Effects of dielectric decrement on surface potential in a mixed electrolyte solution

doi:10.1088/1674-1056/27/12/126801

中国物理B ›› 2018, Vol. 27 ›› Issue (12): 126801-126801.doi: 10.1088/1674-1056/27/12/126801

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Effects of dielectric decrement on surface potential in a mixed electrolyte solution

Jing Peng(彭景), Wen-Xin Zou(邹温馨), Rui Tian(田锐), Hang Li(李航), Xin-Min Liu(刘新敏)

Chongqing Key Laboratory of Soil Multiscale Interfacial Process, College of Resources and Environment, Southwest University, Chongqing 400715, China

收稿日期:2018-06-28 修回日期:2018-09-07 出版日期:2018-12-05 发布日期:2018-12-05
通讯作者: Xin-Min Liu E-mail:lucimir@163.com
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 41501240, 41530855, 41501241, and 41877026), the Natural Science Foundation of Chongqing CSTC (Grant No. cstc2018jcyjAX0318), and the Fundamental Research Funds for the Central Universities, China (Grant No. XDJK2017B029).

Effects of dielectric decrement on surface potential in a mixed electrolyte solution

Jing Peng(彭景), Wen-Xin Zou(邹温馨), Rui Tian(田锐), Hang Li(李航), Xin-Min Liu(刘新敏)

Chongqing Key Laboratory of Soil Multiscale Interfacial Process, College of Resources and Environment, Southwest University, Chongqing 400715, China

Received:2018-06-28 Revised:2018-09-07 Online:2018-12-05 Published:2018-12-05
Contact: Xin-Min Liu E-mail:lucimir@163.com
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 41501240, 41530855, 41501241, and 41877026), the Natural Science Foundation of Chongqing CSTC (Grant No. cstc2018jcyjAX0318), and the Fundamental Research Funds for the Central Universities, China (Grant No. XDJK2017B029).

摘要/Abstract

摘要：

Surface potential is an important parameter related to the physical and chemical properties of charged particles. A simple analytical model for the estimation of surface potential is established based on the Poisson-Boltzmann theory with the consideration of the dielectric decrement in mixed electrolyte. The analytical relationships between surface potential and charge density are derived in different mixed electrolytes with monovalent and bivalent ions. The dielectric decrease on the charged surface strongly affects the surface potential at a high charge density with different ion strengths and concentration ratios of counter-ions. The surface potential based on the Gouy-Chapman model is underestimated because of the dielectric decrement on the surface. The diffuse layer can be regarded as a continuous uniform medium only when the surface charge density is lower than 0.3 C·m^-2. However, the surface charge densities of many materials in practical applications are higher than 0.3 C·m^-2. The new model for the estimation of surface potential can return to the results obtained based on the Gouy-Chapman model at a low charge density. Therefore, it is implied that the established model that considers the dielectric decrement is valid and widely applicable.

关键词: surface potential, colloidal particle, dielectric decrement, charge density, electrolyte

Abstract:

Key words: surface potential, colloidal particle, dielectric decrement, charge density, electrolyte

中图分类号: (Liquid-solid interface structure: measurements and simulations)

68.08.De

68.08.-p (Liquid-solid interfaces) 82.65.+r (Surface and interface chemistry; heterogeneous catalysis at surfaces) 82.45.Un (Dielectric materials in electrochemistry)

彭景, 邹温馨, 田锐, 李航, 刘新敏. Effects of dielectric decrement on surface potential in a mixed electrolyte solution[J]. 中国物理B, 2018, 27(12): 126801-126801.

Jing Peng(彭景), Wen-Xin Zou(邹温馨), Rui Tian(田锐), Hang Li(李航), Xin-Min Liu(刘新敏). Effects of dielectric decrement on surface potential in a mixed electrolyte solution[J]. Chin. Phys. B, 2018, 27(12): 126801-126801.

参考文献 36

[1]	Liu X, Li H, Du W, Tian R, Li R and Jiang X 2013 J. Phys. Chem. C 117 6245 doi: 10.1021/jp312682u
[2]	Liu X, Li H, Li R, Xie D, Ni J and Wu L 2015 Sci. Rep. 4 5047 doi: 10.1038/srep05047
[3]	Xin Y, Zheng Y X and Yu Y X 2016 Mol. Phys. 114 2328 doi: 10.1080/00268976.2015.1090637
[4]	Hu F, Xu C, Li H, Li S, Yu Z, Li Y and He X 2015 Soil Till. Res. 147 1
[5]	Xu C, Li H, Hu F, Li S, Liu X and Li Y 2015 Eur. J. Soil Sci. 66 615 doi: 10.1111/ejss.12252
[6]	Mugele F, Bera B, Cavalli A, Siretanu I, Maestro A, Duits M, Cohen-Stuart M, Van Den Ende D, Stocker I and Collins I 2015 Sci. Rep. 5 10519 doi: 10.1038/srep10519
[7]	Brogioli D 2009 Phys. Rev. Lett. 103 058501 doi: 10.1103/PhysRevLett.103.058501
[8]	Trefalt G, Behrens S H and Borkovec M 2016 Langmuir 32 380 doi: 10.1021/acs.langmuir.5b03611
[9]	Vlachy V 1999 Ann. Rev. Phys. Chem. 50 145 doi: 10.1146/annurev.physchem.50.1.145
[10]	Wang K, Yu Y X and Gao G H 2008 J. Chem. Phys. 128 185101 doi: 10.1063/1.2918342
[11]	Peng B and Yu Y X 2009 J. Chem. Phys. 131 134703 doi: 10.1063/1.3243873
[12]	Liu X M, Yang G, Li H, Li H, Tian R, Ding W Q and Yuan R 2015 Chin. Phys. B 24 068202 doi: 10.1088/1674-1056/24/6/068202
[13]	Wan L, Xu S, Liao M, Liu C and Shen P 2014 Physics 43 589 (in Chinese)
[14]	Liu Y, Yan E C, Zhao X and Eisenthal K B 2001 Langmuir 17 2063 doi: 10.1021/la0011634
[15]	Yan E C Y, Liu Y and Eisenthal K B 1998 J. Phys. Chem. B 102 6331
[16]	Brown M A, Abbas Z, Kleibert A, Green R G, Goel A, May S and Squires T M 2016 Phys. Rev. X 6 011007
[17]	Li H, Wei S, Qing C and Yang J 2003 J. Colloid Interface Sci. 258 40 doi: 10.1016/S0021-9797(02)00077-2
[18]	Liu X, Ding W, Tian R, Du W and Li H 2017 Soil Sci. Soc. Am. J. 81 268 doi: 10.2136/sssaj2016.08.0261
[19]	Grahame D C 1950 J. Chem. Phys. 18 903 doi: 10.1063/1.1747807
[20]	Orl D H 2007 Phys. Rev. Lett. 99 077801 doi: 10.1103/PhysRevLett.99.077801
[21]	Parkhurst D L and Appelo C A J 2013 Description Input Examples For PHREEQC version 3-A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations (USGS)
[22]	Hou J and Li H 2009 Soil Sci. Soc. Am. J. 73 1658 doi: 10.2136/sssaj2008.0017
[23]	Li H, Qing C L, Wei S Q and Jiang X J 2004 J. Colloid Interface Sci. 275 172 doi: 10.1016/j.jcis.2003.12.055
[24]	Zhao R, van Soestbergen M, Rijnaarts H H M, van der Wal A, Bazant M Z and Biesheuvel P M 2012 J. Colloid Interface Sci. 384 38
[25]	Liu X, Tian R, Li R, Ding W, Li H and Yuan R 2015 Proc. Royal Soc. A 471 20150064 doi: 10.1098/rspa.2015.0064
[26]	Sposito G 1984 The Surface Chemistry of Soils (Oxford/New York: Clarendon Press/Oxford University Press)
[27]	Gongadze E, van Rienen U, Kralj-Iglič V and Iglič A 2011 Gen. Physiol. Biophys. 30 130 doi: 10.4149/gpb_2011_02_130
[28]	Mashayak S Y and Aluru N R 2017 J. Chem. Phys. 146 044108 doi: 10.1063/1.4973934
[29]	Liu X, Li H, Li R and Tian R 2013 Surf. Sci. 607 197 doi: 10.1016/j.susc.2012.09.008
[30]	Gavish N and Promislow K 2016 Phys. Rev. E 94 012611 doi: 10.1103/PhysRevE.94.012611
[31]	Low P F 1981 Soil Sci. Soc. Am. J. 45 1074 doi: 10.2136/sssaj1981.03615995004500060013x
[32]	Parsons D F and Ninham B W 2010 Langmuir 26 1816 doi: 10.1021/la902533x
[33]	Bousse L J, Mostarshed S and Hafeman D 1992 Sensors Actuators B: Chem. 10 67 doi: 10.1016/0925-4005(92)80013-N
[34]	Perram J W 1973 J. Chem. Soc. Faraday Trans. 69 993
[35]	Bowden J W, Posner A M and Quirk J P 1977 Soil Res. 15 121
[36]	Stern O 1924 Zeit. Elektrochem 30 508

Effects of dielectric decrement on surface potential in a mixed electrolyte solution

Effects of dielectric decrement on surface potential in a mixed electrolyte solution

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