中国物理B ›› 2020, Vol. 29 ›› Issue (3): 37702-037702.doi: 10.1088/1674-1056/ab695e

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇    下一篇

Surface passivation in n-type silicon and its application insilicon drift detector

Yiqing Wu(吴怡清), Ke Tao(陶科), Shuai Jiang(姜帅), Rui Jia(贾锐), Ye Huang(黄也)   

  1. 1 School of Physical and Electronic Science, Changsha University of Science and Technology, Changsha 410114, China;
    2 Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China
  • 收稿日期:2019-10-12 修回日期:2019-12-20 出版日期:2020-03-05 发布日期:2020-03-05
  • 通讯作者: Ke Tao, Rui Jia E-mail:taoke@ime.ac.cn;imesolar@126.com
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant Nos. 51602340, 51702355, and 61674167), the Natural Science Foundation of Beijing Municipality of China (Grant No. 4192064), the National Key Research Program of China (Grant Nos. 2018YFB1500500 and 2018YFB1500200), and the JKW Project of China (Grant No. 31512060106).

Surface passivation in n-type silicon and its application insilicon drift detector

Yiqing Wu(吴怡清)1,2, Ke Tao(陶科)2, Shuai Jiang(姜帅)2, Rui Jia(贾锐)2, Ye Huang(黄也)1   

  1. 1 School of Physical and Electronic Science, Changsha University of Science and Technology, Changsha 410114, China;
    2 Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China
  • Received:2019-10-12 Revised:2019-12-20 Online:2020-03-05 Published:2020-03-05
  • Contact: Ke Tao, Rui Jia E-mail:taoke@ime.ac.cn;imesolar@126.com
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant Nos. 51602340, 51702355, and 61674167), the Natural Science Foundation of Beijing Municipality of China (Grant No. 4192064), the National Key Research Program of China (Grant Nos. 2018YFB1500500 and 2018YFB1500200), and the JKW Project of China (Grant No. 31512060106).

摘要: Based on the surface passivation of n-type silicon in a silicon drift detector (SDD), we propose a new passivation structure of SiO2/Al2O3/SiO2 passivation stacks. Since the SiO2 formed by the nitric-acid-oxidation-of-silicon (NAOS) method has good compactness and simple process, the first layer film is formed by the NAOS method. The Al2O3 film is also introduced into the passivation stacks owing to exceptional advantages such as good interface characteristic and simple process. In addition, for requirements of thickness and deposition temperature, the third layer of the SiO2 film is deposited by plasma enhanced chemical vapor deposition (PECVD). The deposition of the SiO2 film by PECVD is a low-temperature process and has a high deposition rate, which causes little damage to the device and makes the SiO2 film very suitable for serving as the third passivation layer. The passivation approach of stacks can saturate dangling bonds at the interface between stacks and the silicon substrate, and provide positive charge to optimize the field passivation of the n-type substrate. The passivation method ultimately achieves a good combination of chemical and field passivations. Experimental results show that with the passivation structure of SiO2/Al2O3/SiO2, the final minority carrier lifetime reaches 5223 μs at injection of 5×1015 cm-3. When it is applied to the passivation of SDD, the leakage current is reduced to the order of nA.

关键词: SiO2/Al2O3/SiO2 stacks, chemical passivation, field passivation, silicon drift detector

Abstract: Based on the surface passivation of n-type silicon in a silicon drift detector (SDD), we propose a new passivation structure of SiO2/Al2O3/SiO2 passivation stacks. Since the SiO2 formed by the nitric-acid-oxidation-of-silicon (NAOS) method has good compactness and simple process, the first layer film is formed by the NAOS method. The Al2O3 film is also introduced into the passivation stacks owing to exceptional advantages such as good interface characteristic and simple process. In addition, for requirements of thickness and deposition temperature, the third layer of the SiO2 film is deposited by plasma enhanced chemical vapor deposition (PECVD). The deposition of the SiO2 film by PECVD is a low-temperature process and has a high deposition rate, which causes little damage to the device and makes the SiO2 film very suitable for serving as the third passivation layer. The passivation approach of stacks can saturate dangling bonds at the interface between stacks and the silicon substrate, and provide positive charge to optimize the field passivation of the n-type substrate. The passivation method ultimately achieves a good combination of chemical and field passivations. Experimental results show that with the passivation structure of SiO2/Al2O3/SiO2, the final minority carrier lifetime reaches 5223 μs at injection of 5×1015 cm-3. When it is applied to the passivation of SDD, the leakage current is reduced to the order of nA.

Key words: SiO2/Al2O3/SiO2 stacks, chemical passivation, field passivation, silicon drift detector

中图分类号:  (Dielectric thin films)

  • 77.55.-g
77.22.-d (Dielectric properties of solids and liquids) 77.22.-d (Dielectric properties of solids and liquids) 85.40.-e (Microelectronics: LSI, VLSI, ULSI; integrated circuit fabrication technology)