Forming solid electrolyte interphase in situ in an ionic conductingLi1.5Al0.5Ge1.5(PO4)3-polypropylene (PP) basedseparator for Li-ion batteries

doi:10.1088/1674-1056/25/7/078204

中国物理B ›› 2016, Vol. 25 ›› Issue (7): 78204-078204.doi: 10.1088/1674-1056/25/7/078204

• RAPID COMMUNICATION • 上一篇下一篇

Forming solid electrolyte interphase in situ in an ionic conductingLi_1.5Al_0.5Ge_1.5(PO₄)₃-polypropylene (PP) basedseparator for Li-ion batteries

Jiao-Yang Wu(吴娇杨), Shi-Gang Ling(凌仕刚), Qi Yang(杨琪), Hong Li(李泓), Xiao-Xiong Xu(许晓雄), Li-Quan Chen(陈立泉)

1 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2 Ningbo Institute of Material Technology Engineering, Chinese Academy of Sciences, Zhejiang 315201, China

收稿日期:2016-04-13 修回日期:2016-04-20 出版日期:2016-07-05 发布日期:2016-07-05
通讯作者: Hong Li E-mail:hli@iphy.ac.cn
基金资助:
Project supported by the Beijing Science and Technology Project, China (Grant No. Z13111000340000), the National Basic Research Program of China (Grant No. 2012CB932900), and the National Natural Science Foundation of China (Grant Nos. 51325206 and 51421002).

Forming solid electrolyte interphase in situ in an ionic conductingLi_1.5Al_0.5Ge_1.5(PO₄)₃-polypropylene (PP) basedseparator for Li-ion batteries

Jiao-Yang Wu(吴娇杨)¹, Shi-Gang Ling(凌仕刚)¹, Qi Yang(杨琪)¹, Hong Li(李泓)¹, Xiao-Xiong Xu(许晓雄)², Li-Quan Chen(陈立泉)¹

1 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2 Ningbo Institute of Material Technology Engineering, Chinese Academy of Sciences, Zhejiang 315201, China

Received:2016-04-13 Revised:2016-04-20 Online:2016-07-05 Published:2016-07-05
Contact: Hong Li E-mail:hli@iphy.ac.cn
Supported by:
Project supported by the Beijing Science and Technology Project, China (Grant No. Z13111000340000), the National Basic Research Program of China (Grant No. 2012CB932900), and the National Natural Science Foundation of China (Grant Nos. 51325206 and 51421002).

摘要/Abstract

摘要：

A new concept of forming solid electrolyte interphases (SEI) in situ in an ionic conducting Li_1.5Al_0.5Ge_1.5(PO₄)₃-polypropylene (LAGP-PP) based separator during charging and discharging is proposed and demonstrated. This unique structure shows a high ionic conductivity, low interface resistance with electrode, and can suppress the growth of lithium dendrite. The features of forming the SEI in situ are investigated by scanning electron microscopy (SEM) and x-ray photoelectron spectroscopy (XPS). The results confirm that SEI films mainly consist of lithium fluoride and carbonates with various alkyl contents. The cell assembled by using the LAGP-coated separator demonstrates a good cycling performance even at high charging rates, and the lithium dendrites were not observed on the lithium metal electrode. Therefore, the SEI-LAGP-PP separator can be used as a promising flexible solid electrolyte for solid state lithium batteries.

关键词: solid state lithium batteries, solid electrolyte interphase, ionic conductor coated separator, lithium dendrite

Abstract:

Key words: solid state lithium batteries, solid electrolyte interphase, ionic conductor coated separator, lithium dendrite

中图分类号: (Lithium-ion batteries)

82.47.Aa

65.40.gk (Electrochemical properties) 82.45.Fk (Electrodes)

吴娇杨, 凌仕刚, 杨琪, 李泓, 许晓雄, 陈立泉. Forming solid electrolyte interphase in situ in an ionic conductingLi_1.5Al_0.5Ge_1.5(PO₄)₃-polypropylene (PP) basedseparator for Li-ion batteries[J]. 中国物理B, 2016, 25(7): 78204-078204.

Jiao-Yang Wu(吴娇杨), Shi-Gang Ling(凌仕刚), Qi Yang(杨琪), Hong Li(李泓), Xiao-Xiong Xu(许晓雄), Li-Quan Chen(陈立泉). Forming solid electrolyte interphase in situ in an ionic conductingLi_1.5Al_0.5Ge_1.5(PO₄)₃-polypropylene (PP) basedseparator for Li-ion batteries[J]. Chin. Phys. B, 2016, 25(7): 78204-078204.

参考文献 31

[1]	Whittingham M S 2008 Mrs Bulletin 33 411
[2]	Arico A S, Bruce P, Scrosati B, Tarascon J M and Van Schalkwijk W 2005 Nat. Mater. 4 366
[3]	Tarascon J M and Armand M 2001 Nature 414 359
[4]	Abraham K M and Jiang Z 1996 J. Electrochem. Soc. 143 1
[5]	Quartarone E, Mustarelli P and Magistris A 1998 Solid State Ion. 110 1
[6]	Masoud E M, El-Bellihi A A, Bayoumy W A and Mousa M A 2013 J. Alloy. Compound. 575 223
[7]	Kim J W, Ji K S, Lee J P and Park J W 2003 J. Power Sources 119 415
[8]	Stephan A M and Nahm K S 2006 Polymer 47 5952
[9]	Choi J H, Lee C H, Yu J H, Doh C H and Lee S M 2015 J. Power Sources 274 458
[10]	Croce F, Appetecchi G B, Persi L and Scrosati B 1998 Nature 394 456
[11]	Kamaya N, Homma K, Yamakawa Y, Hirayama M, Kanno R, Yonemura M, Kamiyama T, Kato Y, Hama S, Kawamoto K and Mitsui A 2011 Nat. Mater. 10 682
[12]	Zhao Y, Wu C, Peng G, Chen X, Yao X, Bai Y, Wu F, Chen S and Xu X 2016 J. Power Sources 301 47
[13]	Luo F, Chu G, Xia X, Liu B, Zheng J, Li J, Li H, Gu C and Chen L 2015 Nanoscale 7 7651
[14]	Shi J, Xia Y, Han S, Fang L, Pan M, Xu X and Liu Z 2015 J. Power Sources 273 389
[15]	Wu Y P, Rahm E and Holze R 2003 J. Power Sources 114 228
[16]	Takamura T, Sumiya K, Suzuki J, Yamada C and Sekine K 1999 J. Power Sources 81 368
[17]	Hartmann P, Leichtweiss T, Busche M R, Schneider M, Reich M, Sann J, Adelhelm P and Janek J 2013 J. Phys. Chem. C 117 21064
[18]	Mariappan C R, Yada C, Rosciano F and Roling B 2011 J. Power Sources 196 6456
[19]	Moller K C, Hodal T, Appel W K, Winter M and Besenhard J O 2001 J. Power Sources 97 595
[20]	Lu M, Cheng H and Yang Y 2008 Electrochim. Acta 53 3539
[21]	Lee S H, You H G, Han K S, Kim J, Jung I H and Song J H 2014 J. Power Sources 247 307
[22]	Cannas C, Casu M, Lai A, Musinu A and Piccaluga G 1999 J. Mater. Chem. 9 1765
[23]	Inada R, Ishida K I, Tojo M, Okada T, Tojo T and Sakurai Y 2015 Ceram. Int. 41 11136
[24]	Bettge M, Li Y, Sankaran B, Rago N D, Spila T, Haasch R T, Petrov I and Abraham D P 2013 J. Power Sources 233 346
[25]	Sugimoto T, Kikuta M, Ishiko E, Kono M and Ishikawa M 2008 J. Power Sources 183 436
[26]	Howlett P C, Brack N, Hollenkamp A F, Forsyth M and MacFarlane D R 2006 J. Electrochem. Soc. 153 A595
[27]	Budi A, Basile A, Opletal G, Hollenkamp A F, Best A S, Rees R J, Bhatt A I, O'Mullane A P and Russo S P 2012 J. Phys. Chem. C 116 19789
[28]	Wang X, Xiang J, Wang W, Xiong Y, Zhang J and Zhao C 2015 Appl. Surf. Sci. 357 1857
[29]	Kato K, Kyogoku S, Sakashita M, Takeuchi W, Kondo H, Takeuchi S, Nakatsuka O and Zaima S 2011 Jpn J. Appl. Phys. 50 10PE02
[30]	Aurbach D, Zinigrad E, Teller H, Cohen Y, Salitra G, Yamin H, Dan P and Elster E 2002 J. Electrochem. Soc. 149 A1267
[31]	Miao R, Yang J, Feng X, Jia H, Wang J and Nuli Y 2014 J. Power Sources 271 291

Forming solid electrolyte interphase in situ in an ionic conductingLi_1.5Al_0.5Ge_1.5(PO₄)₃-polypropylene (PP) basedseparator for Li-ion batteries

Forming solid electrolyte interphase in situ in an ionic conductingLi_1.5Al_0.5Ge_1.5(PO₄)₃-polypropylene (PP) basedseparator for Li-ion batteries

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 31

相关文章 4

Metrics

本文评价

推荐阅读 0

[1]	Fangrong Hu(胡放荣), Mingyang Zhang(张铭扬), Wenbin Qi(起文斌), Jieyun Zheng(郑杰允), Yue Sun(孙悦), Jianyu Kang(康剑宇), Hailong Yu(俞海龙), Qiyu Wang(王其钰), Shijuan Chen(陈世娟), Xinhua Sun(孙新华), Baogang Quan(全保刚), Junjie Li(李俊杰), Changzhi Gu(顾长志), and Hong Li(李泓). Silicon micropillar electrodes of lithiumion batteries used for characterizing electrolyte additives[J]. 中国物理B, 2021, 30(6): 68202-068202.
[2]	郑杰允, 刘家亮, 王绥军, 罗飞, 贲留斌, 李泓. Influence of fluoroethylene carbonate on the solid electrolyte interphase of silicon anode for Li-ion batteries: A scanning force spectroscopy study[J]. 中国物理B, 2020, 29(4): 48203-048203.
[3]	李钰琦, 陆雅翔, 陈立泉, 胡勇胜. Failure analysis with a focus on thermal aspect towards developing safer Na-ion batteries[J]. 中国物理B, 2020, 29(4): 48201-048201.
[4]	徐航宇, 李泉, 潘弘毅, 邱纪亮, 曹文卓, 禹习谦, 李泓. Artificial solid electrolyte interphase based on polyacrylonitrile for homogenous and dendrite-free deposition of lithium metal[J]. 中国物理B, 2019, 28(7): 78202-078202.