Self-assembly and growth of manganese phthalocyanine on an Au(111) surface

doi:10.1088/1674-1056/20/9/096401

中国物理B ›› 2011, Vol. 20 ›› Issue (9): 96401-096401.doi: 10.1088/1674-1056/20/9/096401

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Self-assembly and growth of manganese phthalocyanine on an Au(111) surface

姜宇航, 刘立巍, 杨锴, 肖文德, 高鸿钧

Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

收稿日期:2011-05-09 修回日期:2011-05-25 出版日期:2011-09-15 发布日期:2011-09-15

Self-assembly and growth of manganese phthalocyanine on an Au(111) surface

Jiang Yu-Hang(姜宇航), Liu Li-Wei(刘立巍), Yang Kai(杨锴), Xiao Wen-De(肖文德), and Gao Hong-Jun(高鸿钧)^†

Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Received:2011-05-09 Revised:2011-05-25 Online:2011-09-15 Published:2011-09-15

摘要/Abstract

摘要： Self-assembly and growth of manganese phthalocyanine (MnPc) molecules on an Au(111) surface is investigated by means of low-temperature scanning tunneling microscopy. At the initial stage, MnPc molecules preferentially occupy the step edges and elbow sites on the Au(111) surface, then they are separately adsorbed on the face-centered cubic and hexagonal closely packed regions due to a long-range repulsive molecule—molecule interaction. After the formation of a closely packed monolayer, molecular islands with second and third layers are observed.

Abstract: Self-assembly and growth of manganese phthalocyanine (MnPc) molecules on an Au(111) surface is investigated by means of low-temperature scanning tunneling microscopy. At the initial stage, MnPc molecules preferentially occupy the step edges and elbow sites on the Au(111) surface, then they are separately adsorbed on the face-centered cubic and hexagonal closely packed regions due to a long-range repulsive molecule—molecule interaction. After the formation of a closely packed monolayer, molecular islands with second and third layers are observed.

Key words: self-assembly, manganese phthalocyanine, scanning tunneling microscopy

中图分类号: (Self-assembly)

64.75.Yz

68.37.Ef (Scanning tunneling microscopy (including chemistry induced with STM)) 34.35.+a (Interactions of atoms and molecules with surfaces)

姜宇航, 刘立巍, 杨锴, 肖文德, 高鸿钧. Self-assembly and growth of manganese phthalocyanine on an Au(111) surface[J]. 中国物理B, 2011, 20(9): 96401-096401.

Jiang Yu-Hang(姜宇航), Liu Li-Wei(刘立巍), Yang Kai(杨锴), Xiao Wen-De(肖文德), and Gao Hong-Jun(高鸿钧) . Self-assembly and growth of manganese phthalocyanine on an Au(111) surface[J]. Chin. Phys. B, 2011, 20(9): 96401-096401.

参考文献 38

[1]	Barth J V, Costantini G and Kern K 2005 Nature 437 671
[2]	Feng M, Gao L, Deng Z T, Ji W, Guo X F, Du S X, Shi D X, Zhang D Q, Zhu D B and Gao H J 2007 J. Am. Chem. Soc. 129 2204
[3]	Gao H J and Gao L 2010 Prog. Surf. Sci. 85 28
[4]	Wang Y F, Kroger J, Berndt R and Hofer W 2009 Angewandte Chemie-International Edition 48 1261
[5]	Gao H J, Sohlberg K, Xue Z Q, Chen H Y, Hou S M, Ma L P, Fang X W, Pang S J and Pennycook S J 2000 Phys. Rev. Lett. 84 1780
[6]	Cheng Z H, Gao L, Deng Z T, Liu Q, Jiang N, Lin X, He X B, Du S X and Gao H J 2007 J. Phys. Chem. C 111 2656
[7]	Xiao W D, Feng X L, Ruffieux P, Groning O, Mullen K and Fasel R 2008 J. Am. Chem. Soc. 130 8910
[8]	Coe S, Woo W K, Bawendi M and Bulovic V 2002 Nature 420 800
[9]	Cheng Z H, Gao L, Deng Z T, Jiang N, Liu Q, Shi D X, Du S X, Guo H M and Gao H J 2007 J. Phys. Chem. C 111 9240
[10]	Ruffieux P, Palotas K, Groning O, Wasserfallen D, Mullen K, Hofer W A, Groning P and Fasel R 2007 J. Am. Chem. Soc. 129 5007
[11]	Kröger J, Jensen H and Neel N 2007 Surf. Sci. 601 4180
[12]	Nilson K, Ahlund J, Brena B, Gothelid E, Schiessling J, Martensson N and Puglia C 2007 J. Chem. Phys. 127 114702
[13]	Gao L, Ji W, Hu Y B, Cheng Z H, Deng Z T, Liu Q, Jiang N, Lin X, Guo W, Du S X, Hofer W A, Xie X C and Gao H J 2007 Phys. Rev. Lett. 99 106402
[14]	Iancu V, Deshpande A and Hla S W 2006 Nano Lett. bf6 820
[15]	Tsukahara N, Noto K I, Ohara M, Shiraki S, Takagi N, Takata Y, Miyawaki J, Taguchi M, Chainani A, Shin S and Kawai M 2009 Phys. Rev. Lett. 102 167203
[16]	Zhao A D, Li Q X, Chen L, Xiang H J, Wang W H, Pan S, Wang B, Xiao X D, Yang J L, Hou J G and Zhu Q S 2005 Science 309 1542
[17]	Gopakumar T G, Lackinger M, Hackert M, Muller F and Hietschold M 2004 J. Phys. Chem. B 108 7839
[18]	Ahlund J, Schnadt J, Nilson K, Gothelid E, Schiessling J, Besenbacher F, Martensson N and Puglia C 2007 Surf. Sci. 601 3661
[19]	Scarfato A, Chang S H, Kuck S, Brede J, Hoffmann G and Wiesendanger R 2008 Surf. Sci. 602 677
[20]	Lu X, Hipps K W, Wang X D and Mazur U 1996 J. Am. Chem. Soc. 118 7197
[21]	Lu X and Hipps K W 1997 J. Phys. Chem. B 101 5391
[22]	Koudia M, Abel M, Maurel C, Bliek A, Catalin D, Mossoyan M, Mossoyan J C and Porte L 2006 J. Phys. Chem. B 110 10058
[23]	Bai Y, Buchner F, Wendahl M T, Kellner I, Bayer A, Steinruck H P, Marbach H and Gottfried J M 2008 J. Phys. Chem. C 112 6087
[24]	Yokoyama T, Takahashi T, Shinozaki K and Okamoto M 2007 Phys. Rev. Lett. 98 206102
[25]	Karacuban H, Lange M, Schaffert J, Weingart O, Wagner T and Moller R 2009 Surf. Sci. 603 L39
[26]	Mao J H, Zhang H G, Jiang Y H, Pan Y, Gao M, Xiao W D and Gao H J 2009 J. Am. Chem. Soc. 131 14136
[27]	Shi Z L and Lin N 2009 J. Am. Chem. Soc. 131 5376
[28]	Lian J C, Cheng Z H, Jiang Y H, Zhang Y Y, Liu L W, Ji W, Xiao W D, Du S X, Hofer W A and Gao H J 2010 Phys. Rev. B 81 195411
[29]	Gao L, Liu Q, Zhang Y Y, Jiang N, Zhang H G, Cheng Z H, Qiu W F, Du S X, Liu Y Q, Hofer W A and Gao H J 2008 Phys. Rev. Lett. 101 197209
[30]	Yokoyama T, Yokoyama S, Kamikado T, Okuno Y and Mashiko S 2001 Nature 413 619
[31]	Zhang L Z, Cheng Z H, Huan Q, He X B, Lin X, Gao L, Deng Z T, Jiang N, Liu Q, Du S X, Guo H M and Gao H J 2011 J. Phys. Chem. C 115 10791
[32]	Repp J, Moresco F, Meyer G, Rieder K H, Hyldgaard P and Persson M 2000 Phys. Rev. Lett. 85 2981
[33]	Silly F, Pivetta M, Ternes M, Patthey F, Pelz J P and Schneider W D 2004 Phys. Rev. Lett. 92 016101
[34]	Fernandez-Torrente I, Monturet S, Franke K J, Fraxedas J, Lorente N and Pascual J I 2007 Phys. Rev. Lett. 99 176103
[35]	Jiang N, Zhang Y Y, Liu Q, Cheng Z H, Deng Z T, Du S X, Gao H J, Beck M J and Pantelides S T 2010 Nano Lett. 10 1184
[36]	Eaglesham D J and Cerullo M 1990 Phys. Rev. Lett. 64 1943
[37]	Linstead R P and Robertson J M 1936 J. Chem. Soc. 1736
[38]	Cheng Z H, Du S X, Jiang N, Zhang Y Y, Guo W, Hofer W A and Gao H J 2011 Surf. Sci. 605 415

Self-assembly and growth of manganese phthalocyanine on an Au(111) surface

Self-assembly and growth of manganese phthalocyanine on an Au(111) surface

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