Magnetocaloric properties of Nd-doped Gd5Si4 microparticles and nanopowders

doi:10.1088/1674-1056/ad6de7

中国物理B ›› 2024, Vol. 33 ›› Issue (11): 117502-117502.doi: 10.1088/1674-1056/ad6de7

Magnetocaloric properties of Nd-doped Gd₅Si₄ microparticles and nanopowders

Kaiyang Zhang(张凯扬), Huanhuan Wang(王欢欢), Ying Wang(王颖)†, and Tao Wang(王涛)‡

School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China

收稿日期:2024-05-09 修回日期:2024-08-09 接受日期:2024-08-12 出版日期:2024-11-15 发布日期:2024-11-15
基金资助:
Project supported by the Natural Science Foundation of Gansu Province (Grant No. 22JR5RA404).

Magnetocaloric properties of Nd-doped Gd₅Si₄ microparticles and nanopowders

Kaiyang Zhang(张凯扬), Huanhuan Wang(王欢欢), Ying Wang(王颖)†, and Tao Wang(王涛)‡

School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China

Received:2024-05-09 Revised:2024-08-09 Accepted:2024-08-12 Online:2024-11-15 Published:2024-11-15
Contact: Ying Wang, Tao Wang E-mail:yingw@lzu.edu.cn;wtao@lzu.edu.cn
Supported by:
Project supported by the Natural Science Foundation of Gansu Province (Grant No. 22JR5RA404).

摘要/Abstract

摘要： The preparation of materials with enhanced magnetocaloric properties is crucial for magnetic refrigeration. In this study, Nd-doped Gd$_{5}$Si$_{4}$ microparticles and nanomaterials were synthesized using the reduction-diffusion method. The impact of Nd doping with varying compositions on the structure and entropy change properties of the materials was investigated. The Curie temperatures of both the micron- and nano-sized materials ranged from 190 K to 210 K, which were lower than previously reported values. Micron-sized samples doped with 1% Nd exhibited superior magnetocaloric properties, demonstrating a maximum entropy change of 4.98 J$\cdot $kg$^{-1}\cdot $K$^{-1}$ at 5 T, with an entropy change exceeding 4 J$\cdot $kg$^{-1}\cdot $K$^{-1}$ over a wide temperature range of approximately 70 K. Conversely, the nanomaterials had broader entropy change peaks but lower values. All samples exhibited a second-order phase transition, as confirmed by the Arrott plots.

关键词: magnetocaloric, Gd$_{5}$Si$_{4}$, Nd doping, reduction-diffusion method

Abstract: The preparation of materials with enhanced magnetocaloric properties is crucial for magnetic refrigeration. In this study, Nd-doped Gd$_{5}$Si$_{4}$ microparticles and nanomaterials were synthesized using the reduction-diffusion method. The impact of Nd doping with varying compositions on the structure and entropy change properties of the materials was investigated. The Curie temperatures of both the micron- and nano-sized materials ranged from 190 K to 210 K, which were lower than previously reported values. Micron-sized samples doped with 1% Nd exhibited superior magnetocaloric properties, demonstrating a maximum entropy change of 4.98 J$\cdot $kg$^{-1}\cdot $K$^{-1}$ at 5 T, with an entropy change exceeding 4 J$\cdot $kg$^{-1}\cdot $K$^{-1}$ over a wide temperature range of approximately 70 K. Conversely, the nanomaterials had broader entropy change peaks but lower values. All samples exhibited a second-order phase transition, as confirmed by the Arrott plots.

Key words: magnetocaloric, Gd$_{5}$Si$_{4}$, Nd doping, reduction-diffusion method

中图分类号: (Magnetocaloric effect, magnetic cooling)

75.30.Sg

Kaiyang Zhang(张凯扬), Huanhuan Wang(王欢欢), Ying Wang(王颖), and Tao Wang(王涛). Magnetocaloric properties of Nd-doped Gd₅Si₄ microparticles and nanopowders[J]. 中国物理B, 2024, 33(11): 117502-117502.

Kaiyang Zhang(张凯扬), Huanhuan Wang(王欢欢), Ying Wang(王颖), and Tao Wang(王涛). Magnetocaloric properties of Nd-doped Gd₅Si₄ microparticles and nanopowders[J]. Chin. Phys. B, 2024, 33(11): 117502-117502.

参考文献

[1] Gschneidner K A, Pecharsky V K and Tsokol A O 2005 Rep. Prog. Phys. 68 1479
[2] Gschneidner K A and Pecharsky V K 2000 Annu. Rev. Mater. Res. 30 387
[3] Pecharsky V K and Gschneidner K A 1999 J. Magn. Magn. Mater. 200 44
[4] Hao J Z, Hu F X, Yu Z B, Shen F R, Zhou H B, Gao Y H, Qiao K M, Li J, Zhang C, Liang W H, Wang J, He J, Sun J R and Shen B G 2020 Chin. Phys. B 29 047504
[5] Brown G V 1976 J. Appl. Phys. 47 3673
[6] Franco V, Blázquez J S, Ingale B and Conde A 2012 Annu. Rev. Mater. Res. 42 305
[7] Oesterreicher H and Parker F T 1984 J. Appl. Phys. 55 4334
[8] Shen B G, Sun J R, Hu F X, Zhang H W and Cheng Z H 2009 Adv. Mater. 21 4545
[9] Tegus O, Brück E, Buschow K H J and de Boer F R 2002 Nature 415 150
[10] Balli M, Jandl S, Fournier P and Kedous-Lebouc A 2017 Appl. Phys. Rev. 4 021305
[11] Banerjee B K 1964 Phys. Lett. 12 16
[12] Dan’kov S Y, Tishin A M, Pecharsky V K and Gschneidner K A 1998 Phys. Rev. B 57 3478
[13] Holtzberg F, Gambino R J and McGuire T R 1967 J. Phys. Chem. Solids 28 2283
[14] Pecharsky V K and Gschneidner Jr. K A 2001 Adv. Mater. 13 683
[15] Hu P Q, Zhang Z M, Zhang F X, Guan W Z, Wang D H and Du Y W 2022 Curr. Appl. Phys. 34 95
[16] Morellon L, Algarabel P A, Ibarra M R, Blasco J, García-Landa B, Arnold Z and Albertini F 1998 Phys. Rev. B 58 R14721
[17] Pecharsky V K and Gschneidner K A 1997 J. Alloys Compd. 260 98
[18] Harstad S M, El-Gendy A A, Gupta S, Pecharsky V K and Hadimani R L 2019 JOM 71 3159
[19] Pecharsky V K and Gschneidner Jr. K A 1997 Phys. Rev. Lett. 78 4494
[20] Choe W, Pecharsky V K, Pecharsky A O, Gschneidner K A, Young V G and Miller G J 2000 Phys. Rev. Lett. 84 4617
[21] Pecharsky A O, Gschneidner K A and Pecharsky V K 2003 J. Appl. Phys. 93 4722
[22] Tang B Z, Liu X P, Li D M, Yu P and Xia L 2020 Chin. Phys. B 29 056401
[23] Levin E M, Pecharsky V K and Gschneidner K A 1999 Phys. Rev. B 60 7993
[24] Provenzano V, Shapiro A J and Shull R D 2004 Nature 429 853
[25] Uthaman B and Raama Varma M 2015 Mater. Sci. Forum 830-831 501
[26] Kou R H, Gao J, Ren Y, Sanyal B, Bhandary S, Heald S M, Fisher B and Sun C J 2018 AIP Adv. 8 125219
[27] Nikitin S, Smirnov A, Bogdanov A and Ovchenkova I 2018 EPJ Web of Conferences 185 05006
[28] Pavan Kumar N, Prabahar K, Raj Kumar D M and Manivel Raja M 2019 J. Supercond. Novel Magn. 32 319
[29] Zhang T B, Chen Y G, Tang Y B, Du H J, Ren T and Tu M J 2007 J. Alloys Compd. 433 18
[30] Paixão L S, Rangel G, Usuda E O, Imamura W, Tedesco J C G, Patiño J C, Gomes A M, Alves C S and Carvalho A M G 2020 J. Magn. Magn. Mater. 493 165693
[31] Nauman M, Alnasir M H, Hamayun M A, Wang Y X, Shatruk M and Manzoor S 2020 RSC Adv. 10 28383
[32] Canepa F, Cirafici S and Napoletano M 2002 J. Alloys Compd. 335 L1
[33] Tung L D, Lees M R, Balakrishnan G and Paul D M 2005 Phys. Rev. B 71 144410
[34] Altounian Z and Liu X B 2007 J. Appl. Phys. 101 09
[35] Landers J, Salamon S, Keune W, Gruner M E, Krautz M, Zhao J, Hu M Y, Toellner T S, Alp E E, Gutfleisch O and Wende H 2018 Phys. Rev. B 98 024417
[36] Arrott A and Noakes J E 1967 Phys. Rev. Lett. 19 786
[37] Aharoni A 1986 J. Magn. Magn. Mater. 58 297
[38] Duc N H, Kim Anh D T and Brommer P E 2002 Physica B 319 1

Magnetocaloric properties of Nd-doped Gd₅Si₄ microparticles and nanopowders

Magnetocaloric properties of Nd-doped Gd₅Si₄ microparticles and nanopowders

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Li-Bo Zhang(张黎博), Qing-Xin Dong(董庆新), Jian-Li Bai(白建利), Qiao-Yu Liu(刘乔宇), Jing-Wen Cheng(程靖雯), Cun-Dong Li(李存东), Pin-Yu Liu(刘品宇), Ying-Rui Sun(孙英睿), Yu Huang(黄宇), Zhi-An Ren(任治安), and Gen-Fu Chen(陈根富). Magnetism, heat capacity, magnetocaloric effect, and magneto-transport properties of heavy fermion antiferromagnet CeGaSi[J]. 中国物理B, 2024, 33(6): 67101-067101.
[2]	Xiaochen Sun(孙笑晨), Chenghao Xie(谢承昊), Sihan Chen(陈思汗), Jingwei Wan(万京伟), Gangjian Tan(谭刚健), and Xinfeng Tang(唐新峰). Rational design and synthesis of Cr_1-xTe/Ag₂Te composites for solid-state thermoelectromagnetic cooling near room temperature[J]. 中国物理B, 2024, 33(5): 57201-057201.
[3]	Shi-Lin Yu(于世霖), Lu Tian(田路), Jun-Feng Wang(王俊峰), Xin-Guo Zhao(赵新国), Da Li(李达), Zhao-Jun Mo(莫兆军), and Bing Li(李昺). Magnetic and magnetocaloric effect of Er₂₀Ho₂₀Dy₂₀Cu₂₀Ni₂₀ high-entropy metallic glass[J]. 中国物理B, 2024, 33(5): 57502-057502.
[4]	Changji Xu(徐长吉), Xinyu Jiang(姜心雨), Zhengguang Zou(邹正光), Zhuojia Xie(谢卓家), Weijian Zhang(张伟建), and Min Feng(冯敏). Tuning the magnetocaloric and structural properties of La_0.67Sr_0.28Pr_0.05Mn_1-xCo_xO₃ refrigeration materials[J]. 中国物理B, 2024, 33(12): 127501-127501.
[5]	Yun-Guo Ma(马云国), Liang Qiao(乔亮), Zu-Ying Zheng(郑祖应), Hong-Bo Hao(郝宏波), Hao Wang(王浩), Zhe Sun(孙哲), Cheng-Fa Tu(涂成发), Tao Wang(王涛), Zheng Yang(杨正), and Fa-Shen Li(李发伸). Microwave absorption and bandwidth study of Y₂Co₁₇ rare earth soft magnetic alloy with easy-plane anisotropy[J]. 中国物理B, 2023, 32(8): 84202-084202.
[6]	Shao-Shan Xu(徐少山), Qi Fu(付琪), Yi-Fan Zhou(周益帆), Ling Peng(彭铃), Xin-Qiang Gao(高新强), Zhen-Xing Li(李振兴), Mao-Qiong Gong(公茂琼), Xue-Qiang Dong(董学强), and Jun Shen(沈俊). Magnetocaloric properties of phenolic resin bonded La(Fe,Si)₁₃-based plates and its use in a hybrid magnetic refrigerator[J]. 中国物理B, 2023, 32(2): 27502-027502.
[7]	Zhaojun Mo(莫兆军), Jianjian Gong(巩建建), Huicai Xie(谢慧财), Lei Zhang(张磊), Qi Fu(付琪), Xinqiang Gao(高新强), Zhenxing Li(李振兴), and Jun Shen(沈俊). Giant low-field cryogenic magnetocaloric effect in polycrystalline LiErF₄ compound[J]. 中国物理B, 2023, 32(2): 27503-027503.
[8]	Zhihong Hao(郝志红), Hui Liu(刘辉), and Juguo Zhang(张聚国). Structure, magnetism and magnetocaloric effects in Er₅Si₃B_x (x=0.3, 0.6) compounds[J]. 中国物理B, 2023, 32(11): 117501-117501.
[9]	Tina Raoufi, Jincheng He(何金城), Binbin Wang(王彬彬), Enke Liu(刘恩克), and Young Sun(孙阳). Magnetocaloric properties and Griffiths phase of ferrimagnetic cobaltite CaBaCo₄O₇[J]. 中国物理B, 2023, 32(1): 17504-017504.
[10]	Yong Li(李勇), Liang Qin(覃亮), Hongguo Zhang(张红国), and Lingwei Li(李领伟). Tailored martensitic transformation and enhanced magnetocaloric effect in all-d-metal Ni₃₅Co₁₅Mn₃₃Fe₂Ti₁₅ alloy ribbons[J]. 中国物理B, 2022, 31(8): 87103-087103.
[11]	Yan Zhang(张艳), You-Guo Shi(石友国), Li-Chen Wang(王利晨), Xin-Qi Zheng(郑新奇), Jun Liu(刘俊), Ya-Xu Jin(金亚旭), Ke-Wei Zhang(张克维), Hong-Xia Liu(刘虹霞), Shuo-Tong Zong(宗朔通), Zhi-Gang Sun(孙志刚), Ji-Fan Hu(胡季帆), Tong-Yun Tong(赵同云), and Bao-Gen Shen(沈保根). Large inverse and normal magnetocaloric effects in HoBi compound with nonhysteretic first-order phase transition[J]. 中国物理B, 2022, 31(7): 77501-077501.
[12]	Yao-Dong Wu(吴耀东), Wei-Wei Duan(段薇薇), Qiu-Yue Li(李秋月), Yong-Liang Qin(秦永亮),Zhen-Fa Zi(訾振发), and Jin Tang(汤进). Magnetic and magnetocaloric effect in a stuffed honeycomb polycrystalline antiferromagnet GdInO₃[J]. 中国物理B, 2022, 31(6): 67501-067501.
[13]	Hao Sun(孙浩), Junfeng Wang(王俊峰), Lu Tian(田路), Jianjian Gong(巩建建), Zhaojun Mo(莫兆军), Jun Shen(沈俊), and Baogen Shen(沈保根). Magnetic properties and magnetocaloric effects of Tm_1-xEr_xCuAl (x = 0.25, 0.5, and 0.75) compounds[J]. 中国物理B, 2022, 31(12): 127501-127501.
[14]	Hao Wang(王浩), Liang Qiao(乔亮), Zu-Ying Zheng(郑祖应), Hong-Bo Hao(郝宏波), Tao Wang(王涛), Zheng Yang(杨正), and Fa-Shen Li(李发伸). Microwave absorption properties regulation and bandwidth formula of oriented Y₂Fe₁₇N_3-δ@SiO₂/PU composite synthesized by reduction-diffusion method[J]. 中国物理B, 2022, 31(11): 114206-114206.
[15]	Hao Sun(孙浩), Junfeng Wang(王俊峰), Lu Tian(田路), Jianjian Gong(巩建建), Zhaojun Mo(莫兆军), Jun Shen(沈俊), and Baogen Shen(沈保根). Magnetic properties and magnetocaloric effect in RE₅₅Co₃₀Al₁₀Si₅ (RE = Er and Tm) amorphous ribbons[J]. 中国物理B, 2022, 31(11): 117503-117503.