Up-conversion photoluminescence characteristics of Yb3+:Er3+:Tm3+ co-doped borosilicate glasses

doi:10.1088/1674-1056/19/4/047801

中国物理B ›› 2010, Vol. 19 ›› Issue (4): 47801-047801.doi: 10.1088/1674-1056/19/4/047801

Up-conversion photoluminescence characteristics of Yb³⁺:Er³⁺:Tm³⁺ co-doped borosilicate glasses

李成仁¹, 徐伟¹, 程宇琪¹, 殷海涛¹, 李淑凤², 丁建华², 董斌³

(1)College of Physics and Electronic Technology, Liaoning Normal University, Dalian 116029, China; (2)School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024, China; (3)School of Science, Dalian Nationalities University, Dalian 116600, China

收稿日期:2009-06-28 修回日期:2009-09-28 出版日期:2010-04-15 发布日期:2010-04-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No.~10804015) and the Science Foundation of the Education Department of Liaoning Province of China (Grant No.~2009A417).

Up-conversion photoluminescence characteristics of Yb³⁺:Er³⁺:Tm³⁺ co-doped borosilicate glasses

Li Cheng-Ren(李成仁)^a)^†,Xu Wei(徐伟)^a),Dong Bin(董斌)^b), Li Shu-Feng(李淑凤)^c),Ding Jian-Hua(丁建华)^c), Cheng Yu-Qi(程宇琪)^a), and Yin Hai-Tao(殷海涛)^a)

^a College of Physics and Electronic Technology, Liaoning Normal University, Dalian 116029, China; ^b School of Science, Dalian Nationalities University, Dalian 116600, China; ^c School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024, China

Received:2009-06-28 Revised:2009-09-28 Online:2010-04-15 Published:2010-04-15
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No.~10804015) and the Science Foundation of the Education Department of Liaoning Province of China (Grant No.~2009A417).

摘要/Abstract

摘要： Yb³⁺:Er³⁺:Tm³⁺co-doped borosilicate glasses are prepared. Their strong up-conversion photoluminescence spectra in a range from ultra-violet to near-infrared, which are excited by a 978-nm laser diode, are measured, and the mechanisms of energy transfer among Yb³⁺, Er³⁺ and Tm³⁺ ions are discussed. The results show that there is an unexpected wavelength at 900-nm emission from Yb³⁺ Stark splitting levels to pump Tm³⁺ ions and there exists an optimum pump power. The concentration of the Tm³⁺ dopant gives rise to a prominent effect on the intensity of visible and near-infrared emissions for the Yb³⁺:Er³⁺:Tm³⁺ co-doped borosilicate glasses.

Abstract: Yb³⁺:Er³⁺:Tm³⁺co-doped borosilicate glasses are prepared. Their strong up-conversion photoluminescence spectra in a range from ultra-violet to near-infrared, which are excited by a 978-nm laser diode, are measured, and the mechanisms of energy transfer among Yb³⁺, Er³⁺ and Tm³⁺ ions are discussed. The results show that there is an unexpected wavelength at 900-nm emission from Yb³⁺ Stark splitting levels to pump Tm³⁺ ions and there exists an optimum pump power. The concentration of the Tm³⁺ dopant gives rise to a prominent effect on the intensity of visible and near-infrared emissions for the Yb³⁺:Er³⁺:Tm³⁺ co-doped borosilicate glasses.

Key words: Er³⁺:Yb³⁺:Tm³⁺ co-doped borosilicate glasses, up-conversion emission, two pump wavelengths, optimum pump power

中图分类号: (Other solid inorganic materials)

78.55.Hx

78.20.Jq (Electro-optical effects) 71.70.Ej (Spin-orbit coupling, Zeeman and Stark splitting, Jahn-Teller effect) 61.72.S- (Impurities in crystals)

李成仁, 徐伟, 董斌, 李淑凤, 丁建华, 程宇琪, 殷海涛. Up-conversion photoluminescence characteristics of Yb³⁺:Er³⁺:Tm³⁺ co-doped borosilicate glasses[J]. 中国物理B, 2010, 19(4): 47801-047801.

Li Cheng-Ren(李成仁),Xu Wei(徐伟),Dong Bin(董斌), Li Shu-Feng(李淑凤),Ding Jian-Hua(丁建华), Cheng Yu-Qi(程宇琪), and Yin Hai-Tao(殷海涛). Up-conversion photoluminescence characteristics of Yb³⁺:Er³⁺:Tm³⁺ co-doped borosilicate glasses[J]. Chin. Phys. B, 2010, 19(4): 47801-047801.

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Up-conversion photoluminescence characteristics of Yb³⁺:Er³⁺:Tm³⁺ co-doped borosilicate glasses

Up-conversion photoluminescence characteristics of Yb³⁺:Er³⁺:Tm³⁺ co-doped borosilicate glasses

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