Raman phonons in multiferroic FeVO4 crystals

doi:10.1088/1674-1056/24/12/126301

中国物理B ›› 2015, Vol. 24 ›› Issue (12): 126301-126301.doi: 10.1088/1674-1056/24/12/126301

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Raman phonons in multiferroic FeVO₄ crystals

张安民^a, 刘凯^a, 籍建葶^a, 何长振^b, 田勇^a, 金峰^a, 张清明^a

a Department of Physics, Beijing Key Laboratory of Opto-Electronic Functional Materials and Micro-nano Devices, Renmin University of China, Beijing 100872, China;
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

收稿日期:2015-09-27 修回日期:2015-10-08 出版日期:2015-12-05 发布日期:2015-12-05
通讯作者: Zhang Qing-Ming E-mail:qmzhang@ruc.edu.cn
基金资助:
Project supported by the National Basic Research Program of China (Grant No. 2012CB921701), the National Natural Science Foundation of China (Grant Nos. 11174367 and 11004243), the China Postdoctoral Science Foundation, the Fundamental Research Funds for the Central Universities, and the Research Funds of Renmin University of China (Grant Nos. 10XNI038, 14XNLF06, and 14XNLQ03).

Raman phonons in multiferroic FeVO₄ crystals

Zhang An-Min (张安民)^a, Liu Kai (刘凯)^a, Ji Jian-Ting (籍建葶)^a, He Chang-Zhen (何长振)^b, Tian Yong (田勇)^a, Jin Feng (金峰)^a, Zhang Qing-Ming (张清明)^a

a Department of Physics, Beijing Key Laboratory of Opto-Electronic Functional Materials and Micro-nano Devices, Renmin University of China, Beijing 100872, China;
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received:2015-09-27 Revised:2015-10-08 Online:2015-12-05 Published:2015-12-05
Contact: Zhang Qing-Ming E-mail:qmzhang@ruc.edu.cn
Supported by:
Project supported by the National Basic Research Program of China (Grant No. 2012CB921701), the National Natural Science Foundation of China (Grant Nos. 11174367 and 11004243), the China Postdoctoral Science Foundation, the Fundamental Research Funds for the Central Universities, and the Research Funds of Renmin University of China (Grant Nos. 10XNI038, 14XNLF06, and 14XNLQ03).

摘要/Abstract

摘要：

Multiferroic materials are promising candidates for next-generation multi-functional devices, because of the coexistence of multi-orders and the coupling between the orders. FeVO₄ has been confirmed to be a multiferroic compound, since it exhibits both ferroelectricity and antiferromagnetic ordering at low temperatures. In this paper, we have performed careful Raman scattering measurements on high-quality FeVO₄ single crystals. The compound has a very rich phonon structure due to its low crystal symmetry (P-1) and at least 47 Raman-active phonon modes have been resolved in the low and hightemperature spectra. Most of the observed modes are well assigned with aid of first-principles calculations and symmetry analysis. The present study provides an experimental basis for exploring spin-lattice coupling and the mechanism of multiferroicity in FeVO₄

关键词: Raman scattering, phonon assignment multiferroics

Abstract:

Key words: Raman scattering, phonon assignment multiferroics

中图分类号: (Measurements)

63.20.dd

63.20.dk (First-principles theory) 75.85.+t (Magnetoelectric effects, multiferroics) 78.30.Hv (Other nonmetallic inorganics)

张安民, 刘凯, 籍建葶, 何长振, 田勇, 金峰, 张清明. Raman phonons in multiferroic FeVO₄ crystals[J]. 中国物理B, 2015, 24(12): 126301-126301.

Zhang An-Min (张安民), Liu Kai (刘凯), Ji Jian-Ting (籍建葶), He Chang-Zhen (何长振), Tian Yong (田勇), Jin Feng (金峰), Zhang Qing-Ming (张清明). Raman phonons in multiferroic FeVO₄ crystals[J]. Chin. Phys. B, 2015, 24(12): 126301-126301.

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Raman phonons in multiferroic FeVO₄ crystals

Raman phonons in multiferroic FeVO₄ crystals

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