A single dual-mode gas sensor for early safety warning of Li-ion batteries: Micro-scale Li dendrite and electrolyte leakage

doi:10.1088/1674-1056/ac98a3

中国物理B ›› 2022, Vol. 31 ›› Issue (11): 110704-110704.doi: 10.1088/1674-1056/ac98a3

A single dual-mode gas sensor for early safety warning of Li-ion batteries: Micro-scale Li dendrite and electrolyte leakage

Wenjun Yan(闫文君)^1,2,†, Zhishen Jin(金志燊)¹, Zhengyang Lin(林政扬)¹, Shiyu Zhou(周诗瑜)², Yonghai Du(杜永海)¹, Yulong Chen(陈宇龙)^3,‡, and Houpan Zhou(周后盘)¹

1 School of Automation, Hangzhou Dianzi University, Hangzhou 310018, China;
2 Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
3 Institute of Microelectronics, University of Macau, Avenida da Universidade, Taipa, Macau, China

收稿日期:2022-08-17 修回日期:2022-09-29 接受日期:2022-10-10 出版日期:2022-10-17 发布日期:2022-11-03
通讯作者: Wenjun Yan, Yulong Chen E-mail:yanwenjun@hdu.edu.cn;yulongchen@um.edu.mo
基金资助:
This research was supported by the Zhejiang Science and Technology Foundation (Grant No. LQ20F040006).

A single dual-mode gas sensor for early safety warning of Li-ion batteries: Micro-scale Li dendrite and electrolyte leakage

Wenjun Yan(闫文君)^1,2,†, Zhishen Jin(金志燊)¹, Zhengyang Lin(林政扬)¹, Shiyu Zhou(周诗瑜)², Yonghai Du(杜永海)¹, Yulong Chen(陈宇龙)^3,‡, and Houpan Zhou(周后盘)¹

1 School of Automation, Hangzhou Dianzi University, Hangzhou 310018, China;
2 Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
3 Institute of Microelectronics, University of Macau, Avenida da Universidade, Taipa, Macau, China

Received:2022-08-17 Revised:2022-09-29 Accepted:2022-10-10 Online:2022-10-17 Published:2022-11-03
Contact: Wenjun Yan, Yulong Chen E-mail:yanwenjun@hdu.edu.cn;yulongchen@um.edu.mo
Supported by:
This research was supported by the Zhejiang Science and Technology Foundation (Grant No. LQ20F040006).

摘要/Abstract

摘要： Li dendrites and electrolyte leakage are common causes of Li-ion battery failure. H₂, generated by Li dendrites, and electrolyte vapors have been regarded as gas markers of the early safety warning of Li-ion batteries. SnO₂-based gas sensors, widely used for a variety of applications, are promising for the early safety detection of Li-ion batteries, which are necessary and urgently required for the development of Li-ion battery systems. However, the traditional SnO₂ sensor, with a single signal, cannot demonstrate intelligent multi-gas recognition. Here, a single dual-mode (direct and alternating current modes) SnO₂ sensor demonstrates clear discrimination of electrolyte vapors and H₂, released in different states of Li-ion batteries, together with principal component analysis (PCA) analysis. This work provides insight into the intelligent technology of single gas sensors.

关键词: gas sensors, single dual-mode, multivariable sensors, Li-batteries, early safety warning

Abstract: Li dendrites and electrolyte leakage are common causes of Li-ion battery failure. H₂, generated by Li dendrites, and electrolyte vapors have been regarded as gas markers of the early safety warning of Li-ion batteries. SnO₂-based gas sensors, widely used for a variety of applications, are promising for the early safety detection of Li-ion batteries, which are necessary and urgently required for the development of Li-ion battery systems. However, the traditional SnO₂ sensor, with a single signal, cannot demonstrate intelligent multi-gas recognition. Here, a single dual-mode (direct and alternating current modes) SnO₂ sensor demonstrates clear discrimination of electrolyte vapors and H₂, released in different states of Li-ion batteries, together with principal component analysis (PCA) analysis. This work provides insight into the intelligent technology of single gas sensors.

Key words: gas sensors, single dual-mode, multivariable sensors, Li-batteries, early safety warning

中图分类号: (Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing)

07.07.Df

85.30.-z (Semiconductor devices) 84.37.+q (Measurements in electric variables (including voltage, current, resistance, capacitance, inductance, impedance, and admittance, etc.)) 89.60.Ec (Environmental safety)

Wenjun Yan(闫文君), Zhishen Jin(金志燊), Zhengyang Lin(林政扬), Shiyu Zhou(周诗瑜), Yonghai Du(杜永海), Yulong Chen(陈宇龙), and Houpan Zhou(周后盘). A single dual-mode gas sensor for early safety warning of Li-ion batteries: Micro-scale Li dendrite and electrolyte leakage[J]. 中国物理B, 2022, 31(11): 110704-110704.

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A single dual-mode gas sensor for early safety warning of Li-ion batteries: Micro-scale Li dendrite and electrolyte leakage

A single dual-mode gas sensor for early safety warning of Li-ion batteries: Micro-scale Li dendrite and electrolyte leakage

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