Resisting shrinkage properties of volume holograms recorded in TiO2 nanoparticle-dispersed acrylamide-based photopolymer

doi:10.1088/1674-1056/22/12/124207

中国物理B ›› 2013, Vol. 22 ›› Issue (12): 124207-124207.doi: 10.1088/1674-1056/22/12/124207

• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇下一篇

Resisting shrinkage properties of volume holograms recorded in TiO₂ nanoparticle-dispersed acrylamide-based photopolymer

赵磊^{a b}, 韩俊鹤^a, 李若平^a, 王龙阁^a, 黄明举^a

a Key Discipline Open Laboratory of Photonic and Electronic Information Materials and Devices, Henan University, Kaifeng 475004, China;
b College of Peili Engineering Technology, Lanzhou City University, Lanzhou 730070, China

收稿日期:2012-12-24 修回日期:2013-04-04 出版日期:2013-10-25 发布日期:2013-10-25
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 61177004).

Resisting shrinkage properties of volume holograms recorded in TiO₂ nanoparticle-dispersed acrylamide-based photopolymer

Zhao Lei (赵磊)^{a b}, Han Jun-He (韩俊鹤)^a, Li Ruo-Ping (李若平)^a, Wang Long-Ge (王龙阁)^a, Huang Ming-Ju (黄明举)^a

a Key Discipline Open Laboratory of Photonic and Electronic Information Materials and Devices, Henan University, Kaifeng 475004, China;
b College of Peili Engineering Technology, Lanzhou City University, Lanzhou 730070, China

Received:2012-12-24 Revised:2013-04-04 Online:2013-10-25 Published:2013-10-25
Contact: Huang Ming-Ju E-mail:hmingju@163.com
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 61177004).

摘要/Abstract

摘要： A novel organic–inorganic nanoparticle–photopolymer composite system is developed, and its fundamental holographic recording characteristics are studied. In this hydrophilic TiO₂-nanoparticle-dispersed acrylamide photopolymer composite system, the counter-diffusion of monomers and nanoparticles plays a fundamental and key role in hologram grating formation. The experimental results indicate that the volume shrinkage of the nanoparticle–photopolymer film during the holographic recording can be drastically reduced compared with the undoped photopolymer film. It is also found that the diffraction efficiency of the grating recorded in the nanoparticle–photopolymer film depends strongly on the concentration of the TiO₂-nanoparticles, and there exists an optimal TiO₂-nanoparticle-doping concentration to make the diffraction efficiency and the refractive index modulation reach their maxima. Additionally, the digital data page is stored and reconstructed in the nanoparticle–photopolymer film.

关键词: holographic proprieties, TiO₂-nanoparticle, diffraction efficiency, Bragg-mismatch

Abstract: A novel organic–inorganic nanoparticle–photopolymer composite system is developed, and its fundamental holographic recording characteristics are studied. In this hydrophilic TiO₂-nanoparticle-dispersed acrylamide photopolymer composite system, the counter-diffusion of monomers and nanoparticles plays a fundamental and key role in hologram grating formation. The experimental results indicate that the volume shrinkage of the nanoparticle–photopolymer film during the holographic recording can be drastically reduced compared with the undoped photopolymer film. It is also found that the diffraction efficiency of the grating recorded in the nanoparticle–photopolymer film depends strongly on the concentration of the TiO₂-nanoparticles, and there exists an optimal TiO₂-nanoparticle-doping concentration to make the diffraction efficiency and the refractive index modulation reach their maxima. Additionally, the digital data page is stored and reconstructed in the nanoparticle–photopolymer film.

Key words: holographic proprieties, TiO₂-nanoparticle, diffraction efficiency, Bragg-mismatch

中图分类号: (Holographic recording materials; optical storage media)

42.70.Ln

42.40.Lx (Diffraction efficiency, resolution, and other hologram characteristics) 42.40.Pa (Volume holograms)

赵磊, 韩俊鹤, 李若平, 王龙阁, 黄明举. Resisting shrinkage properties of volume holograms recorded in TiO₂ nanoparticle-dispersed acrylamide-based photopolymer[J]. 中国物理B, 2013, 22(12): 124207-124207.

Zhao Lei (赵磊), Han Jun-He (韩俊鹤), Li Ruo-Ping (李若平), Wang Long-Ge (王龙阁), Huang Ming-Ju (黄明举). Resisting shrinkage properties of volume holograms recorded in TiO₂ nanoparticle-dispersed acrylamide-based photopolymer[J]. Chin. Phys. B, 2013, 22(12): 124207-124207.

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Resisting shrinkage properties of volume holograms recorded in TiO₂ nanoparticle-dispersed acrylamide-based photopolymer

Resisting shrinkage properties of volume holograms recorded in TiO₂ nanoparticle-dispersed acrylamide-based photopolymer

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