中国物理B ›› 2013, Vol. 22 ›› Issue (7): 77801-077801.doi: 10.1088/1674-1056/22/7/077801

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇    下一篇

Photoluminescence properties of Ce3+ and Mn2+-activated Ba9Sc2Si6O24 phosphor for white light emitting diodes

边柳, 王婷, 宋振, 刘朝晖, 李嘉旭, 刘泉林   

  1. School of Materials Science & Engineering and State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
  • 收稿日期:2013-01-26 修回日期:2013-03-04 出版日期:2013-06-01 发布日期:2013-06-01
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant No. 51272027) and the Ph. D. Program Foundation of Education Ministry of China (Grant No. 20100006110011).

Photoluminescence properties of Ce3+ and Mn2+-activated Ba9Sc2Si6O24 phosphor for white light emitting diodes

Bian Liu (边柳), Wang Ting (王婷), Song Zhen (宋振), Liu Zhao-Hui (刘朝晖), Li Jia-Xu (李嘉旭), Liu Quan-Lin (刘泉林)   

  1. School of Materials Science & Engineering and State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
  • Received:2013-01-26 Revised:2013-03-04 Online:2013-06-01 Published:2013-06-01
  • Contact: Liu Quan-Lin E-mail:qlliu@ustb.edu.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No. 51272027) and the Ph. D. Program Foundation of Education Ministry of China (Grant No. 20100006110011).

摘要: A single-phased silicate compound (Ba1-xCex)9(Sc1-yMny)2Si6O24 was prepared by solid-state reaction at high temperature. From powder X-ray diffraction (XRD) analysis, the formation of Ba9Sc2Si6O24 with R3 space group was confirmed. In the photoluminescence spectra under ultraviolet (UV) ray excitation, the Ba9Sc2Si6O24:Ce3+, Mn2+ phosphor emits two distinctive color light bands: a blue one originating from Ce3+ and a red one caused by Mn2+. The energy transfer process from Ce3+ to Mn2+ was confirmed, the critical radius as well as the transfer efficiency was calculated, and the energy transfer mechanism was discussed. In addition, the decay-time testing indicates that the energy transfer efficiencies from Ce(1) to Mn2+ and Ce(2) to Mn2+ are different. The emission chromaticity of Ba9Sc2Si6O24:Ce3+, Mn2+ phosphor could be tuned from blue to red by altering the Ce3+/Mn2+ concentration ratio.

关键词: Ba9Sc2Si6O24, Ce3+, Mn2+ co-doped, energy transfer

Abstract: A single-phased silicate compound (Ba1-xCex)9(Sc1-yMny)2Si6O24 was prepared by solid-state reaction at high temperature. From powder X-ray diffraction (XRD) analysis, the formation of Ba9Sc2Si6O24 with R3 space group was confirmed. In the photoluminescence spectra under ultraviolet (UV) ray excitation, the Ba9Sc2Si6O24:Ce3+, Mn2+ phosphor emits two distinctive color light bands: a blue one originating from Ce3+ and a red one caused by Mn2+. The energy transfer process from Ce3+ to Mn2+ was confirmed, the critical radius as well as the transfer efficiency was calculated, and the energy transfer mechanism was discussed. In addition, the decay-time testing indicates that the energy transfer efficiencies from Ce(1) to Mn2+ and Ce(2) to Mn2+ are different. The emission chromaticity of Ba9Sc2Si6O24:Ce3+, Mn2+ phosphor could be tuned from blue to red by altering the Ce3+/Mn2+ concentration ratio.

Key words: Ba9Sc2Si6O24, Ce3+, Mn2+ co-doped, energy transfer

中图分类号:  (Photoluminescence, properties and materials)

  • 78.55.-m
87.15.mq (Luminescence) 33.50.-j (Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion))