中国物理B ›› 2016, Vol. 25 ›› Issue (4): 47802-047802.doi: 10.1088/1674-1056/25/4/047802

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇    下一篇

Effect of co-doped metal caions on the properties of Y2O3:Eu3+ phosphors synthesized by gel-combustion method

Hui Shi(石慧), Xi-Yan Zhang(张希艳), Wei-Li Dong(董玮利), Xiao-Yun Mi(米晓云), Neng-Li Wang(王能利), Yan Li(李艳), Hong-Wei Liu(刘宏伟)   

  1. School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China
  • 收稿日期:2015-10-10 修回日期:2015-12-20 出版日期:2016-04-05 发布日期:2016-04-05
  • 通讯作者: Hui Shi, Xi-Yan Zhang E-mail:sh_1985@126.com;xiyzhang@126.com

Effect of co-doped metal caions on the properties of Y2O3:Eu3+ phosphors synthesized by gel-combustion method

Hui Shi(石慧), Xi-Yan Zhang(张希艳), Wei-Li Dong(董玮利), Xiao-Yun Mi(米晓云), Neng-Li Wang(王能利), Yan Li(李艳), Hong-Wei Liu(刘宏伟)   

  1. School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China
  • Received:2015-10-10 Revised:2015-12-20 Online:2016-04-05 Published:2016-04-05
  • Contact: Hui Shi, Xi-Yan Zhang E-mail:sh_1985@126.com;xiyzhang@126.com

摘要: Y2O3:Eu3+ phosphors co-doped with different metal cations (Li+, Na+, K+, Mg2+, Ca2+) are prepared by the gel-combustion method with Y2O3, Eu2O3, and R(NO3)x (R=Li, Na, K, Mg, Ca) serving as raw materials and glycine as fuel, calcined at 1000 ℃ for 2 h. The synthesized Y2O3:Eu3+ phosphors doped with different metal cations and doping ratios are characterized by x-ray diffractometry (XRD), fluorescence and phosphorescent spectrophotometer. The co-doping metal cations are advantageous to the development of Y2O3:Eu3+ lattice. All the samples can emit red light peaked at 611 nm under 254-nm excited. The luminescence intensities of co-doping samples are increased because the cations increase the electron transition probability of Eu3+ from 5D0 level to 7F level. The fluorescence lifetime of Eu3+ (5D07F2) is increased by doping metal cations.

关键词: combustion method, metal cations, Y2O3:Eu3+

Abstract: Y2O3:Eu3+ phosphors co-doped with different metal cations (Li+, Na+, K+, Mg2+, Ca2+) are prepared by the gel-combustion method with Y2O3, Eu2O3, and R(NO3)x (R=Li, Na, K, Mg, Ca) serving as raw materials and glycine as fuel, calcined at 1000 ℃ for 2 h. The synthesized Y2O3:Eu3+ phosphors doped with different metal cations and doping ratios are characterized by x-ray diffractometry (XRD), fluorescence and phosphorescent spectrophotometer. The co-doping metal cations are advantageous to the development of Y2O3:Eu3+ lattice. All the samples can emit red light peaked at 611 nm under 254-nm excited. The luminescence intensities of co-doping samples are increased because the cations increase the electron transition probability of Eu3+ from 5D0 level to 7F level. The fluorescence lifetime of Eu3+ (5D07F2) is increased by doping metal cations.

Key words: combustion method, metal cations, Y2O3:Eu3+

中图分类号:  (Photoluminescence, properties and materials)

  • 78.55.-m
81.07.-b (Nanoscale materials and structures: fabrication and characterization) 32.50.+d (Fluorescence, phosphorescence (including quenching))