Study of the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser

doi:10.1088/1009-1963/13/6/031

中国物理B ›› 2004, Vol. 13 ›› Issue (6): 968-973.doi: 10.1088/1009-1963/13/6/031

Study of the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser

阎晓娜¹, 邱建荣¹, 姜雄伟¹, 朱从善¹, 陈彬², 余昺鲲²

(1)Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China; (2)Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China; Department of Physics, College of Sciences, Shanghai University, Shanghai 200436, China

收稿日期:2003-07-10 修回日期:2003-11-18 出版日期:2004-07-05 发布日期:2005-07-05

Study of the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser

Chen Bin (陈彬)^ab, Yu Bing-Kun (余昺鲲)^ab, Yan Xiao-Na (阎晓娜)^a, Qiu Jian-Rong (邱建荣)^a, Jiang Xiong-Wei (姜雄伟)^a, Zhu Cong-Shan (朱从善)^a

^a Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China; ^b Department of Physics, College of Sciences, Shanghai University, Shanghai 200436, China

Received:2003-07-10 Revised:2003-11-18 Online:2004-07-05 Published:2005-07-05

摘要/Abstract

摘要： This paper describes the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser. Such structural transformations were verified by Raman spectroscopy. The borate glass is transformed into low temperature (LT) phase of barium metaborate (BaB_2O_4) crystals after being irradiated for 10 min by a femtosecond laser. In addition, after 20 min of irradiation, high temperature (HT) phase of BaB_2O_4 crystals is also produced. Further studies demonstrate that LT phase BaB_2O_4 crystals are formed in the HT phase BaB_2O_4 crystals after femtosecond laser irradiation for 10 s.

关键词: femtosecond laser, borate glass, barium metaborate crystal, Raman spectra

Abstract: This paper describes the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser. Such structural transformations were verified by Raman spectroscopy. The borate glass is transformed into low temperature (LT) phase of barium metaborate (BaB$_2$O$_4$) crystals after being irradiated for 10 min by a femtosecond laser. In addition, after 20 min of irradiation, high temperature (HT) phase of BaB$_2$O$_4$ crystals is also produced. Further studies demonstrate that LT phase BaB$_2$O$_4$ crystals are formed in the HT phase BaB$_2$O$_4$ crystals after femtosecond laser irradiation for 10 s.

Key words: femtosecond laser, borate glass, barium metaborate crystal, Raman spectra

中图分类号: (Crystallographic aspects of phase transformations; pressure effects)

61.50.Ks

42.65.Re (Ultrafast processes; optical pulse generation and pulse compression) 42.70.Ce (Glasses, quartz) 78.30.Hv (Other nonmetallic inorganics) 81.40.-z (Treatment of materials and its effects on microstructure, nanostructure, And properties)

陈彬, 余昺鲲, 阎晓娜, 邱建荣, 姜雄伟, 朱从善. Study of the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser[J]. 中国物理B, 2004, 13(6): 968-973.

Chen Bin (陈彬), Yu Bing-Kun (余昺鲲), Yan Xiao-Na (阎晓娜), Qiu Jian-Rong (邱建荣), Jiang Xiong-Wei (姜雄伟), Zhu Cong-Shan (朱从善). Study of the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser[J]. Chinese Physics, 2004, 13(6): 968-973.

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Study of the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser

Study of the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser

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