High pressure and high temperature induced polymerization of C60 quantum dots

doi:10.1088/1674-1056/ab6657

中国物理B ›› 2020, Vol. 29 ›› Issue (2): 26402-026402.doi: 10.1088/1674-1056/ab6657

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

High pressure and high temperature induced polymerization of C₆₀ quantum dots

Shi-Hao Ruan(阮世豪), Chun-Miao Han(韩春淼), Fu-Lu Li(李福禄), Bing Li(李冰), Bing-Bing Liu(刘冰冰)

1 State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China;
2 College of Physics, Changchun Normal University, Changchun 130032, China

收稿日期:2019-12-05 修回日期:2019-12-26 出版日期:2020-02-05 发布日期:2020-02-05
通讯作者: Bing Li E-mail:Lib_ccsfu@163.com
基金资助:
Project supported by the National Key R&D Program of China (Grant No. 2018YFA0305900), the National Natural Science Foundation of China (Grant Nos. 11634004 and 11404036), “the 13th Five-year” Planning Project of Jilin Provincial Education Department Foundation, China (Grant No. 20190504), JLU Science and Technology Innovative Research Team, China (Grant No. 2017TD-01), and Natural Science Foundation of Chang-chun Normal University, China (Grant No. 2014-001).

High pressure and high temperature induced polymerization of C₆₀ quantum dots

Shi-Hao Ruan(阮世豪)¹, Chun-Miao Han(韩春淼)², Fu-Lu Li(李福禄)², Bing Li(李冰)^1,2, Bing-Bing Liu(刘冰冰)¹

1 State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China;
2 College of Physics, Changchun Normal University, Changchun 130032, China

Received:2019-12-05 Revised:2019-12-26 Online:2020-02-05 Published:2020-02-05
Contact: Bing Li E-mail:Lib_ccsfu@163.com
Supported by:
Project supported by the National Key R&D Program of China (Grant No. 2018YFA0305900), the National Natural Science Foundation of China (Grant Nos. 11634004 and 11404036), “the 13th Five-year” Planning Project of Jilin Provincial Education Department Foundation, China (Grant No. 20190504), JLU Science and Technology Innovative Research Team, China (Grant No. 2017TD-01), and Natural Science Foundation of Chang-chun Normal University, China (Grant No. 2014-001).

摘要/Abstract

摘要： We synthesized C₆₀ quantum dots (QDs) with a uniform size by a modified ultrasonic process and studied its polymerization under high pressure and high temperature (HPHT). Raman spectra showed that a phase assemblage of a dimer (D) phase (62 vol%) and a one-dimensional chain orthorhombic (O) phase (38 vol%) was obtained at 1.5 GPa and 300 °C. At 2.0 GPa and 430 °C, the proportion of the O phase increased to 46 vol%, while the corresponding D phase decreased to 54 vol%. Compared with bulk and nanosized C₆₀, C₆₀ QDs cannot easily form a high-dimensional polymeric structure. This fact is probably caused by the small particle size, orientation of the disordered structure of C₆₀ QDs, and the barrier of oxide function groups between C₆₀ molecules. Our studies enhance the understanding of the polymerization behavior of low-dimension C₆₀ nanomaterials under HPHT conditions.

关键词: C₆₀ quantum dots, high pressure and high temperature, fullerene polymer

Abstract: We synthesized C₆₀ quantum dots (QDs) with a uniform size by a modified ultrasonic process and studied its polymerization under high pressure and high temperature (HPHT). Raman spectra showed that a phase assemblage of a dimer (D) phase (62 vol%) and a one-dimensional chain orthorhombic (O) phase (38 vol%) was obtained at 1.5 GPa and 300 °C. At 2.0 GPa and 430 °C, the proportion of the O phase increased to 46 vol%, while the corresponding D phase decreased to 54 vol%. Compared with bulk and nanosized C₆₀, C₆₀ QDs cannot easily form a high-dimensional polymeric structure. This fact is probably caused by the small particle size, orientation of the disordered structure of C₆₀ QDs, and the barrier of oxide function groups between C₆₀ molecules. Our studies enhance the understanding of the polymerization behavior of low-dimension C₆₀ nanomaterials under HPHT conditions.

Key words: C₆₀ quantum dots, high pressure and high temperature, fullerene polymer

中图分类号: (Structural transitions in nanoscale materials)

64.70.Nd

91.60.Gf (High-pressure behavior) 61.48.-c (Structure of fullerenes and related hollow and planar molecular structures) 64.70.km (Polymers)

阮世豪, 韩春淼, 李福禄, 李冰, 刘冰冰. High pressure and high temperature induced polymerization of C₆₀ quantum dots[J]. 中国物理B, 2020, 29(2): 26402-026402.

Shi-Hao Ruan(阮世豪), Chun-Miao Han(韩春淼), Fu-Lu Li(李福禄), Bing Li(李冰), Bing-Bing Liu(刘冰冰). High pressure and high temperature induced polymerization of C₆₀ quantum dots[J]. Chin. Phys. B, 2020, 29(2): 26402-026402.

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High pressure and high temperature induced polymerization of C₆₀ quantum dots

High pressure and high temperature induced polymerization of C₆₀ quantum dots

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