Large-scale synthesis of polyynes with commercial laser marking technology

doi:10.1088/1674-1056/ac7cd1

中国物理B ›› 2022, Vol. 31 ›› Issue (12): 126803-126803.doi: 10.1088/1674-1056/ac7cd1

所属专题： SPECIAL TOPIC — The third carbon: Carbyne with one-dimensional sp-carbon

Large-scale synthesis of polyynes with commercial laser marking technology

Liang Fang(房良)^1,†, Yanping Xie(解燕平)², Shujie Sun(孙书杰)¹, and Wei Zi(訾威)¹

1 Collaborative Innovation Center of Henan Province for Energy-Saving Building Materials, Xinyang Normal University, Xinyang 464000, China;
2 Analysis&Testing Center, Xinyang Normal University, Xinyang 464000, China

收稿日期:2022-05-10 修回日期:2022-06-17 接受日期:2022-06-29 出版日期:2022-11-11 发布日期:2022-11-21
通讯作者: Liang Fang E-mail:fangliang@xynu.edu.cn
基金资助:
The authors thank Qiuju Zhou, Zongwen Zhang, and Dongli Xu at the Analysis and Testing Center of Xinyang Normal University (XYNU) for materials characterization. Project supported by the Nanhu Scholars Program for Young Scholars of Xinyang Normal University.

Large-scale synthesis of polyynes with commercial laser marking technology

Liang Fang(房良)^1,†, Yanping Xie(解燕平)², Shujie Sun(孙书杰)¹, and Wei Zi(訾威)¹

1 Collaborative Innovation Center of Henan Province for Energy-Saving Building Materials, Xinyang Normal University, Xinyang 464000, China;
2 Analysis&Testing Center, Xinyang Normal University, Xinyang 464000, China

Received:2022-05-10 Revised:2022-06-17 Accepted:2022-06-29 Online:2022-11-11 Published:2022-11-21
Contact: Liang Fang E-mail:fangliang@xynu.edu.cn
Supported by:
The authors thank Qiuju Zhou, Zongwen Zhang, and Dongli Xu at the Analysis and Testing Center of Xinyang Normal University (XYNU) for materials characterization. Project supported by the Nanhu Scholars Program for Young Scholars of Xinyang Normal University.

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摘要/Abstract

摘要： The space-confined synthesis method has been an efficient way for the preparation of linear carbon chains. However, the large-scale preparation of linear carbon chains still faces many challenges due to the lack of methods for the large-scale synthesis of precursors, such as short carbon chains (polyynes), and regulation technology for the transport of reactants in one-dimensional space. Here, we report a facile method for the rapid preparation of polyynes in large quantities using a commercial laser marking machine. Spectroscopic characterizations show that a large number of polyynes, such as C₈H₂, C₁₀H₂, C₁₂H₂, and C₁₄H₂, can be produced by ablating the graphite plate immersed in the organic liquid using a laser marking machine. The results of in situ Raman spectroscopy investigation of C_2nH₂-filled single-walled carbon nanotubes further confirm that a variety of polyyne molecules are synthesized. Meanwhile, in situ Raman spectroscopy also shows that the local heating treatment can accelerate the filling process of C_2nH₂ into one-dimensional channels. This work provides new insights into the study of linear carbon chains and space-confined synthesis methods.

关键词: polyynes, carbon chains, single-walled carbon nanotubes

Abstract: The space-confined synthesis method has been an efficient way for the preparation of linear carbon chains. However, the large-scale preparation of linear carbon chains still faces many challenges due to the lack of methods for the large-scale synthesis of precursors, such as short carbon chains (polyynes), and regulation technology for the transport of reactants in one-dimensional space. Here, we report a facile method for the rapid preparation of polyynes in large quantities using a commercial laser marking machine. Spectroscopic characterizations show that a large number of polyynes, such as C₈H₂, C₁₀H₂, C₁₂H₂, and C₁₄H₂, can be produced by ablating the graphite plate immersed in the organic liquid using a laser marking machine. The results of in situ Raman spectroscopy investigation of C_2nH₂-filled single-walled carbon nanotubes further confirm that a variety of polyyne molecules are synthesized. Meanwhile, in situ Raman spectroscopy also shows that the local heating treatment can accelerate the filling process of C_2nH₂ into one-dimensional channels. This work provides new insights into the study of linear carbon chains and space-confined synthesis methods.

Key words: polyynes, carbon chains, single-walled carbon nanotubes

中图分类号: (Other materials)

68.35.bt

78.30.-j (Infrared and Raman spectra) 66.30.Pa (Diffusion in nanoscale solids)

Liang Fang(房良), Yanping Xie(解燕平), Shujie Sun(孙书杰), and Wei Zi(訾威). Large-scale synthesis of polyynes with commercial laser marking technology[J]. 中国物理B, 2022, 31(12): 126803-126803.

Liang Fang(房良), Yanping Xie(解燕平), Shujie Sun(孙书杰), and Wei Zi(訾威). Large-scale synthesis of polyynes with commercial laser marking technology[J]. Chin. Phys. B, 2022, 31(12): 126803-126803.

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Large-scale synthesis of polyynes with commercial laser marking technology

Large-scale synthesis of polyynes with commercial laser marking technology

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