Highly stable two-dimensional graphene oxide: Electronic properties of its periodic structure and optical properties of its nanostructures

doi:10.1088/1674-1056/27/2/027301

中国物理B ›› 2018, Vol. 27 ›› Issue (2): 27301-027301.doi: 10.1088/1674-1056/27/2/027301

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Highly stable two-dimensional graphene oxide: Electronic properties of its periodic structure and optical properties of its nanostructures

Qin Zhang(张琴), Hong Zhang(张红), Xin-Lu Cheng(程新路)

1. College of Physical Science and Technology, Sichuan University, Chengdu 610065, China;
2. Key Laboratory of High Energy Density Physics and Technology of Ministry of Education, Sichuan University, Chengdu 610065, China

收稿日期:2017-09-18 修回日期:2017-11-06 出版日期:2018-02-05 发布日期:2018-02-05
通讯作者: Hong Zhang E-mail:hongzhang@scu.edu.cn
基金资助:
Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0303600) and the National Natural Science Foundation of China (Grant Nos. 11474207 and 11374217).

Highly stable two-dimensional graphene oxide: Electronic properties of its periodic structure and optical properties of its nanostructures

Qin Zhang(张琴)¹, Hong Zhang(张红)^1,2, Xin-Lu Cheng(程新路)²

1. College of Physical Science and Technology, Sichuan University, Chengdu 610065, China;
2. Key Laboratory of High Energy Density Physics and Technology of Ministry of Education, Sichuan University, Chengdu 610065, China

Received:2017-09-18 Revised:2017-11-06 Online:2018-02-05 Published:2018-02-05
Contact: Hong Zhang E-mail:hongzhang@scu.edu.cn
About author:73.20.At; 71.15.Mb; 73.20.Mf
Supported by:
Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0303600) and the National Natural Science Foundation of China (Grant Nos. 11474207 and 11374217).

摘要/Abstract

摘要： According to first principle simulations, we theoretically predict a type of stable single-layer graphene oxide (C₂O). Using density functional theory (DFT), C₂O is found to be a direct gap semiconductor. In addition, we obtain the absorption spectra of the periodic structure of C₂O, which show optical anisotropy. To study the optical properties of C₂O nanostructures, time-dependent density functional theory (TDDFT) is used. The C₂O nanostructure has a strong absorption near 7 eV when the incident light polarizes along the armchair-edge. Besides, we find that the optical properties can be controlled by the edge configuration and the size of the C₂O nanostructure. With the elongation strain increasing, the range of light absorption becomes wider and there is a red shift of absorption spectrum.

关键词: two-dimensional (2D) materials, graphene oxide, surface plasmons

Abstract: According to first principle simulations, we theoretically predict a type of stable single-layer graphene oxide (C₂O). Using density functional theory (DFT), C₂O is found to be a direct gap semiconductor. In addition, we obtain the absorption spectra of the periodic structure of C₂O, which show optical anisotropy. To study the optical properties of C₂O nanostructures, time-dependent density functional theory (TDDFT) is used. The C₂O nanostructure has a strong absorption near 7 eV when the incident light polarizes along the armchair-edge. Besides, we find that the optical properties can be controlled by the edge configuration and the size of the C₂O nanostructure. With the elongation strain increasing, the range of light absorption becomes wider and there is a red shift of absorption spectrum.

Key words: two-dimensional (2D) materials, graphene oxide, surface plasmons

中图分类号: (Surface states, band structure, electron density of states)

73.20.At

71.15.Mb (Density functional theory, local density approximation, gradient and other corrections) 73.20.Mf (Collective excitations (including excitons, polarons, plasmons and other charge-density excitations))

张琴, 张红, 程新路. Highly stable two-dimensional graphene oxide: Electronic properties of its periodic structure and optical properties of its nanostructures[J]. 中国物理B, 2018, 27(2): 27301-027301.

Qin Zhang(张琴), Hong Zhang(张红), Xin-Lu Cheng(程新路). Highly stable two-dimensional graphene oxide: Electronic properties of its periodic structure and optical properties of its nanostructures[J]. Chin. Phys. B, 2018, 27(2): 27301-027301.

参考文献 34

[1]	Nie S and Emery S R 1997 Science 275 5303
[2]	Xu H, Bjerneld E J and Käll M 1999 Phys. Rev. Lett. 83 4357
[3]	Maier S A, Kik P G, and Atwater H A 2002 Appl. Phys. Lett. 81 1714
[4]	Yan J and Gao S W 2008 Phys. Rev. B 78 235413
[5]	Hirsch L R, Stafford R J and Bankson J A 2003 Proc. Nat. Acad. Sci. 100 13549
[6]	Bachelier G, Russier-Antoine I and Benichou E 2008 Phys. Rev. Lett. 101 197401
[7]	Brown L V, Sobhani H and Lassiter J B 2010 ACS Nano 4 819
[8]	Yin H F and Zhang H 2012 Physica B:Condens. Matter 407 416
[9]	Rao C N R, Sood A K and Subrahmanyam K S 2009 Angewandte Chemie International Edition 48 7752
[10]	Allen M J, Tung V C and Kaner R B 2010 Chem. Rev. 110 132
[11]	Yin Y H, Niu Y X and Ding M 2016 Chin. Phys. Lett. 33 057202
[12]	Sun M, Ren Q and Zhao Y 2017 Carbon 120 265
[13]	Sun M L, Chou J P and Ren Q 2017 Appl. Phys. Lett. 110 392
[14]	Kim J, Cote L J and Kim F 2010 J. Am. Chem. Soc. 132 8180
[15]	Suarez A M, Radovic L R and Bar-Ziv E 2011 Phys. Rev. Lett. 106 146802
[16]	Gao W, Alemany L B and Ci L 2009 Nat. Chem. 1 403
[17]	Loh K P, Bao Q and Eda G 2010 Nat. Chem. 2 1015
[18]	Huang B, Xiang H and Xu Q 2013 Phys. Rev. Lett. 110 085501
[19]	Li L Y, Yan B P and Zhang C M 2012 Acta Phys. Sin. 61 167506(in Chinese)
[20]	Perdew J P, Burke K and Ernzerhof M 1996 Phys. Rev. Lett. 77 3865
[21]	Segall M D, Lindan P J D and Probert M J 2002 J. Phys.:Condens. Matter 14 2717
[22]	Baroni S, de Gironcoli S 2001 Rev. Mod. Phys 73 515
[23]	Marques M A L, Castro A and Bertsch G F 2003 Comput. Phys. Commun. 151 60
[24]	Troullier N and Martins J L 1991 Phys. Rev. B 43 1993
[25]	Gerlich D 1993 J. Chem. Soc. Faraday Trans. 89 2199
[26]	Liu D, Every A G and Tománek D 2016 Phys. Rev. B 94 165432
[27]	Nagare B J 2015 RSC Adv. 5 77478
[28]	Yin H and Zhang H 2012 J. Appl. Phys. 111 103502
[29]	Zhang K and Zhang H 2014 J. Phys. Chem. C 118 635
[30]	Shao L, Ruan Q F and Li Y 2017 Chin. Phys. B 26 036802
[31]	Yuan S J, Zhang H and Cheng X L 2017 Plasmonics 1
[32]	Lalmi B, Oughaddou H and Enriquez H 2010 Appl. Phys. Lett. 97 223109
[33]	Vogt P, De Padova P and Quaresima C 2012 Phys. Rev. Lett. 108 155501
[34]	Li J, Xu S and Zhang J Y 2017 Chin. Phys. B 26 036802

Highly stable two-dimensional graphene oxide: Electronic properties of its periodic structure and optical properties of its nanostructures

Highly stable two-dimensional graphene oxide: Electronic properties of its periodic structure and optical properties of its nanostructures

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