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LOCAL MODE SPECTROSCOPIC STUDY OF THE AsH3 MOLECULE: THE PERTURBED (500) LOCAL MODE OVERTONE
林海, N. Ulenikov, M. Olekhnovitch, 王冬, 陈习意, 郝绿原, 朱清时
2000 (2):
113-118.
doi: 10.1088/1009-1963/9/2/007
摘要
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The high resolution Fourier transform spectra of AsH3 in the region of 9720-9900 cm-1, which had been recorded at a resolution of 0.015 cm-1, were assigned to the (500; A1) and (500; E) local mode overtones and rotationally analyzed. The effective spectroscopic parameters were obtained by nonlinear least-squares fitting the vibration-rotational Hamiltonian with the rotational energy levels up to J=6 (98 levels in all) included. The evolution of the rotational energy patterns from v=1 to v=6 shows that the tendency of normal mode to local mode vibration evolution has been stopped by perturbations in relatively high energy region.
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