Microwave-assisted synthesis of Mg:PbI2 nanostructures and their structural, morphological, optical, dielectric and electrical properties for optoelectronic technology

doi:10.1088/1674-1056/aba60e

中国物理B ›› 2020, Vol. 29 ›› Issue (11): 116102-.doi: 10.1088/1674-1056/aba60e

Mohd. Shkir¹^,†(), Ziaul Raza Khan², T Alshahrani³, Kamlesh V. Chandekar⁴, M Aslam Manthrammel¹, Ashwani Kumar⁵, S AlFaify¹

收稿日期:2020-05-23 修回日期:2020-07-07 接受日期:2020-07-15 出版日期:2020-11-05 发布日期:2020-11-03

Microwave-assisted synthesis of Mg:PbI₂ nanostructures and their structural, morphological, optical, dielectric and electrical properties for optoelectronic technology

Mohd. Shkir^{1, †}, Ziaul Raza Khan², T Alshahrani³, Kamlesh V. Chandekar⁴, M Aslam Manthrammel¹, Ashwani Kumar⁵, and S AlFaify¹$

1 Advanced Functional Materials and Optoelectronics Laboratory (AFMOL), Department of Physics, College of Science, King Khalid University, Abha 61413, P.O. Box 9004, Saudi Arabia
2 Department of Physics, College of Science, University of Hail, P.O. Box 2440, Hail, Saudi Arabia
3 Department of Physics, College of Science, Princess Nourah Bint Abdulrahman University, Riyadh 11671, Saudi Arabia
4 Department of Physics, Rayat Shikshan Sanstha’s, Karmaveer Bhaurao Patil College, Vashi, Navi Mumbai 400703, India
5 Department of Physics, IK Gujral Punjab Technical University, Jalandhar 144603, India

Received:2020-05-23 Revised:2020-07-07 Accepted:2020-07-15 Online:2020-11-05 Published:2020-11-03
Contact: ^†Corresponding author. E-mail: shkirphysics@gmail.com
Supported by:
the Deanship of Scientific Research at King Khalid University (Grant No. R.G.P1/207/41), the Deanship of Scientific Research at Princess Nourah bint Abdulrahman University through the Fast-track Research Funding Program, and Deanship of Research, University of Hail.

摘要/Abstract

Abstract:

This work reports the cost-effective growth of Mg:PbI₂ nanostructures with 0, 1, 2.5 and 5.0 wt.% Mg doping concentrations. Structural, vibrational, morphological properties are analyzed using x-ray diffraction (XRD), Raman spectroscopy and scanning electron microscopy (SEM). XRD and Raman studies confirm the monophasic hexagonal system of Mg:PbI₂, and no additional impurity peaks are detected. The Scherrer formula is used to determine sizes of crystallites to be in the range of 47–52 nm. EDX/SEM e-mapping analyses confirm the incorporation of Mg in PbI₂ matrix and its uniform distribution throughout the sample. The hexagonal nanosheet- and nanoplate-like morphologies are detected in SEM images for pure and Mg-doped PbI₂. An optical band gap of nanostructures is obtained from Tauc’s relation to be in the range 3.0–3.25 eV. Dielectric and electrical properties are found in significant enhancement as Mg doping in PbI₂ matrix, also the conduction mechanism is discussed.

Key words: Mg:PbI₂ nanostructures, structural properties, optical band gap, dielectric constant, ac conductivity

Mohd. Shkir, Ziaul Raza Khan, T Alshahrani, Kamlesh V. Chandekar, M Aslam Manthrammel, Ashwani Kumar, S AlFaify. [J]. 中国物理B, 2020, 29(11): 116102-.

Mohd. Shkir, Ziaul Raza Khan, T Alshahrani, Kamlesh V. Chandekar, M Aslam Manthrammel, Ashwani Kumar, and S AlFaify$. Microwave-assisted synthesis of Mg:PbI₂ nanostructures and their structural, morphological, optical, dielectric and electrical properties for optoelectronic technology[J]. Chin. Phys. B, 2020, 29(11): 116102-.

图/表 7

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Sample	POWDERX software			Rietveld refined			D₁₀₁/nm	δ₁₀₁/10⁻⁴ nm⁻²	ε₁₀₁/10⁻³
Pb_1–xMg_xI₂	a/Å	c/Å	V/Å³	a/Å	c/Å	V/Å³	D₁₀₁/nm	δ₁₀₁/10⁻⁴ nm⁻²	ε₁₀₁/10⁻³
JCPSD#7-0235	4.5570	6.9790	125.5100	–	–	–	–	–	–
x = 0.0 wt.%	4.5572	6.9786	125.5160	4.5556	6.9767	125.3918	51.23	3.81	3.02
x = 1.0 wt.%	4.5577	6.9778	125.5310	4.5578	6.9812	125.5946	49.25	4.12	3.15
x = 2.5 wt.%	4.5574	6.9803	125.5605	4.5550	6.9769	125.3650	48.20	4.30	3.21
x = 5.0 wt.%	4.5590	6.9822	125.6817	4.5553	6.9782	125.4019	47.47	4.44	3.27

Microwave-assisted synthesis of Mg:PbI₂ nanostructures and their structural, morphological, optical, dielectric and electrical properties for optoelectronic technology

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