Effect of Hf4+ doping on structure and enhancement of upconversion luminescence in Yb: Tm: LiNbO3 crystals

doi:10.1088/1674-1056/27/11/114217

中国物理B ›› 2018, Vol. 27 ›› Issue (11): 114217-114217.doi: 10.1088/1674-1056/27/11/114217

• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇下一篇

Effect of Hf⁴⁺ doping on structure and enhancement of upconversion luminescence in Yb: Tm: LiNbO₃ crystals

Li Dai(代丽), Chunrui Liu(刘春蕊), Xianbo Han(韩县博), Luping Wang(王路平), Yu Shao(邵瑀), Yuheng Xu(徐玉恒)

1 College of Science, Harbin University of Science and Technology, Harbin 150080, China;
2 School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 150040, China;
3 Department of the Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China

收稿日期:2018-04-26 修回日期:2018-07-03 出版日期:2018-11-05 发布日期:2018-11-05
通讯作者: Li Dai E-mail:daili198108@126.com
基金资助:
Project supported by Special Funds of Harbin Innovation Talents in Science and Technology Research, China (Grant No. 2015RQQXJ045) and Science Funds for the Young Innovative Talents of HUST, China.

Effect of Hf⁴⁺ doping on structure and enhancement of upconversion luminescence in Yb: Tm: LiNbO₃ crystals

Li Dai(代丽)¹, Chunrui Liu(刘春蕊)¹, Xianbo Han(韩县博)¹, Luping Wang(王路平)², Yu Shao(邵瑀)¹, Yuheng Xu(徐玉恒)³

1 College of Science, Harbin University of Science and Technology, Harbin 150080, China;
2 School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 150040, China;
3 Department of the Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China

Received:2018-04-26 Revised:2018-07-03 Online:2018-11-05 Published:2018-11-05
Contact: Li Dai E-mail:daili198108@126.com
Supported by:
Project supported by Special Funds of Harbin Innovation Talents in Science and Technology Research, China (Grant No. 2015RQQXJ045) and Science Funds for the Young Innovative Talents of HUST, China.

摘要/Abstract

摘要：

A series of Yb:Tm:LiNbO₃ crystals doped with x mol% Hf⁴⁺ ions (x=2, 4, and 6) were grown by the Czochralski method. The dopant occupancy and defect structure of Hf:Yb:Tm:LiNbO₃ crystals were investigated by x-ray diffraction and infrared transmission spectra. The influence of Hf⁴⁺ ions concentration on UV-VIS-NIR absorption spectra of Hf:Yb:Tm:LiNbO₃ crystals was discussed. The upconversion luminescence of Hf:Yb:Tm:LiNbO₃ crystals was obtained under 980 nm excitation. Strong emissions were observed at 475 nm in the blue wavelength range and 651 nm in the red wavelength range. Remarkably, enhancement of the red and blue upconversion luminescence was achieved by tridoping Hf⁴⁺ ions.

关键词: Hf:Yb:Tm:LiNbO₃ crystals, crystal structure, upconversion luminescence

Abstract:

Key words: Hf:Yb:Tm:LiNbO₃ crystals, crystal structure, upconversion luminescence

中图分类号: (Optical materials)

42.70.-a

61.50.Ah (Theory of crystal structure, crystal symmetry; calculations and modeling) 78.55.-m (Photoluminescence, properties and materials)

代丽, 刘春蕊, 韩县博, 王路平, 邵瑀, 徐玉恒. Effect of Hf⁴⁺ doping on structure and enhancement of upconversion luminescence in Yb: Tm: LiNbO₃ crystals[J]. 中国物理B, 2018, 27(11): 114217-114217.

Li Dai(代丽), Chunrui Liu(刘春蕊), Xianbo Han(韩县博), Luping Wang(王路平), Yu Shao(邵瑀), Yuheng Xu(徐玉恒). Effect of Hf⁴⁺ doping on structure and enhancement of upconversion luminescence in Yb: Tm: LiNbO₃ crystals[J]. Chin. Phys. B, 2018, 27(11): 114217-114217.

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Effect of Hf⁴⁺ doping on structure and enhancement of upconversion luminescence in Yb: Tm: LiNbO₃ crystals

Effect of Hf⁴⁺ doping on structure and enhancement of upconversion luminescence in Yb: Tm: LiNbO₃ crystals

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