Synthesis of large diamond crystals containing high-nitrogen concentration at high pressure and high temperature using Ni-based solvent by temperature gradient method

doi:10.1088/1674-1056/19/11/118101

中国物理B ›› 2010, Vol. 19 ›› Issue (11): 118101-118101.doi: 10.1088/1674-1056/19/11/118101

Synthesis of large diamond crystals containing high-nitrogen concentration at high pressure and high temperature using Ni-based solvent by temperature gradient method

李尚升¹, 黄国锋², 张亚飞², 李勇², 赵明², 马红安², 贾晓鹏³

(1)Henan Polytechnic University, Jiaozuo 454000, China; (2)National Lab of Superhard Materials, Jilin University, Jilin 130012, China; (3)National Lab of Superhard Materials, Jilin University, Jilin 130012, China; Henan Polytechnic University, Jiaozuo 454000, China

收稿日期:2010-03-19 修回日期:2010-05-12 出版日期:2010-11-15 发布日期:2010-11-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 50572032).

Synthesis of large diamond crystals containing high-nitrogen concentration at high pressure and high temperature using Ni-based solvent by temperature gradient method

Huang Guo-Feng(黄国锋)^a), Jia Xiao-Peng(贾晓鹏)^a)b), Li Shang-Sheng(李尚升)^b), Zhang Ya-Fei(张亚飞)^a), Li Yong(李勇)^a), Zhao Ming(赵明)^a), and Ma Hong-An(马红安)^a)^†

^a National Lab of Superhard Materials, Jilin University, Jilin 130012, China; ^b Henan Polytechnic University, Jiaozuo 454000, China

Received:2010-03-19 Revised:2010-05-12 Online:2010-11-15 Published:2010-11-15
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 50572032).

摘要/Abstract

摘要： This paper reprots that with Ni-based catalyst/solvent and with a dopant of NaN₃, large green single crystal diamonds with perfect shape are successfully synthesized by temperature gradient method under high pressure and high temperature in a China-type cubic anvil high-pressure apparatus (SPD-6×1200), and the highest nitrogen concentration reaches approximately 1214-1257 ppm calculated by infrared absorption spectra. The synthesis conditions are about 5.5 GPa and 1240-1300 ℃. The growth behaviour of diamond with high-nitrogen concentration is investigated in detail. The results show that, with increasing the content of NaN₃ added in synthesis system, the width of synthesis temperature region for growth high-quality diamonds becomes narrower, and the morphology of diamond crystal is changed from cube-octahedral to octahedral at same temperature and pressure, the crystal growth rate is slowed down, nevertheless, the nitrogen concentration doped in synthetic diamond increases.

Abstract: This paper reprots that with Ni-based catalyst/solvent and with a dopant of NaN₃, large green single crystal diamonds with perfect shape are successfully synthesized by temperature gradient method under high pressure and high temperature in a China-type cubic anvil high-pressure apparatus (SPD-6×1200), and the highest nitrogen concentration reaches approximately 1214-1257 ppm calculated by infrared absorption spectra. The synthesis conditions are about 5.5 GPa and 1240-1300 ℃. The growth behaviour of diamond with high-nitrogen concentration is investigated in detail. The results show that, with increasing the content of NaN₃ added in synthesis system, the width of synthesis temperature region for growth high-quality diamonds becomes narrower, and the morphology of diamond crystal is changed from cube-octahedral to octahedral at same temperature and pressure, the crystal growth rate is slowed down, nevertheless, the nitrogen concentration doped in synthetic diamond increases.

Key words: high temperature and high pressure, nitrogen-doped diamond crystal, temperature gradient method, additive NaN₃

中图分类号: (Impurities in crystals)

61.72.S-

62.50.-p (High-pressure effects in solids and liquids) 81.10.Dn (Growth from solutions)

黄国锋, 贾晓鹏, 李尚升, 张亚飞, 李勇, 赵明, 马红安. Synthesis of large diamond crystals containing high-nitrogen concentration at high pressure and high temperature using Ni-based solvent by temperature gradient method[J]. 中国物理B, 2010, 19(11): 118101-118101.

Huang Guo-Feng(黄国锋), Jia Xiao-Peng(贾晓鹏), Li Shang-Sheng(李尚升), Zhang Ya-Fei(张亚飞), Li Yong(李勇), Zhao Ming(赵明), and Ma Hong-An(马红安). Synthesis of large diamond crystals containing high-nitrogen concentration at high pressure and high temperature using Ni-based solvent by temperature gradient method[J]. Chin. Phys. B, 2010, 19(11): 118101-118101.

参考文献 17

[1]	Sumiya H and Toda N 2005 wxNew Materials60 15
[2]	Blank V D, Kuznetsov M S, Nosukhin S A, Terentiev S A and Denisov V N 2007 wxDiamond and Relat. Mater.16 800
[3]	Woods G S 1984 wxPhil. Mag. B50 673
[4]	Chrenko R M, Tuft R E and Strong H M 1977 wxNature270 141
[5]	Evans T and Qi Z 1982 wxProc. Roy. Soc. London A381 159
[6]	Kanda H, Akaishi M and Yamaoka S 1999 wxDiamond Relat. Mater.8 1441
[7]	Borzdov Yu, Pal'yanov Yu, Kupriyanov I, Gusev V, Khokhryakov A, Sokol A and Efremov A 2002 wxDiamond Relat. Mater.11 1863
[8]	Liang Z Z, Jia X, Ma H A, Zang C Y, Zhu P W, Guan Q F and Kanda H 2005 wxDiamond Relat. Mater.14 1932
[9]	Yu R Z, Ma H A, Liang Z Z, Liu W Q, Zheng Y J and Jia X 2008 wxDiamond Relat. Mater.17 180
[10]	Zhou L, Jia X P, Ma H A, Zheng Y J and Li Y T 2008 wxChin. Phys. B17 4665
[11]	Ma H A, Jia X P, Chen L X, Zhu P W, Guo W L, Guo X B, Wang Y D, Li S Q, Zou G T, Zhang G and Bex P 2002 wxJ. Phys. Condens. Matter14 11269
[12]	Read Jr W T and Lark Harowitz K (Eds.) 1959 wxMethods of Experimental Physics 6A (New York: Academic) p1
[13]	Zhou L, Jia X P, Ma H A, Zheng Y J and Li Y T 2009 wxChin. Phys. B18 333
[14]	Sumiya H, Toda N and Satoh S 2002 wxJ. Crystal Growth237 1281
[15]	Liang Z Z, Jia X, Zhu P W, Ma H A, Zang C Y, Qing J M and Guan Q F 2006 wxDiamond Relat. Mater.15 10
[16]	Kiflawi I, Mayer A E, Spear P M, van Wyk J A and Woods G S 1994 wxPhilos. Mag. B9 1141
[17]	Zhang Y F, Zang C Y, Ma H A, Liang Z Z, Zhou L, Li S S and Jia X P 2008 wxDiamond Relat. Mater.17 209

Synthesis of large diamond crystals containing high-nitrogen concentration at high pressure and high temperature using Ni-based solvent by temperature gradient method

Synthesis of large diamond crystals containing high-nitrogen concentration at high pressure and high temperature using Ni-based solvent by temperature gradient method

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