Gas treatment protection of metallic lithium anode

doi:10.1088/1674-1056/26/8/088202

中国物理B ›› 2017, Vol. 26 ›› Issue (8): 88202-088202.doi: 10.1088/1674-1056/26/8/088202

• SPECIAL TOPIC—Non-equilibrium phenomena in soft matters • 上一篇下一篇

Gas treatment protection of metallic lithium anode

Wen-jun Li(李文俊), Quan Li(李泉), Jie Huang(黄杰), Jia-yue Peng(彭佳悦), Geng Chu(褚赓), Ya-xiang Lu(陆雅翔), Jie-yun Zheng(郑杰允), Hong Li(李泓)

1 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2 University of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2017-05-20 修回日期:2017-05-31 出版日期:2017-08-05 发布日期:2017-08-05
通讯作者: Hong Li E-mail:hli@iphy.ac.cn
基金资助:
Project supported by the National Key Research and Development Program of China (Grant No. 2016YFB0100100), the National Natural Science Foundation of China (Grants Nos. 52315206 and 51502334), and the Fund from Beijing Municipal Science & Technology Commission, China (Grants No. D171100005517001).

Gas treatment protection of metallic lithium anode

Wen-jun Li(李文俊)^1,2, Quan Li(李泉)^1,2, Jie Huang(黄杰)^1,2, Jia-yue Peng(彭佳悦)^1,2, Geng Chu(褚赓)^1,2, Ya-xiang Lu(陆雅翔)¹, Jie-yun Zheng(郑杰允)¹, Hong Li(李泓)¹

1 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2 University of Chinese Academy of Sciences, Beijing 100049, China

Received:2017-05-20 Revised:2017-05-31 Online:2017-08-05 Published:2017-08-05
Contact: Hong Li E-mail:hli@iphy.ac.cn
About author:0.1088/1674-1056/26/8/
Supported by:
Project supported by the National Key Research and Development Program of China (Grant No. 2016YFB0100100), the National Natural Science Foundation of China (Grants Nos. 52315206 and 51502334), and the Fund from Beijing Municipal Science & Technology Commission, China (Grants No. D171100005517001).

摘要/Abstract

摘要：

The effects of different coating layers on lithium metal anode formed by reacting with different controlled atmospheres (argon, CO₂-O₂(2:1), N₂, and CO₂-O₂-N₂(2:1:3)) have been investigated. The obtained XRD, second ion mass spectroscopy (SIMS), and scanning probe microscope (SPM) results demonstrate the formation of coating layers composed of Li₂CO₃, Li₃N, and the mixture of them on lithium tablets, respectively. The Li/Li symmetrical cell and Li/S cell are assembled to prove the advantages of the protected lithium tablet on electrochemical performance. The comparison of SEM and SIMS characterizations before/after cycles clarifies that an SEI-like composition formed on the lithium tablets could modulate the interfacial stabilization between the lithium foil and the ether electrolyte.

关键词: gas treatment, lithium metal anode, lithium ion battery, lithium protection

Abstract:

Key words: gas treatment, lithium metal anode, lithium ion battery, lithium protection

中图分类号: (Lithium-ion batteries)

82.47.Aa

65.40.gk (Electrochemical properties) 82.45.Fk (Electrodes)

李文俊, 李泉, 黄杰, 彭佳悦, 褚赓, 陆雅翔, 郑杰允, 李泓. Gas treatment protection of metallic lithium anode[J]. 中国物理B, 2017, 26(8): 88202-088202.

Wen-jun Li(李文俊), Quan Li(李泉), Jie Huang(黄杰), Jia-yue Peng(彭佳悦), Geng Chu(褚赓), Ya-xiang Lu(陆雅翔), Jie-yun Zheng(郑杰允), Hong Li(李泓). Gas treatment protection of metallic lithium anode[J]. Chin. Phys. B, 2017, 26(8): 88202-088202.

参考文献 36

[1]	Yao X Y, Huang B X, Yin J Y, Peng G, Huang Z, Gao C, Liu D and Xu X X 2016 Chin. Phys. B 25 018802
[2]	Li H 2017 Nat. Sci. Rev. 4 106
[3]	Li H and Xu X X 2016 Energ. Storg. Sci. Tech. 5 607 (in Chinese)
[4]	Yin Y X, Yao H R and Guo Y G 2016 Chin. Phys. B 25 018801
[5]	Bruce P G, Freunberger S A, Hardwick L J and Tarascon J M 2012 Nat. Mater. 11 19
[6]	Li W, Zheng H, Chu G, Luo F, Zheng J, Xiao D, Li X, Gu L, Li H, Wei X, Chen Q and Chen L 2014 Faraday Discuss. 176 109
[7]	Ding F, Xu W, Chen X, Zhang J, Engelhard M H, Zhang Y, Johnson B R, Crum J V, Blake T A, Liu X and Zhang J G 2013 J. Electrochem. Soc. 160 A1894
[8]	Suo L, Hu Y S, Li H, Armand M and Chen L 2013 Nat. Commun. 4 1481
[9]	Walker W, Giordani V, Uddin J, Bryantsev V S, Chase G V and Addison D 2013 J. Am. Chem. Soc. 135 2076
[10]	Liu Z, Chai J, Xu G, Wang Q and Cui G 2015 Coord. Chem. Rev. 292 56
[11]	Zu C, Azimi N, Zhang Z and Manthiram A 2015 J. Mater. Chem. A 3 14864
[12]	Liu P, Ma Q, Fang Z, Ma J, Hu Y S, Zhou Z B, Li H, Huang X J and Chen L Q 2016 Chin. Phys. B 25 078203
[13]	Miao R, Yang J, Xu Z, Wang J, Nuli Y and Sun L 2016 Sci. Rep. 6 21771
[14]	Zhang S, Li W J, Ling S G, Li H, Zhou Z B and Chen L Q 2015 Chin. Phys. B 24 078201
[15]	Zhao C Z, Cheng X B, Zhang R, Peng H J, Huang J Q, Ran R, Huang Z H, Wei F and Zhang Q 2016 Energy Storage Materials 3 77
[16]	Zu C X and Manthiram A 2014 Journal of Physical Chemistry Letters 5 2522
[17]	Li W, Yao H, Yan K, Zheng G, Liang Z, Chiang Y M and Cui Y 2015 Nat. Commun. 6 7436
[18]	Lu Y, Tu Z, Shu J and Archer L A 2015 J. Power Sources 279 413
[19]	Xu W T, Peng H J, Huang J Q, Zhao C Z, Cheng X B and Zhang Q 2015 ChemSusChem 8 2892
[20]	Choudhury S and Archer L A 2016 Adv. Electron. Mater. 2 1500246
[21]	Zhang X Q, Cheng X B, Chen X, Yan C and Zhang Q 2017 Adv. Funct. Mater. 27 1605989
[22]	Wu J Y, Lin S G, Yang Q, Li H, Xu X X and Chen L Q 2016 Chin. Phys. B 25 078204
[23]	Liu K, Zhuo D, Lee H W, Liu W, Lin D, Lu Y and Cui Y 2016 Adv. Mater. 29
[24]	Chen C, Yang Y F and Shao H X 2014 Electrochim. Acta 137 476
[25]	Stone G M, Mullin S A, Teran A A, Hallinan D T, Minor A M, Hexemer A and Balsara N P 2012 J. Electrochem. Soc. 159 A222
[26]	Lu Y, Tu Z and Archer L A 2014 Nat. Mater. 13 961
[27]	Huang J, Peng J Y, Ling S G, Yang Q, Qiu J L, Lu J Z, Zheng J Y, Li Hong and Chen L Q 2017 Chin. Phys. B 26 068201
[28]	Ma G, Wen Z, Wu M, Shen C, Wang Q, Jin J and Wu X 2014 Chem. Commun. 50 14209
[29]	Zheng G, Lee S W, Liang Z, Lee H W, Yan K, Yao H, Wang H, Li W, Chu S and Cui Y 2014 Nat. Nanotechnol. 9 618
[30]	Kazyak E, Wood K N and Dasgupta N P 2015 Chem. Mater. 27 6457
[31]	Kozen A C, Lin C F, Pearse A J, Schroeder M A, Han X, Hu L, Lee S B, Rubloff G W and Noked M 2015 ACS Nano 9 5884
[32]	Liu Q C, Xu J J, Yuan S, Chang Z W, Xu D, Yin Y B, Li L, Zhong H X, Jiang Y S, Yan J M and Zhang X B 2015 Adv. Mater. 27 5241
[33]	Cheng X B Zhang Q 2015 J. Mater. Chem. A 3 7207
[34]	Han X G, Gong Y H, Fu K, He X F, Hitz G T, Dai J Q, Pearse A, Liu B Y, Wang H, Rubloff G, Mo Y F, Thangadurai V, Wachsman E D and Hu L 2016 Nat. Mater. 16 572
[35]	Li N W, Yin Y X, Yang C P and Guo Y G 2016 Adv. Mater. 28 1853
[36]	Zheng G, Wang C, Pei A, Lopez J, Shi F, Chen Z, Sendek A D, Lee H W, Lu Z, Schneider H, Safont-Sempere M M, Chu S, Bao Z and Cui Y 2016 ACS Energy Lett. 1 1247

Gas treatment protection of metallic lithium anode

Gas treatment protection of metallic lithium anode

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