中国物理B ›› 2006, Vol. 15 ›› Issue (8): 1896-1902.doi: 10.1088/1009-1963/15/8/045

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Aggregation processes with catalysis-driven monomer birth/death

陈 玉, 韩安家, 柯见洪, 林振权   

  1. School of Physics and Electronic Information,Wenzhou University, Wenzhou 325027, China
  • 收稿日期:2005-12-16 修回日期:2006-02-24 出版日期:2006-08-20 发布日期:2006-08-20
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant Nos 10305009 and 10275048) and the Zhejiang Provincial Natural Science Foundation, China (Grant No 102067).

Aggregation processes with catalysis-driven monomer birth/death

Chen Yu(陈玉), Han An-Jia(韩安家), Ke Jian-Hong(柯见洪), and Lin Zhen-Quan(林振权)   

  1. School of Physics and Electronic Information,Wenzhou University, Wenzhou 325027, China
  • Received:2005-12-16 Revised:2006-02-24 Online:2006-08-20 Published:2006-08-20
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant Nos 10305009 and 10275048) and the Zhejiang Provincial Natural Science Foundation, China (Grant No 102067).

摘要: We propose two solvable cluster growth models, in which an irreversible aggregation spontaneously occurs between any two clusters of the same species; meanwhile, monomer birth or death of species A occurs with the help of species B. The system with the size-dependent monomer birth/death rate kernel K(i,j) = Jij^v is then investigated by means of the mean-field rate equation. The results show that the kinetic scaling behaviour of species A depends crucially on the value of the index v. For the model with catalysis-driven monomer birth, the cluster-mass distribution of species A obeys the conventional scaling law in the v \le 0 case, while it satisfies a generalized scaling form in the v > 0 case; moreover, the total mass of species A is a nonzero value in the v < 0 case while it grows continuously with time in the v \ge 0 case. For the model with catalysis-driven monomer death, the cluster-mass distribution also approaches the conventional scaling form in the v < 0 case, while the conventional scaling description of the system breaks down in the v \ge 0 case. Additionally, the total mass of species A retains a nonzero quantity in the v < 0 case, but it decreases to zero with time in the v \ge 0 case.

关键词: kinetic behaviour, cluster growth, scaling law, rate equation

Abstract: We propose two solvable cluster growth models, in which an irreversible aggregation spontaneously occurs between any two clusters of the same species; meanwhile, monomer birth or death of species A occurs with the help of species B. The system with the size-dependent monomer birth/death rate kernel $K(i,j) = Jij^v$ is then investigated by means of the mean-field rate equation. The results show that the kinetic scaling behaviour of species A depends crucially on the value of the index $v$. For the model with catalysis-driven monomer birth, the cluster-mass distribution of species $A$ obeys the conventional scaling law in the $v \leq 0$ case, while it satisfies a generalized scaling form in the $v > 0$ case; moreover, the total mass of species A is a nonzero value in the $v < 0$ case while it grows continuously with time in the $v \geq 0$ case. For the model with catalysis-driven monomer death, the cluster-mass distribution also approaches the conventional scaling form in the $v < 0$ case, while the conventional scaling description of the system breaks down in the $v \geq 0$ case. Additionally, the total mass of species A retains a nonzero quantity in the $v < 0$ case, but it decreases to zero with time in the $v \geq 0$ case.

Key words: kinetic behaviour, cluster growth, scaling law, rate equation

中图分类号:  (Disperse systems; complex fluids)

  • 82.70.-y
82.20.Pm (Rate constants, reaction cross sections, and activation energies) 82.30.-b (Specific chemical reactions; reaction mechanisms)