中国物理B ›› 2000, Vol. 9 ›› Issue (2): 86-93.doi: 10.1088/1009-1963/9/2/002

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QUANTUM-MECHANICAL PROPERTIES OF PROTON TRANSPORT IN THE HYDROGEN-BONDED MOLECULAR SYSTEMS

李萍1, 庞小峰2   

  1. (1)Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China; (2)Institute of High-Energy Electronics, University of Electronic Science and Technology, Chengdu 610054, China; International Centre for Material Physics, Chinese Academy of Sciences, Shenyang 110015, China; Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
  • 收稿日期:1998-11-02 修回日期:1999-08-03 出版日期:2000-02-15 发布日期:2005-06-10
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant No. 19974034).

QUANTUM-MECHANICAL PROPERTIES OF PROTON TRANSPORT IN THE HYDROGEN-BONDED MOLECULAR SYSTEMS

Pang Xiao-feng (庞小峰)ab, Li Ping (李萍)b   

  1. a Institute of High-Energy Electronics, University of Electronic Science and Technology, Chengdu 610054, China; International Centre for Material Physics, Chinese Academy of Sciences, Shenyang 110015, China;  b Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
  • Received:1998-11-02 Revised:1999-08-03 Online:2000-02-15 Published:2005-06-10
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No. 19974034).

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摘要： The dynamic equations of the proton transport along the hydrogen bonded molecular systems have been obtained by using completely quantum-mechanical method to be based on new Hamiltonian and model we proposed. Some quantum-mechanical features of the proton-solitons have also been given in such a case. The alternate motion of two defects resulting from proton transfer occurred in the systems can be explained by the results. The results obtained show that the proton-soliton has corpuscle feature and obey classical equations of motion, while the free soliton moves in uniform velocity along the hydrogen bonded chains.

Abstract: The dynamic equations of the proton transport along the hydrogen bonded molecular systems have been obtained by using completely quantum-mechanical method to be based on new Hamiltonian and model we proposed. Some quantum-mechanical features of the proton-solitons have also been given in such a case. The alternate motion of two defects resulting from proton transfer occurred in the systems can be explained by the results. The results obtained show that the proton-soliton has corpuscle feature and obey classical equations of motion, while the free soliton moves in uniform velocity along the hydrogen bonded chains.

中图分类号:  (Solutions of wave equations: bound states)

  • 03.65.Ge
03.65.Vf (Phases: geometric; dynamic or topological) 05.45.Yv (Solitons)