中国物理B ›› 2013, Vol. 22 ›› Issue (6): 66202-066202.doi: 10.1088/1674-1056/22/6/066202

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇    下一篇

High-pressure Raman study of MgV2O6 synthesized at high pressure and high temperature

唐瑞莲a, 李岩a b, 陶强a, 李娜娜a, 李会a, 韩丹丹a, 朱品文a, 王欣a   

  1. a State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China;
    b College of Physics, Jilin University, Changchun 130012, China
  • 收稿日期:2012-10-20 修回日期:2013-01-06 出版日期:2013-05-01 发布日期:2013-05-01
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant No. 51172091) and the Program for New Century Excellent Talents in University.

High-pressure Raman study of MgV2O6 synthesized at high pressure and high temperature

Tang Rui-Lian (唐瑞莲)a, Li Yan (李岩)a b, Tao Qiang (陶强)a, Li Na-Na (李娜娜)a, Li Hui (李会)a, Han Dan-Dan (韩丹丹)a, Zhu Pin-Wen (朱品文)a, Wang Xin (王欣)a   

  1. a State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China;
    b College of Physics, Jilin University, Changchun 130012, China
  • Received:2012-10-20 Revised:2013-01-06 Online:2013-05-01 Published:2013-05-01
  • Contact: Wang Xin E-mail:xin_wang@jlu.edu.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No. 51172091) and the Program for New Century Excellent Talents in University.

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摘要： A new structural phase of MgV2O6 was obtained by a high-pressure, high-temperature (HPHT) synthesis method. The new phase was investigated by Rietveld analysis of X-ray powder diffraction data, showing space group Pbcn (No. 60) symmetry and a=13.6113(6) Å (1 Å=0.1 nm), b=5.5809(1) Å, c=4.8566(3) Å, V=368.93(2) Å3 (Z=4). High pressure behavior was studied by Raman spectroscopy at room temperature. Under 22.5 GPa, there was no sign of a structural phase transition in the spectra, demonstrating stability of the HPHT phase up to the highest pressure.

关键词: high-pressure and high-temperature, MgV2O6, Raman spectroscopy, high-pressure

Abstract: A new structural phase of MgV2O6 was obtained by a high-pressure, high-temperature (HPHT) synthesis method. The new phase was investigated by Rietveld analysis of X-ray powder diffraction data, showing space group Pbcn (No. 60) symmetry and a=13.6113(6) Å (1 Å=0.1 nm), b=5.5809(1) Å, c=4.8566(3) Å, V=368.93(2) Å3 (Z=4). High pressure behavior was studied by Raman spectroscopy at room temperature. Under 22.5 GPa, there was no sign of a structural phase transition in the spectra, demonstrating stability of the HPHT phase up to the highest pressure.

Key words: high-pressure and high-temperature, MgV2O6, Raman spectroscopy, high-pressure

中图分类号:  (High-pressure effects in solids and liquids)

  • 62.50.-p
78.30.-j (Infrared and Raman spectra)