Pre-existing orthorhombic embryos-induced hexagonal—orthorhombic martensitic transformation in MnNiSi1-x(CoNiGe)x alloy

doi:10.1088/1674-1056/ad188d

中国物理B ›› 2024, Vol. 33 ›› Issue (4): 48103-048103.doi: 10.1088/1674-1056/ad188d

Pre-existing orthorhombic embryos-induced hexagonal—orthorhombic martensitic transformation in MnNiSi_1-x(CoNiGe)_x alloy

Ting-Ting Zhang(张婷婷), Yuan-Yuan Gong(龚元元), Zi-Qian Lu(鲁子骞), and Feng Xu(徐锋)^†

MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials Technology, School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

收稿日期:2023-09-18 修回日期:2023-12-17 接受日期:2023-12-25 出版日期:2024-03-19 发布日期:2024-03-27
通讯作者: Feng Xu E-mail:xufeng@njust.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 11974184).

Pre-existing orthorhombic embryos-induced hexagonal—orthorhombic martensitic transformation in MnNiSi_1-x(CoNiGe)_x alloy

Ting-Ting Zhang(张婷婷), Yuan-Yuan Gong(龚元元), Zi-Qian Lu(鲁子骞), and Feng Xu(徐锋)^†

MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials Technology, School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received:2023-09-18 Revised:2023-12-17 Accepted:2023-12-25 Online:2024-03-19 Published:2024-03-27
Contact: Feng Xu E-mail:xufeng@njust.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 11974184).

1. 2024-048103-SI.pdf(905KB)

摘要/Abstract

摘要： The thermal—elastic martensitic transformation from high-temperature Ni$_{2}$In-type hexagonal structure to low-temperature TiNiSi-type orthorhombic structure has been widely studied in Mn$MX$ ($M={\rm Ni}$ or Co, and $X={\rm Ge}$ or Si) alloys. However, the answer to how the orthorhombic martensite nucleates and grows within the hexagonal parent is still unclear. In this work, the hexagonal—orthorhombic martensitic transformation in a Co and Ge co-substituted MnNiSi is investigated. One can find some orthorhombic laths embedded in the hexagonal parent at a temperature above the martensitic transformation start temperature ($M_{\rm s}$). With the the sample cooing to $M_{\rm s}$, the laths turn broader, indicating that the martensitic transformation starts from these pre-existing orthorhombic laths. Microstructure observation suggests that these pre-existing orthorhombic laths do not originate from the hexagonal—orthorhombic martensitic transformation because of the difference between atomic occupations of doping elements in the hexagonal parent and those in the pre-existing orthorhombic laths. The phenomenological crystallographic theory and experimental investigations prove that the pre-existing orthorhombic lath and generated orthorhombic martensite have the same crystallography relationship to the hexagonal parent. Therefore, the orthorhombic martensite can take these pre-existing laths as embryos and grow up. This work implies that the martensitic transformation in MnNiSi$_{1-x}$(CoNiGe)$_{x}$ alloy is initiated by orthorhombic embryos.

关键词: martensitic transformation, MnMX alloy, orthorhombic embryo, crystallography relationship

Abstract: The thermal—elastic martensitic transformation from high-temperature Ni$_{2}$In-type hexagonal structure to low-temperature TiNiSi-type orthorhombic structure has been widely studied in Mn$MX$ ($M={\rm Ni}$ or Co, and $X={\rm Ge}$ or Si) alloys. However, the answer to how the orthorhombic martensite nucleates and grows within the hexagonal parent is still unclear. In this work, the hexagonal—orthorhombic martensitic transformation in a Co and Ge co-substituted MnNiSi is investigated. One can find some orthorhombic laths embedded in the hexagonal parent at a temperature above the martensitic transformation start temperature ($M_{\rm s}$). With the the sample cooing to $M_{\rm s}$, the laths turn broader, indicating that the martensitic transformation starts from these pre-existing orthorhombic laths. Microstructure observation suggests that these pre-existing orthorhombic laths do not originate from the hexagonal—orthorhombic martensitic transformation because of the difference between atomic occupations of doping elements in the hexagonal parent and those in the pre-existing orthorhombic laths. The phenomenological crystallographic theory and experimental investigations prove that the pre-existing orthorhombic lath and generated orthorhombic martensite have the same crystallography relationship to the hexagonal parent. Therefore, the orthorhombic martensite can take these pre-existing laths as embryos and grow up. This work implies that the martensitic transformation in MnNiSi$_{1-x}$(CoNiGe)$_{x}$ alloy is initiated by orthorhombic embryos.

Key words: martensitic transformation, MnMX alloy, orthorhombic embryo, crystallography relationship

中图分类号: (Martensitic transformations)

81.30.Kf

81.05.Bx (Metals, semimetals, and alloys) 68.55.A- (Nucleation and growth) 61.50.Ks (Crystallographic aspects of phase transformations; pressure effects)

Ting-Ting Zhang(张婷婷), Yuan-Yuan Gong(龚元元), Zi-Qian Lu(鲁子骞), and Feng Xu(徐锋). Pre-existing orthorhombic embryos-induced hexagonal—orthorhombic martensitic transformation in MnNiSi_1-x(CoNiGe)_x alloy[J]. 中国物理B, 2024, 33(4): 48103-048103.

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Pre-existing orthorhombic embryos-induced hexagonal—orthorhombic martensitic transformation in MnNiSi_1-x(CoNiGe)_x alloy

Pre-existing orthorhombic embryos-induced hexagonal—orthorhombic martensitic transformation in MnNiSi_1-x(CoNiGe)_x alloy

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