Raman spectroscopy (CARS) technique with the intense pump laser. Here, we present the mechanism of molecular alignment and deformation. The CARS spectra and its FFT spectra of liquid NM show that the NO2 torsional mode couples with the CN symmetric stretching mode and that the NO2 group undergoes ultrafast structural deformation with a relaxation time of 195 fs. The frequency of the NO2 torsional mode in liquid NM (50.8±0.3 cm-1) at room temperature is found. Our results prove the structural deformation of two groups in liquid NM molecule occur simultaneously in the intense laser field.

关键词: coherent anti-Stokes Raman spectroscopy (CARS) spectra, structural deformation, intense laser field, liquid nitromethane

Abstract: The structural deformation of NO2 group induced by an intense femtosecond laser field of liquid nitromethane (NM) molecule is detected by time- and frequency-resolved coherent anti-Stokes Raman spectroscopy (CARS) technique with the intense pump laser. Here, we present the mechanism of molecular alignment and deformation. The CARS spectra and its FFT spectra of liquid NM show that the NO2 torsional mode couples with the CN symmetric stretching mode and that the NO2 group undergoes ultrafast structural deformation with a relaxation time of 195 fs. The frequency of the NO2 torsional mode in liquid NM (50.8±0.3 cm-1) at room temperature is found. Our results prove the structural deformation of two groups in liquid NM molecule occur simultaneously in the intense laser field.

Key words: coherent anti-Stokes Raman spectroscopy (CARS) spectra, structural deformation, intense laser field, liquid nitromethane

中图分类号:  (Stimulated Raman scattering; CARS)

  • 42.65.Dr
33.20.Vq (Vibration-rotation analysis) 61.25.Em (Molecular liquids)