TWO PHOTONS EXCITED 4d RYDBERG STATE OF AsH3

doi:10.1088/1004-423X/7/8/002

中国物理B ›› 1998, Vol. 7 ›› Issue (8): 567-571.doi: 10.1088/1004-423X/7/8/002

TWO PHOTONS EXCITED 4d RYDBERG STATE OF AsH₃

冉琴, 裴林森, 王非, 陈埜, 陈从香, 俞书勤, 马兴孝

Department of Chemical Physics, University of Science and Technology of China, Hefei 230026,China

收稿日期:1997-12-22 修回日期:1998-04-06 出版日期:1998-08-20 发布日期:1998-08-20
基金资助:
Project supported by the National Natural Science Foundation of China under Grunt No.29B43001 and Young Foundation of University of Science and Technology of China.

TWO PHOTONS EXCITED 4d RYDBERG STATE OF AsH₃

Ran Qin (冉琴), Pei Lin-sen (裴林森), Wang Fei (王非), Chen Yang (陈埜), Chen Cong-xiang (陈从香), Yu Shu-qin (俞书勤), Ma Xing-xiao (马兴孝)

Department of Chemical Physics, University of Science and Technology of China, Hefei 230026,China

Received:1997-12-22 Revised:1998-04-06 Online:1998-08-20 Published:1998-08-20
Supported by:
Project supported by the National Natural Science Foundation of China under Grunt No.29B43001 and Young Foundation of University of Science and Technology of China.

摘要/Abstract

摘要： In this paper, by using resonance enhanced (2+1) multiphoton ionization (REMPI) of AsH₃ and detecting the daughter molecular ions AsH⁺ and As⁺, a long progression discrete structure was obtained from 267 to 291 nm, which obeys the formula ν₀(cm^-1)=68875.3+504.1v′₂+5.26v′²₂. Analysis of the spectrum has revealed that it belongs to 4d Rydberg state transition. Our assignment yields the 4d Rydberg state parameters T_e′=67881.1 cm^-1, ω_e′=495.1 cm^-1 and δ=0.962. Finally the 4d Rydberg state structure of AsH₃ was discussed.

Abstract: In this paper, by using resonance enhanced (2+1) multiphoton ionization (REMPI) of AsH₃ and detecting the daughter molecular ions AsH⁺ and As⁺, a long progression discrete structure was obtained from 267 to 291 nm, which obeys the formula $\nu$₀(cm^-1)=68875.3+504.1v′₂+5.26v′²₂. Analysis of the spectrum has revealed that it belongs to 4d Rydberg state transition. Our assignment yields the 4d Rydberg state parameters T_e′=67881.1 cm^-1, $\omega$_e′=495.1 cm^-1 and $\delta$=0.962. Finally the 4d Rydberg state structure of AsH₃ was discussed.

中图分类号: (Multiphoton ionization and excitation to highly excited states (e.g., Rydberg states))

33.80.Rv

33.15.Mt (Rotation, vibration, and vibration-rotation constants) 33.20.Tp (Vibrational analysis)

冉琴, 裴林森, 王非, 陈埜, 陈从香, 俞书勤, 马兴孝. TWO PHOTONS EXCITED 4d RYDBERG STATE OF AsH₃[J]. 中国物理B, 1998, 7(8): 567-571.

Ran Qin (冉琴), Pei Lin-sen (裴林森), Wang Fei (王非), Chen Yang (陈埜), Chen Cong-xiang (陈从香), Yu Shu-qin (俞书勤), Ma Xing-xiao (马兴孝). TWO PHOTONS EXCITED 4d RYDBERG STATE OF AsH₃[J]. Acta Physica Sinica (Overseas Edition), 1998, 7(8): 567-571.

[1]	Keyu Guo(郭珂雨), Min Li(黎敏), Jintai Liang(梁锦台), Chuanpeng Cao(曹传鹏), Yueming Zhou(周月明), and Peixiang Lu((陆培祥). Wavelength- and ellipticity-dependent photoelectron spectra from multiphoton ionization of atoms[J]. 中国物理B, 2023, 32(2): 23201-023201.
[2]	Cai-Ping Zhang(张彩萍) and Xiang-Yang Miao(苗向阳). Decoding the electron dynamics in high-order harmonic generation from asymmetric molecular ions in elliptically polarized laser fields[J]. 中国物理B, 2022, 31(4): 43301-043301.
[3]	Bo Yan(闫博), Yi-Chen Wang(王一琛), Qing-Hua Gao(高庆华), Fang-Jing Cheng(程方晶), Qiu-Shuang Jing(景秋霜), Hong-Jing Liang(梁红静), and Ri Ma(马日). Minimum structure of high-harmonic spectrafrom aligned O₂ and N₂ molecules[J]. 中国物理B, 2021, 30(11): 114213-114213.
[4]	李鹏程, Shih-I Chu. Multiphoton quantum dynamics of many-electron atomic and molecular systems in intense laser fields[J]. 中国物理B, 2020, 29(8): 83202-083202.
[5]	李健, 马凤才. Filling gap of combination of gauge and analytical method in KFR-like theory[J]. 中国物理B, 2020, 29(4): 43205-043205.
[6]	梁红静, 范鑫, 冯爽, 单立宇, 高庆华, 闫博, 马日, 徐海峰. Quantum interference of multi-orbital effects in high-harmonic spectra from aligned carbon dioxide and nitrous oxide[J]. 中国物理B, 2019, 28(9): 94207-094207.
[7]	马俊杨, 林康, 季琴颖, 张文斌, 李韩笑, 孙烽豪, 强俊杰, 陆培芬, 李辉, 宫晓春, 吴健. Coulomb exploded directional double ionization of N₂O molecules in multicycle femtosecond laser pulses[J]. 中国物理B, 2019, 28(9): 93301-093301.
[8]	梁红静, 范鑫, 冯爽, 单立宇, 高庆华, 闫博, 马日, 徐海峰, 丁大军. Resolving multi-orbital effects on high harmonic generation from aligned N₂ molecules in linearly and elliptically polarized intense laser fields[J]. 中国物理B, 2019, 28(9): 94211-094211.
[9]	宋乐乐, 孙亚楠, 王艳辉, 王晓春, 赫兰海, 罗嗣佐, 胡文惠, 佟秋男, 丁大军, 刘福春. Photoelectron imaging of resonance-enhanced multiphoton ionization and above-threshold ionization of ammonia molecules in a strong 800-nm laser pulse[J]. 中国物理B, 2019, 28(6): 63201-063201.
[10]	王瑞, 张世文, 刘洋, 孙添, 吕航, 徐海峰. Effect of laser polarization on strong-field ionization and fragmentation of nitrous oxide molecules[J]. 中国物理B, 2019, 28(5): 53301-053301.
[11]	Jarosław H Bauer, 邓敏. Numerical tests of theoretical models describing ionization of H(1s) atom by linearly polarized flat pulse of laser radiation[J]. 中国物理B, 2018, 27(9): 93202-093202.
[12]	左万龙, 吕航, 梁红静, 单石敏, 马日, 闫冰, 徐海峰. Enhanced ionization of vibrational hot carbon disulfide molecules in strong femtosecond laser fields[J]. 中国物理B, 2018, 27(6): 63301-063301.
[13]	张彩萍, 夏昌龙, 贾祥富, 苗向阳. Effect of multiple rescattering processes on harmonic emission in spatially inhomogeneous field[J]. 中国物理B, 2018, 27(3): 34206-034206.
[14]	霍一宁, 李健, 马凤才. Photoelectron longitudinal momentum distributions containing nondipole effects[J]. 中国物理B, 2018, 27(1): 13203-013203.
[15]	崔会芳, 苗向阳. Influence of the initial electronic state on minima of high-order harmonic spectrum radiated from hydrogen molecular ion[J]. 中国物理B, 2017, 26(10): 103302-103302.

TWO PHOTONS EXCITED 4d RYDBERG STATE OF AsH₃

TWO PHOTONS EXCITED 4d RYDBERG STATE OF AsH₃

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 0