Crystallographic and magnetic properties of van der Waals layered FePS3 crystal

doi:10.1088/1674-1056/28/5/056102

中国物理B ›› 2019, Vol. 28 ›› Issue (5): 56102-056102.doi: 10.1088/1674-1056/28/5/056102

所属专题： Virtual Special Topic — Magnetism and Magnetic Materials

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Crystallographic and magnetic properties of van der Waals layered FePS₃ crystal

Qi-Yun Xie(解其云), Min Wu(吴敏), Li-Min Chen(陈丽敏), Gang Bai(白刚), Wen-Qin Zou(邹文琴), Wei Wang(王伟), Liang He(何亮)

1 Key Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing University of Posts & Telecommunications, Nanjing 210023, China;
2 Key Laboratory of Flexible Electronics(KLOFE) & Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing Tech University, Nanjing 211816, China;
3 Jiangsu Provincial Key Laboratory of Advanced Photonic and Electronic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Electronic Science and Engineering, Nanjing University, Nanjing 210093, China;
4 National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China

收稿日期:2018-11-23 修回日期:2019-02-26 出版日期:2019-05-05 发布日期:2019-05-05
通讯作者: Wei Wang, Liang He E-mail:wwesun2000@163.com;heliang@nju.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 11404169, 51602159, and 11704196), the Scientific Research Foundation of Nanjing University of Posts & Telecommunications, China (Grant Nos. NY217043 and NY218021), and the Postgraduate Research & Practice Innovation Program of Jiangsu Province, China (Grant Nos. KYCX17_0754 and SJCX18_0287).

Crystallographic and magnetic properties of van der Waals layered FePS₃ crystal

Qi-Yun Xie(解其云)^1,4, Min Wu(吴敏)¹, Li-Min Chen(陈丽敏)¹, Gang Bai(白刚)¹, Wen-Qin Zou(邹文琴)³, Wei Wang(王伟)^2,3, Liang He(何亮)³

1 Key Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing University of Posts & Telecommunications, Nanjing 210023, China;
2 Key Laboratory of Flexible Electronics(KLOFE) & Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing Tech University, Nanjing 211816, China;
3 Jiangsu Provincial Key Laboratory of Advanced Photonic and Electronic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Electronic Science and Engineering, Nanjing University, Nanjing 210093, China;
4 National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China

Received:2018-11-23 Revised:2019-02-26 Online:2019-05-05 Published:2019-05-05
Contact: Wei Wang, Liang He E-mail:wwesun2000@163.com;heliang@nju.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 11404169, 51602159, and 11704196), the Scientific Research Foundation of Nanjing University of Posts & Telecommunications, China (Grant Nos. NY217043 and NY218021), and the Postgraduate Research & Practice Innovation Program of Jiangsu Province, China (Grant Nos. KYCX17_0754 and SJCX18_0287).

摘要/Abstract

摘要：

The crystallographic and magnetic properties are presented for van der Waals antiferromagnetic FePS₃. High-quality single crystals of millimeter size have been successfully synthesized through the chemical vapor transport method. The layered structure and cleavability of the compound are apparent, which are beneficial for a potential exploration of the interesting low dimensional magnetism, as well as for incorporation of FePS₃ into van der Waals heterostructures. For the sake of completeness, we have measured both direct current (dc) and alternating current (ac) magnetic susceptibility. The paramagnetic to antiferromagnetic transition occurs at approximately T_N~115 K. The effective moment is larger than the spin-only effective moment, suggesting that an orbital contribution to the total angular momentum of the Fe²⁺ could be present. The ac susceptibility is independent of frequency, which means that the spin freezing effect is excluded. Strong anisotropy of out-of-plane and in-plane susceptibility has been shown, demonstrating the Ising-type magnetic order in FePS₃ system.

关键词: FePS₃, van der Waals crystals, single crystal, antiferromagnetism

Abstract:

Key words: FePS₃, van der Waals crystals, single crystal, antiferromagnetism

中图分类号: (III-V and II-VI semiconductors)

61.72.uj

75.50.Ee (Antiferromagnetics) 78.67.Bf (Nanocrystals, nanoparticles, and nanoclusters)

解其云, 吴敏, 陈丽敏, 白刚, 邹文琴, 王伟, 何亮. Crystallographic and magnetic properties of van der Waals layered FePS₃ crystal[J]. 中国物理B, 2019, 28(5): 56102-056102.

Qi-Yun Xie(解其云), Min Wu(吴敏), Li-Min Chen(陈丽敏), Gang Bai(白刚), Wen-Qin Zou(邹文琴), Wei Wang(王伟), Liang He(何亮). Crystallographic and magnetic properties of van der Waals layered FePS₃ crystal[J]. Chin. Phys. B, 2019, 28(5): 56102-056102.

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Crystallographic and magnetic properties of van der Waals layered FePS₃ crystal

Crystallographic and magnetic properties of van der Waals layered FePS₃ crystal

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