Vibrational effects on electron momentum distributionsof outer valence orbitals of benzene

doi:10.1088/1674-1056/ab671b

中国物理B ›› 2020, Vol. 29 ›› Issue (2): 23402-023402.doi: 10.1088/1674-1056/ab671b

• SPECIAL TOPIC—Recent advances in thermoelectric materials and devices • 上一篇下一篇

Vibrational effects on electron momentum distributionsof outer valence orbitals of benzene

Yu Zhang(张钰), Shanshan Niu(牛珊珊), Yaguo Tang(唐亚国), Yichun Wang(王忆纯), Xu Shan(单旭), Xiangjun Chen(陈向军)

Hefei National Laboratory for Physical Sciences at the Microscale and Department of Modern Physics, University of Science and Technology of China, Hefei 230026, China

收稿日期:2019-10-22 出版日期:2020-02-05 发布日期:2020-02-05
通讯作者: Yu Zhang E-mail:joeyyu@mail.ustc.edu.cn
基金资助:
Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0402300).

Vibrational effects on electron momentum distributionsof outer valence orbitals of benzene

Yu Zhang(张钰), Shanshan Niu(牛珊珊), Yaguo Tang(唐亚国), Yichun Wang(王忆纯), Xu Shan(单旭), Xiangjun Chen(陈向军)

Hefei National Laboratory for Physical Sciences at the Microscale and Department of Modern Physics, University of Science and Technology of China, Hefei 230026, China

Received:2019-10-22 Online:2020-02-05 Published:2020-02-05
Contact: Yu Zhang E-mail:joeyyu@mail.ustc.edu.cn
Supported by:
Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0402300).

摘要/Abstract

摘要： The outer valence electron momentum distributions of benzene are reinvestigated with theoretical calculations involving the vibrational effects. The results are compared with recent experimental measurements [Phys. Rev. A 98 042705 (2018)]. The significant discrepancies between theories and experiments in previous works have now been interpreted quantitatively, indicating that the vibrational motion in benzene molecule has noticeable influence on its electron momentum distributions.

关键词: electron momentum spectroscopy, benzene, outer valence orbitals, vibrational effects

Abstract: The outer valence electron momentum distributions of benzene are reinvestigated with theoretical calculations involving the vibrational effects. The results are compared with recent experimental measurements [Phys. Rev. A 98 042705 (2018)]. The significant discrepancies between theories and experiments in previous works have now been interpreted quantitatively, indicating that the vibrational motion in benzene molecule has noticeable influence on its electron momentum distributions.

Key words: electron momentum spectroscopy, benzene, outer valence orbitals, vibrational effects

中图分类号: (Molecular excitation and ionization)

34.80.Gs

31.15.aj (Relativistic corrections, spin-orbit effects, fine structure; hyperfine structure)

张钰, 牛珊珊, 唐亚国, 王忆纯, 单旭, 陈向军. Vibrational effects on electron momentum distributionsof outer valence orbitals of benzene[J]. 中国物理B, 2020, 29(2): 23402-023402.

Yu Zhang(张钰), Shanshan Niu(牛珊珊), Yaguo Tang(唐亚国), Yichun Wang(王忆纯), Xu Shan(单旭), Xiangjun Chen(陈向军). Vibrational effects on electron momentum distributionsof outer valence orbitals of benzene[J]. Chin. Phys. B, 2020, 29(2): 23402-023402.

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Vibrational effects on electron momentum distributionsof outer valence orbitals of benzene

Vibrational effects on electron momentum distributionsof outer valence orbitals of benzene

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