中国物理B ›› 2017, Vol. 26 ›› Issue (8): 88204-088204.doi: 10.1088/1674-1056/26/8/088204
• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇 下一篇
Fen Zhang(张芬), Huan-Da Ding(丁欢达), Chao Duan(段超), Shuang-Liang Zhao(赵双良), Chao-Hui Tong(童朝晖)
Fen Zhang(张芬)1, Huan-Da Ding(丁欢达)1, Chao Duan(段超)1, Shuang-Liang Zhao(赵双良)2, Chao-Hui Tong(童朝晖)1
摘要:
Langevin dynamics simulations have been performed to investigate the response of bi-disperse and strong polyacid chains grafted on an electrode to electric fields generated by opposite surface charges on the polyelectrolyte (PE)-grafted electrode and a second parallel electrode. Simulation results clearly show that, under a negative external electric field, the longer grafted PE chains are more strongly stretched than the shorter ones in terms of the relative change in their respective brush heights. Whereas under a positive external electric field, the grafted shorter chains collapse more significantly than the longer ones. It was found that, under a positive external electric field, the magnitude of the total electric force acting on one shorter PE chain is larger than that on one longer PE chain, or vice versa. The effects of smeared and discrete charge distributions of grafted PE chains on the response of PE brushes to external electric fields were also examined.
中图分类号: (Polyelectrolytes)