中国物理B ›› 2011, Vol. 20 ›› Issue (6): 67803-067803.doi: 10.1088/1674-1056/20/6/067803

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇    下一篇

Studies on selected polymeric materials using the photoacoustic spectroscopic technique

Hukum Singh   

  1. School of Engineering and Technology, ITM University, Gurgaon-122 017, India
  • 收稿日期:2010-10-25 修回日期:2011-01-14 出版日期:2011-06-15 发布日期:2011-06-15

Studies on selected polymeric materials using the photoacoustic spectroscopic technique

Hukum Singh   

  1. School of Engineering and Technology, ITM University, Gurgaon-122 017, India
  • Received:2010-10-25 Revised:2011-01-14 Online:2011-06-15 Published:2011-06-15

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摘要： Polymethylmethacrylate-graft-polybisphenol-A-carbonate (PMMA-G-PC) with 50% grafting is synthesized. The graft co-polymerization of methylmethacrylate (0.036 mol·lit-1) onto polybisphenol-A-carbonate (0.5 g) in the presence of a redox couple formed from potassium persulphate (40 mol·lit-1) and thio-urea (30 mmol·lit-1) in aqueous nitric acid (0.18 M, 100 ml) in air at (45±2)°C for 3.0 h. Condensation of (PMMA-G-PC) with N- [p-(carboxyl phenyl amino acetic acid)] hydrazide (PCPH) affords polybisphenol-A-carbonate-graft-polymethylmethacrylate hydrazide (PCGH). The photoacoustic (PA) spectra of (PCGH) are recorded in a wavelength range from 200 nm to 800 nm at a modulation frequency of 22 Hz, and compared with those of pure polybisphenol-A-carbonate (PC), (PMMA-G-PC) and (PCPH). In the present work, a non-destructive and non-contact analytical method, namely the photoacoustic technique, is successfully implemented for optical and thermal characterization of selected polymeric materials. The indigenous PA spectrometer used in the present study consists of a 300-W xenon arc lamp, a lock-in amplifier, a chopper, a (1/8)-m monochromator controlled by computer and a home-made PA cell.

Abstract: Polymethylmethacrylate-graft-polybisphenol-A-carbonate (PMMA-G-PC) with 50% grafting is synthesized. The graft co-polymerization of methylmethacrylate (0.036 mol·lit-1) onto polybisphenol-A-carbonate (0.5 g) in the presence of a redox couple formed from potassium persulphate (40 mol·lit-1) and thio-urea (30 mmol·lit-1) in aqueous nitric acid (0.18 M, 100 ml) in air at (45±2)°C for 3.0 h. Condensation of (PMMA-G-PC) with N- [p-(carboxyl phenyl amino acetic acid)] hydrazide (PCPH) affords polybisphenol-A-carbonate-graft-polymethylmethacrylate hydrazide (PCGH). The photoacoustic (PA) spectra of (PCGH) are recorded in a wavelength range from 200 nm to 800 nm at a modulation frequency of 22 Hz, and compared with those of pure polybisphenol-A-carbonate (PC), (PMMA-G-PC) and (PCPH). In the present work, a non-destructive and non-contact analytical method, namely the photoacoustic technique, is successfully implemented for optical and thermal characterization of selected polymeric materials. The indigenous PA spectrometer used in the present study consists of a 300-W xenon arc lamp, a lock-in amplifier, a chopper, a (1/8)-m monochromator controlled by computer and a home-made PA cell.

Key words: photoacoustic, PCPH, PCGH, PMMA

中图分类号:  (Photoacoustic effects)

  • 78.20.Pa
78.20.nb (Photothermal effects)