中国物理B ›› 2020, Vol. 29 ›› Issue (1): 10704-010704.doi: 10.1088/1674-1056/ab5ef6

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Atmospheric N2O gas detection based on an inter-band cascade laser around 3.939 μm

Chun-Yan Sun(孙春艳), Yuan Cao(曹渊), Jia-Jin Chen(陈家金), Jing-Jing Wang(王静静), Gang Cheng(程刚), Gui-Shi Wang(王贵师), Xiao-Ming Gao(高晓明)   

  1. 1 Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;
    2 University of Science and Technology of China, Hefei 230031, China;
    3 Huainan Normal University, Huainan 232001, China
  • 收稿日期:2019-08-10 修回日期:2019-10-22 出版日期:2020-01-05 发布日期:2020-01-05
  • 通讯作者: Gui-Shi Wang E-mail:gswang@aiofm.ac.cn
  • 基金资助:
    Project supported by the National Key Research and Development Program of China (Grant Nos. 2018YFC0213304, 2017YFC0209703, and 2016TFC0303900).

Atmospheric N2O gas detection based on an inter-band cascade laser around 3.939 μm

Chun-Yan Sun(孙春艳)1,2,3, Yuan Cao(曹渊)1,2, Jia-Jin Chen(陈家金)1, Jing-Jing Wang(王静静)1,2, Gang Cheng(程刚)1,2, Gui-Shi Wang(王贵师)1, Xiao-Ming Gao(高晓明)1   

  1. 1 Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;
    2 University of Science and Technology of China, Hefei 230031, China;
    3 Huainan Normal University, Huainan 232001, China
  • Received:2019-08-10 Revised:2019-10-22 Online:2020-01-05 Published:2020-01-05
  • Contact: Gui-Shi Wang E-mail:gswang@aiofm.ac.cn
  • Supported by:
    Project supported by the National Key Research and Development Program of China (Grant Nos. 2018YFC0213304, 2017YFC0209703, and 2016TFC0303900).

摘要: N2O is a significant atmospheric greenhouse gas that contributes to global warming and climate change. In this work, the high sensitivity detection of atmospheric N2O is achieved using wavelength modulation spectroscopy (WMS) with an inter-band cascade laser operating around 3.939 μm. A LabVIEW-based software signal generator and software lock-in amplifiers are designed to simplify the system. In order to eliminate the interference from water vapor, the detection was performed at a pressure of 0.1 atm (1 atm=1.01325×105 Pa) and a drying tube was added to the system. To improve the system performance for long term detection, a novel frequency locking method and 2f/1f calibration-free method were employed to lock the laser frequency and calibrate the power fluctuations, respectively. The Allan deviation analysis of the results indicates a detection limit of ~20 ppb (1 ppb=1.81205 μg/m3) for a 1 s integration time, and the optimal detection limit is ~5 ppb for a 40-s integration time.

关键词: wavelength modulation spectroscopy, inter-band cascade laser, frequency locking, nitrous oxide (N2O)

Abstract: N2O is a significant atmospheric greenhouse gas that contributes to global warming and climate change. In this work, the high sensitivity detection of atmospheric N2O is achieved using wavelength modulation spectroscopy (WMS) with an inter-band cascade laser operating around 3.939 μm. A LabVIEW-based software signal generator and software lock-in amplifiers are designed to simplify the system. In order to eliminate the interference from water vapor, the detection was performed at a pressure of 0.1 atm (1 atm=1.01325×105 Pa) and a drying tube was added to the system. To improve the system performance for long term detection, a novel frequency locking method and 2f/1f calibration-free method were employed to lock the laser frequency and calibrate the power fluctuations, respectively. The Allan deviation analysis of the results indicates a detection limit of ~20 ppb (1 ppb=1.81205 μg/m3) for a 1 s integration time, and the optimal detection limit is ~5 ppb for a 40-s integration time.

Key words: wavelength modulation spectroscopy, inter-band cascade laser, frequency locking, nitrous oxide (N2O)

中图分类号:  (Instruments for environmental pollution measurements)

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42.87.-d (Optical testing techniques) 42.72.Bj (Visible and ultraviolet sources) 33.20.Lg (Ultraviolet spectra)