中国物理B ›› 2025, Vol. 34 ›› Issue (4): 47701-047701.doi: 10.1088/1674-1056/adb25e

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High-performance KNN-based piezoelectric ceramics for buzzer application

Cheng Xiong(熊城)1, Bosen Li(李博森)1, Zhongxin Liao(廖忠新)2, Yan Qiu(邱䶮)2, and Daqiang Gao(高大强)1,†   

  1. 1 School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China;
    2 The Audiowell Electronics (Guangdong) Co., Ltd., Guangzhou 511493, China
  • 收稿日期:2024-10-16 修回日期:2025-01-11 接受日期:2025-02-05 出版日期:2025-04-15 发布日期:2025-04-15
  • 通讯作者: Daqiang Gao E-mail:gaodq@lzu.edu.cn
  • 基金资助:
    Project supported by the Key Research and Develop Projects in Gansu Province (Grant No. 23YFGA0002) and the project funding of Audiowell Electronics (Guangdong) Co., Ltd.

High-performance KNN-based piezoelectric ceramics for buzzer application

Cheng Xiong(熊城)1, Bosen Li(李博森)1, Zhongxin Liao(廖忠新)2, Yan Qiu(邱䶮)2, and Daqiang Gao(高大强)1,†   

  1. 1 School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China;
    2 The Audiowell Electronics (Guangdong) Co., Ltd., Guangzhou 511493, China
  • Received:2024-10-16 Revised:2025-01-11 Accepted:2025-02-05 Online:2025-04-15 Published:2025-04-15
  • Contact: Daqiang Gao E-mail:gaodq@lzu.edu.cn
  • Supported by:
    Project supported by the Key Research and Develop Projects in Gansu Province (Grant No. 23YFGA0002) and the project funding of Audiowell Electronics (Guangdong) Co., Ltd.

摘要: Piezoelectric ceramic materials are important components of piezoelectric buzzers, where the parameter of inverse piezoelectric coefficient ($d_{33}^{\ast }$) plays a decisive role in the performance of the buzzer. Here, we report the manufacture and performance of a lead-free ceramic-based (0.96(K$_{0.5}$Na$_{0.5}$)(Nb$_{0.96}$Sb$_{0.04}$)O$_{3}$-0.04(Bi$_{0.5}$Na$_{0.5}$)ZrO$_{3}$-1 mol% Al$_{2}$O$_{3}$, abbreviated as KNNS-BNZ-1 mol% Al$_{2}$O$_{3}$) piezoelectric buzzer and compare it with commercial (PbZr$_{0.5}$Ti$_{0.5}$O$_{3}$, abbreviated as PZT) ceramics. Briefly, KNN-based ceramics have a typical perovskite structure and piezoelectric properties of $d_{33}=480 $ pC/N, $k_{\rm p}=0.62$ and $d_{33}^{\ast }=830 $ pm/V, compared to $d_{33}=500 $ pC/N, $k_{\rm p}=0.6$ and $d_{33}^{\ast}=918 $ pm/V of the commercial PZT-4 ceramics. Our results show that the KNNS-BNZ-1 mol% Al$_{2}$O$_{3}$ ceramics have a similar sound pressure level performance over the testing frequency range to commercial PZT ceramics (which is even better in the 3-4 kHz range). These findings highlight the great application potential of KNN-based piezoelectric ceramics.

关键词: lead-free piezoelectric ceramics, phase structure engineering, buzzer, atomizer

Abstract: Piezoelectric ceramic materials are important components of piezoelectric buzzers, where the parameter of inverse piezoelectric coefficient ($d_{33}^{\ast }$) plays a decisive role in the performance of the buzzer. Here, we report the manufacture and performance of a lead-free ceramic-based (0.96(K$_{0.5}$Na$_{0.5}$)(Nb$_{0.96}$Sb$_{0.04}$)O$_{3}$-0.04(Bi$_{0.5}$Na$_{0.5}$)ZrO$_{3}$-1 mol% Al$_{2}$O$_{3}$, abbreviated as KNNS-BNZ-1 mol% Al$_{2}$O$_{3}$) piezoelectric buzzer and compare it with commercial (PbZr$_{0.5}$Ti$_{0.5}$O$_{3}$, abbreviated as PZT) ceramics. Briefly, KNN-based ceramics have a typical perovskite structure and piezoelectric properties of $d_{33}=480 $ pC/N, $k_{\rm p}=0.62$ and $d_{33}^{\ast }=830 $ pm/V, compared to $d_{33}=500 $ pC/N, $k_{\rm p}=0.6$ and $d_{33}^{\ast}=918 $ pm/V of the commercial PZT-4 ceramics. Our results show that the KNNS-BNZ-1 mol% Al$_{2}$O$_{3}$ ceramics have a similar sound pressure level performance over the testing frequency range to commercial PZT ceramics (which is even better in the 3-4 kHz range). These findings highlight the great application potential of KNN-based piezoelectric ceramics.

Key words: lead-free piezoelectric ceramics, phase structure engineering, buzzer, atomizer

中图分类号:  (Dielectric, piezoelectric, ferroelectric, and antiferroelectric materials)

  • 77.84.-s
77.80.B- (Phase transitions and Curie point) 85.50.-n (Dielectric, ferroelectric, and piezoelectric devices) 77.80.bg (Compositional effects)