Liquid-liquid phase transition in confined liquid titanium

doi:10.1088/1674-1056/ac6dc0

中国物理B ›› 2023, Vol. 32 ›› Issue (2): 26801-026801.doi: 10.1088/1674-1056/ac6dc0

Liquid-liquid phase transition in confined liquid titanium

Di Zhang(张迪)¹, Yunrui Duan(段云瑞)², Peiru Zheng(郑培儒)¹, Yingjie Ma(马英杰)¹, Junping Qian(钱俊平)¹, Zhichao Li(李志超)¹, Jian Huang(黄建)¹, Yanyan Jiang(蒋妍彦)^1,†, and Hui Li(李辉)^1,‡

1 Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan 250061, China;
2 College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China

收稿日期:2022-02-11 修回日期:2022-04-21 接受日期:2022-05-07 出版日期:2023-01-10 发布日期:2023-01-18
通讯作者: Yanyan Jiang, Hui Li E-mail:yanyan.jiang@sdu.edu.cn;lihuilmy@hotmail.com
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. U1806219 and 52171038), the Special Funding in the Project of the Taishan Scholar Construction Engineering and the Program of Jinan Science and Technology Bureau (Grant No. 2020GXRC019), and Key R&D Projects in Shandong Province, China (Grant No. 2021SFGC1001).

Liquid-liquid phase transition in confined liquid titanium

1 Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan 250061, China;
2 College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Received:2022-02-11 Revised:2022-04-21 Accepted:2022-05-07 Online:2023-01-10 Published:2023-01-18
Contact: Yanyan Jiang, Hui Li E-mail:yanyan.jiang@sdu.edu.cn;lihuilmy@hotmail.com
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. U1806219 and 52171038), the Special Funding in the Project of the Taishan Scholar Construction Engineering and the Program of Jinan Science and Technology Bureau (Grant No. 2020GXRC019), and Key R&D Projects in Shandong Province, China (Grant No. 2021SFGC1001).

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摘要/Abstract

摘要： We report the layering and liquid-liquid phase transition of liquid titanium confined between two parallel panel walls. Abnormal changes in the volume and the potential energy confirm the existence of the liquid-liquid phase transition of the liquid titanium. The typical feature of the liquid-liquid phase transition is layering, which is induced by the slit size, pressure and temperature. We highlight the fact that the slit size and pressure will determine the number of layers. In addition, with the change in the slit size, the density of the confined liquid expresses a fluctuating law. The phase diagram of the layering transition is drawn to clearly understand the layering. This study provides insights into the liquid-liquid phase transition of liquid metal in a confined space.

关键词: titanium, layering transition, liquid-liquid phase transition, confined space

Abstract: We report the layering and liquid-liquid phase transition of liquid titanium confined between two parallel panel walls. Abnormal changes in the volume and the potential energy confirm the existence of the liquid-liquid phase transition of the liquid titanium. The typical feature of the liquid-liquid phase transition is layering, which is induced by the slit size, pressure and temperature. We highlight the fact that the slit size and pressure will determine the number of layers. In addition, with the change in the slit size, the density of the confined liquid expresses a fluctuating law. The phase diagram of the layering transition is drawn to clearly understand the layering. This study provides insights into the liquid-liquid phase transition of liquid metal in a confined space.

Key words: titanium, layering transition, liquid-liquid phase transition, confined space

中图分类号: (Phase transitions in liquid thin films)

68.18.Jk

61.30.Hn (Surface phenomena: alignment, anchoring, anchoring transitions, surface-induced layering, surface-induced ordering, wetting, prewetting transitions, and wetting transitions) 61.25.Mv (Liquid metals and alloys) 61.30.Pq (Microconfined liquid crystals: droplets, cylinders, randomly confined liquid crystals, polymer dispersed liquid crystals, and porous systems)

Di Zhang(张迪), Yunrui Duan(段云瑞), Peiru Zheng(郑培儒), Yingjie Ma(马英杰), Junping Qian(钱俊平), Zhichao Li(李志超), Jian Huang(黄建), Yanyan Jiang(蒋妍彦), and Hui Li(李辉). Liquid-liquid phase transition in confined liquid titanium[J]. 中国物理B, 2023, 32(2): 26801-026801.

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Liquid-liquid phase transition in confined liquid titanium

Liquid-liquid phase transition in confined liquid titanium

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