Review of magnetocaloric effect in perovskite-type oxides

doi:10.1088/1674-1056/22/5/057501

摘要/Abstract

摘要： We survey the magnetocaloric effect in perovskite-type oxides (including doped ABO₃-type manganese oxides, A₃B₂O₇-type two-layered perovskite oxides, and A2B'B''O₆-type ordered double-perovskite oxides). Magnetic entropy changes larger than those of gadolinium can be observed in polycrystalline La_1-xCa_xMnO₃ and alkali-metal (Na or K) doped La_0.8Ca_0.2MnO₃ perovskite-type manganese oxides. The large magnetic entropy change produced by an abrupt reduction of magnetization is attributed to the anomalous thermal expansion at the Curie temperature. Considerable magnetic entropy changes can also be observed in two-layered perovskites La_1.6Ca_1.4Mn₂O₇ and La_2.5-xK_0.5+xMn₂O_7+δ (0 < x < 0.5), and double-perovskite Ba₂Fe_1+xMo_1-xO₆ (0 ≤ x ≤ 0.3) near their respective Curie temperatures. Compared with rare earth metals and their alloys, the perovskite-type oxides are lower in cost, and they exhibit higher chemical stability and higher electrical resistivity, which together favor lower eddy-current heating. They are potential magnetic refrigerants at high temperatures, especially near room temperature.

关键词: perovskite-type oxides, magnetocaloric effect, magnetic entropy change, magnetic phase transition

Abstract: We survey the magnetocaloric effect in perovskite-type oxides (including doped ABO₃-type manganese oxides, A₃B₂O₇-type two-layered perovskite oxides, and A2B'B''O₆-type ordered double-perovskite oxides). Magnetic entropy changes larger than those of gadolinium can be observed in polycrystalline La_1-xCa_xMnO₃ and alkali-metal (Na or K) doped La_0.8Ca_0.2MnO₃ perovskite-type manganese oxides. The large magnetic entropy change produced by an abrupt reduction of magnetization is attributed to the anomalous thermal expansion at the Curie temperature. Considerable magnetic entropy changes can also be observed in two-layered perovskites La_1.6Ca_1.4Mn₂O₇ and La_2.5-xK_0.5+xMn₂O_7+δ (0 < x < 0.5), and double-perovskite Ba₂Fe_1+xMo_1-xO₆ (0 ≤ x ≤ 0.3) near their respective Curie temperatures. Compared with rare earth metals and their alloys, the perovskite-type oxides are lower in cost, and they exhibit higher chemical stability and higher electrical resistivity, which together favor lower eddy-current heating. They are potential magnetic refrigerants at high temperatures, especially near room temperature.

Key words: perovskite-type oxides, magnetocaloric effect, magnetic entropy change, magnetic phase transition

中图分类号: (Magnetocaloric effect, magnetic cooling)

75.30.Sg

75.50.Bb (Fe and its alloys)

钟伟, 区泽棠, 都有为. Review of magnetocaloric effect in perovskite-type oxides[J]. 中国物理B, 2013, 22(5): 57501-057501.

Zhong Wei (钟伟), Au Chak-Tong (区泽棠), Du You-Wei (都有为). Review of magnetocaloric effect in perovskite-type oxides[J]. Chin. Phys. B, 2013, 22(5): 57501-057501.

参考文献 103

[1]	Gschneidner Jr K A and Pecharsky V K 2000 Mater. Sci. Eng. A 287 301
[2]	Gschneidner Jr K A and Pecharsky V K 1999 J. Appl. Phys. 85 5365
[3]	Pecharsky V K, Gschneidner Jr K A and Tsokol A O 2005 Rep. Prog. Phys. 68 1479
[4]	Debye P 1926 Ann. Physik. 386 1154
[5]	Giauque W F 1927 J. Am. Chem. Soc. 49 1870
[6]	Giauque W F and MacDougall D P 1933 Phys. Rev. 43 768
[7]	Barclay J A, Jaeger S R and Prenger F C 1990 Adv. Cryog. Eng. B 35 1097
[8]	Prenger F C, Hill D D, Trueblood J, Servais T, Laatsch J and Barcaly J A 1990 Adv. Cryog. Eng. B 35 1105
[9]	Hashimoto T, Numasawa T, Shino M and Okada T 1981 Cryogenics 21 647
[10]	Brown G V 1976 J. Appl. Phys. 47 3673
[11]	Pecharsky V K and Gschneidner Jr K A 1997 Phys. Rev. Lett. 78 4494
[12]	Pecharsky V K and Gschneidner Jr K A 1997 Appl. Phys. Lett. 70 3299
[13]	Hu F X, Shen B G and Sun J R 2000 Appl. Phys. Lett. 76 3460
[14]	Hu F X, Shen B G, Sun J R and Wu G H 2001 Phys. Rev. B 64 132412
[15]	Wada H and Tanabe Y 2001 Appl. Phys. Lett. 79 3302
[16]	Fujieda S, Fujita A and Fukamichi K 2002 Appl. Phys. Lett. 81 1276
[17]	Tegus O, Bruck E, Buschow K H J and de Boer F R 2002 Nature 415 150
[18]	Kuwahara K, Tomioka Y, Moritomo Y, Asamitsu A, Kasai M, Kumai R and Tokura Y 1996 Science 272 80
[19]	Radaelli P G, Cox D E, Marezio M, Cheong S W, Schiffer P E and Ramirez A P 1995 Phys. Rev. Lett. 75 4488
[20]	Dai P, Zhang J D, Mook H A, Liou S H, Dowben P A and Plummer E W 1996 Phys. Rev. B 54 3694
[21]	Ibara M R, Algarabel P A, Marquina C, Blasco J and García J 1995 Phys. Rev. Lett. 75 3541
[22]	Argyriou D N, Mitchell J F, Potter C D, Hinks D G, Jorgense J D and Bader S D 1996 Phys. Rev. Lett. 76 3826
[23]	Guo Z B, Zhang J R, Huang H, Ding W P and Y W Du 1997 Appl. Phys. Lett. 70 904
[24]	Guo Z B, Du Y W, Zhu J S, Huang H, Ding W P and Feng D 1997 Phys. Rev. Lett. 78 1142
[25]	Von Helmolt R, Wecker J, Holzapfel B, Schultz L and Samwer K 1993 Phys. Rev. Lett. 71 2331
[26]	Jin S, Tiefel T H, McCormack M, Fastnacht R A, Ramesh R and Chen L H 1994 Scicnce 264 413
[27]	Schiffer P, Ramirez A P, Bao W and Cheong S W 1995 Phys. Rev. Lett. 75 3336
[28]	Hwang H Y, Cheong S W, Radaelli P G, Marezio M and Batlogg B 1995 Phys. Rev. Lett. 75 914
[29]	Moritomo Y, Asamitsu A and Tokura Y 1995 Phys. Rev. B 51 16491
[30]	Arnold Z, Kamenev K, Ibarra M R, Algarabel P A, Marquina C, Blasco J and García J 1995 Appl. Phys. Lett. 67 2875
[31]	Kuwahara H, Tomioka Y, Moritomo Y, Asamitsu A, Kasai M, Kumai R and Tokura Y 1996 Science 272 80
[32]	Hashimoto T, Kuzuhara T, Sahashi M, Inomata K, Tomokiyo A and Yayama H 1987 J. Appl. Phys. 62 3873
[33]	Morelli D T, Mance A M, Mantese J V and Micheli A L 1996 J. Appl. Phys. 79 373
[34]	Zhang X X, Tejada J, Xin Y, Sun G F, Wong K W and Bohigas X 1996 Appl. Phys. Lett. 69 3596
[35]	Lin G C, Wei Q and Zhang J X 2006 J. Magn. Magn. Mater. 300 392
[36]	Zhong W, Chen W, Ding W P, Zhang N, Du Y W and Yan Q J 1998 Solid State Commun. 106 55
[37]	Zhong W, Chen W, Ding W P, Zhang N, Hu A, Du Y W and Yan Q J 1998 Eur. Phys. J. B 3 169
[38]	Zhong W, Chen W, Ding W P, Zhang N, Hu A, Du Y W and Yan Q J 1999 J. Magn. Magn. Mater. 195 112
[39]	Tang T, Gu K M, Cao Q Q, Wang D H, Wang S Y, Zhang S Y and Du Y W 2000 J. Magn. Magn. Mater. 222 110
[40]	Zhong W, Chen W, Wang J H and Du Y W 2001 Chin. Phys. Lett. 18 1114
[41]	Damay F, Martin C, Martin A and Raveau B 1997 J. Appl. Phys. 81 1372
[42]	Rodriguez-Martinez L M and Attfield J P 1996 Phys. Rev. B 54 15622
[43]	Akther Hossain A K M, Cohen L F, Kodenkandeth T, MacManus-Driscoll J and McNalford N 1999 J. Magn. Magn. Mater. 195 31
[44]	Abdelmoula N, Guidara K, Cheikh-Rouhou A, Dhahri E and Joubert J C 2000 J. Solid State Chem. 151 139
[45]	Millis A J, Littlewood P B and Shraiman B I 1995 Phys. Rev. Lett. 74 5144
[46]	Zhong W, Chen W, Au C T and Du Y W 2003 J. Magn. Magn. Mater. 261 238
[47]	Hou D L, Bai Y, Xu J, Tang G D and Nie X F 2004 J. Alloys Compd. 384 62
[48]	Phan M H, Yu S C and Hur N H 2003 J. Magn. Magn. Mater. 262 407
[49]	Phan M H, Yu S C, Moon Y M and Hur N H 2004 J. Magn. Magn. Mater. 272-276 E503
[50]	Chen W, Zhong W, Hou D L, Gao R W, Feng W C, Zhu M G and Du Y W 2002 J. Phys. Condens. Mater. 14 11889
[51]	Jia L, Liu G J, Wang J Z, Sun J R, Zhang H W and Shen B G 2006 Appl. Phys. Lett. 89 122515
[52]	Liu G J, Sun J R, Wang J Z and Shen B G 2006 Appl. Phys. Lett. 89 222503
[53]	Liu G J, Sun J R, Wang J Z, Zhao T Y and Shen B G 2007 J. Phys. Condens. Matter 19 466215
[54]	Moritomo Y, Tomioka Y, Asamitsu A, Tokura Y and Matsui Y 1996 Nature 380 141
[55]	Kimura T, Tomioka Y, Kuwahara H, Asamitsu A, Tamura M and Tokura Y 1996 Science 274 1698
[56]	Argyiou D N, Mitchell J F, Goodenough J B, Chmaissem O, Short S and Jorgensen J D 1997 Phys. Rev. Lett. 78 1568
[57]	Mitchell J F, Argyiou D N, Jorgensen J D, Hinks D G, Potter C D and Bader S D 1997 Phys. Rev. B 55 63
[58]	Potter C D, Swiatek M, Bader S D, Argyiou D N, Mitchell J F, Miller D J, Hinks D G and Jorgensen J D 1998 Phys. Rev. B 57 72
[59]	Mahesh R, Wang R and Itoh M 1998 Phys. Rev. B 57 104
[60]	Kimura T, Asamitsu A, Tomioka Y and Tokura Y 1997 Phys. Rev. Lett. 79 3720
[61]	Kimura T, Kumai R, Tokura Y, Li J Q and Matsui Y 1998 Phys. Rev. B 58 11081
[62]	Hayashi T, Miura N, Tokunaga M, Kimura T and Tokura Y 1998 J. Phys.: Condens. Matter 10 11525
[63]	Argyiou D N, Mitchell J F, Radaelli P G, Bordallo H N, Cox D E, Medarde M and Jorgensen J D 1999 Phys. Rev. B 59 8695
[64]	Ling C D, Millburn J E, Mitchell J F, Argyiou D N, Linton J and Bordallo H N 2000 Phys. Rev. B 62 15096
[65]	Suryanarayanan R, Dhalenne G, Revcolevschi A, Prellier W, Renard J P, Dupas C, Caliebe W and Chatterji T 1999 Solid State Commun. 113 267
[66]	Zhong W, Chen W, Jiang H Y, Liu X S, Au C T and Du Y W 2002 Eur. Phys. J. B 30 331
[67]	Zhong W, Liu W, Liu X S, Jiang H Y, Au C T and Du Y W 2003 Phys. Stat. Sol. (a) 195 440
[68]	Zhou T J, Yu Z, Zhong W, Xu X N, Zhang H H and Du Y W 1999 J. Appl. Phys. 85 7975
[69]	Zhu H, Song H and Zhang Y H 2002 Appl. Phys. Lett. 81 3416
[70]	Woodward P, Hoffmann R D and Sleight A W 1994 J. Mater. Res. 9 2118
[71]	Kobayashi K I, Kimura T, Sawada H, Terakura K and Tokura Y 1998 Nature 395 677
[72]	Sarma D D, Mahadevan P, Saha-Dasgupta T, Ray S and Kumar A 2000 Phys. Rev. Lett. 85 2549
[73]	Yanagihara H, Cheong W, Salamon M B, Xu S and Moritomo Y 2002 Phys. Rev. B 65 092411
[74]	Huang Y H, Karppinen M, Yamauchi H and Goodenough J B 2006 Phys. Rev. B 73 104408
[75]	Kobayashi K I, Kimura T, Tomioka Y, Sawada H, Terakura K and Tokura Y 1999 Phys. Rev. B 59 11159
[76]	Kato H, Okuda T, Okimoto Y, Tomioka Y, Oikawa K, Kamiyama T and Tokura Y 2002 Phys. Rev. B 65 144404
[77]	De Teresa J M, Serrate D, Blasco J, Ibarra M R and Morellon L 2004 Phys. Rev. B 69 144401
[78]	Asano H, Kozuka N, Tsuzuki A and Matsui M 2004 Appl. Phys. Lett. 85 263
[79]	Vaitheeswaran G, Kanchana V and Delin A 2005 Appl. Phys. Lett. 86 032513
[80]	Philipp J B, Majewski P, Alff L, Erb A, Gross R, Graf T, Brandt M S, Simon J, Walther T, Mader W, Topwal D and Sarma D D 2003 Phys. Rev. B 68 144431
[81]	Kawanaka H, Hase I, Toyama S and Nishihara Y 2000 Phys. B 281 518
[82]	Moritomo Y, Xu S, Machida A, Akimoto T, Nishibori E, Takata M and Sakata M 2001 Phys. Rev. B 63 144425
[83]	Viola M C, Martinez-Lope M J, Alonso J A, Martinez J L, Paoli J M De, Pagola S, Pedregosa J C, Fernandez-Diaz M T and Carbonio R E 2003 Chem. Mater. 15 1655
[84]	Kuz'min E V, Ovchinnikov S G and Singh D J 2003 Phys. Rev. B 68 024409
[85]	Lindén J, Yamamoto T, Karppinen M and Yamauchi H 2000 Appl. Phys. Lett. 76 2925
[86]	Karppinen M, Yamauchi H, Yasukawa Y, Lindén J, Chan T S, Liu R S and Chen J M 2003 Chem. Mater. 15 4118
[87]	Kang J S, Kim J H, Sekiyama A, Kasai S, Suga S, Han S W, Kim K H, Muro T, Saitoh Y, Hwang C, Olson C G, Park B J, Lee B W, Shim J H, Park J H and Min B I 2002 Phys. Rev. B 66 113105
[88]	Feng X M, Rao G H, Liu G Y, Liu W F, Ouyang Z W and Liang J K 2004 J. Phys.: Condens. Matter 16 1813
[89]	Zhong W, Tang N J, Wu X L, Liu W, Chen W, Jiang H Y and Du Y W 2004 J. Magn. Magn. Mater. 282 151
[90]	Zhong W, Liu W, Au C T, Lv L Y and Du Y W 2006 J. Magn. Magn. Mater. 303 E212
[91]	Zhong W, W Liu, Au C T and Du Y W 2006 Nanotechnology 17 250
[92]	Zhong W, Tang N J, Au C T and Du Y W 2007 IEEE Trans. Mag. 43 3079
[93]	Zhong W, Tang N J, Au C T and Du Y W 2008 J. Nanosci. Nanotechnol. 8 2793
[94]	Ogale A S, Ogale S B, Ramesh R and Venkatesan T 1999 Appl. Phys. Lett. 75 537
[95]	Balcells LI, Navarro J, Bibes M, Roig A, Martínez B and Fontcuberta J 2001 Appl. Phys. Lett. 78 781
[96]	Sakuma H, Taniyama T, Kitamoto Y and Yamazaki Y 2003 J. Appl. Phys. 93 2816
[97]	Lee W Y, Han H, Kim S B, Kim C S and Lee B W 2003 J. Magn. Magn. Mater. 254-255 577
[98]	Tovar M, Causa M T, Butera A, Navarro J, Martínez B, Fontcuberta J and Passeggi M C G 2002 Phys. Rev. B 66 024409
[99]	Serrate D, de Teresa J, Blasco J, Ibarra M, Morellon L and Ritter C 2002 Appl. Phys. Lett. 80 4573
[100]	Navarro J, Fontcuberta J, Izquierdo M, Avila J and Asensio M C 2004 Phys. Rev. B 69 115101
[101]	Frontera C and Fontcuberta J 2004 Phys. Rev. B 69 014406
[102]	Topwal D, Sarma D D, Kato H, Tokura Y and Avignon M 2006 Phys. Rev. B 73 094419
[103]	Kim J, Sung J G, Yang H M and Lee B W 2004 J. Magn. Magn. Mater. 290-291 1009